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Fiveling
A fiveling, also known as a decahedral nanoparticle, a multiply-twinned particle (MTP), a pentagonal nanoparticle, a pentatwin, or a five-fold twin is a type of twinned crystal that can exist at sizes ranging from nanometers to Millimetre, millimetres. It contains five different single crystals arranged around a common axis. In most cases each unit has a Cubic crystal system#Bravais lattice, face centered cubic (fcc) arrangement of the atoms, although they are also known for other types of crystal structure. They nucleate at quite small sizes in the nanometer range, but can be grown much larger. They have been found in mineral Crystal, crystals excavated from mines such as pentagonite or native gold from Ukraine, in rods of metals grown via electrochemical processes and in nanoparticles produced by the condensation of metals either onto substrates or in inert gases. They have been investigated for their potential uses in areas such as improving the efficiency of solar cell or he ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nanomaterials
* Nanomaterials describe, in principle, materials of which a single unit is sized (in at least one dimension) between 1 and 100 nm (the usual definition of nanoscale). Nanomaterials research takes a materials science-based approach to nanotechnology, leveraging advances in materials metrology and synthesis which have been developed in support of microfabrication research. Materials with structure at the nanoscale often have unique optical, electronic, thermo-physical or mechanical properties. Nanomaterials are slowly becoming commercialized and beginning to emerge as commodities. Definition In ISO/TS 80004, ''nanomaterial'' is defined as the "material with any external dimension in the nanoscale or having internal structure or surface structure in the nanoscale", with ''nanoscale'' defined as the "length range approximately from 1 nm to 100 nm". This includes both ''nano-objects'', which are discrete pieces of material, and ''nanostructured materials'', which have ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vacuum Deposition
Vacuum deposition is a group of processes used to deposit layers of material atom-by-atom or molecule-by-molecule on a solid surface. These processes operate at pressures well below atmospheric pressure (i.e., vacuum). The deposited layers can range from a thickness of one atom up to millimeters, forming freestanding structures. Multiple layers of different materials can be used, for example to form optical coatings. The process can be qualified based on the vapor source; physical vapor deposition uses a liquid or solid source and chemical vapor deposition uses a chemical vapor. Description The vacuum environment may serve one or more purposes: * reducing the particle density so that the mean free path for collision is long * reducing the particle density of undesirable atoms and molecules (contaminants) * providing a low pressure plasma environment * providing a means for controlling gas and vapor composition * providing a means for mass flow control into the processing ch ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Victor Mordechai Goldschmidt
Victor Mordechai Goldschmidt (10 February 1853 in Mainz – 8 May 1933 in Salzburg) was a German mineralogist, natural philosopher, and art collector. Life Born 1853 in Mainz, Goldschmidt attended the Bergakademie Freiberg in Saxony and graduated in engineering in 1874. He received his doctorate in 1880 in Heidelberg for his work on mechanical rock analysis and continued his studies in Vienna from 1882 to 1887. In 1888 he wrote his habilitation about "Projektion und graphische Krystallberechnung" (''Projection and graphical Crystal Classification'') under the same supervisor as his doctoral dissertation. He founded the Institut für Mineralogie und Kristallographie in Heidelberg in association with the Josefine and Eduard von Portheim Stiftung, which he founded in memory of his maternal ancestors. In 1893, he became an adjunct professor (''Honorarprofessor'') at the University of Heidelberg and in 1913, he was awarded membership in the Heidelberger Akademie der Wissenschaf ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystal Twinning
Crystal twinning occurs when two or more adjacent crystals of the same mineral are oriented so that they share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals that are tightly bonded to each other. The surface along which the lattice points are shared in twinned crystals is called a composition surface or twin plane. Crystallographers classify twinned crystals by a number of twin laws. These twin laws are specific to the crystal structure. The type of twinning can be a diagnostic tool in mineral identification. Deformation twinning, in which twinning develops in a crystal in response to a shear stress, is an important mechanism for permanent shape changes in a crystal.Courtney, Thomas H. (2000) ''Mechanical Behavior of Materials'', 2nd ed. McGraw Hill. Definition Twinning is a form of symmetrical intergrowth between two or more adjacent crystals of the same mineral. It differs from the ordinary random ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gustav Rose
Prof Gustavus ("Gustav") Rose FRSFor HFRSE (18 March 1798 – 15 July 1873) was a German mineralogist who was a native of Berlin. He was President of the German Geological Society from 1863 to 1873. Life He was born in Berlin the son of pharmacologist Valentin Rose. Rose was a graduate of the University of Berlin, where he was a student of mineralogist Christian Samuel Weiss (1780–1856). He also studied under Swedish physical chemist Jöns Jakob Berzelius (1779–1848) in Stockholm. While studying with Berzelius, Rose met German chemist Eilhard Mitscherlich (1794–1863), with whom he maintained a lifelong friendship. Rose provided assistance to Mitscherlich's development of the law of isomorphism. In 1826 he became an associate professor of mineralogy in Berlin. In 1829, with German naturalists Alexander von Humboldt (1769–1859) and Christian Gottfried Ehrenberg (1795–1876), Rose took part in a scientific expedition throughout Imperial Russia. In Russia he performed m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Marcasite
The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both structures do have in common that they contain the disulfide S22− ion, having a short bonding distance between the sulfur atoms. The structures differ in how these di-anions are arranged around the Fe2+ cations. Marcasite is lighter and more brittle than pyrite. Specimens of marcasite often crumble and break up due to the unstable crystal structure. On fresh surfaces, it is pale yellow to almost white and has a bright metallic luster. It tarnishes to a yellowish or brownish color and gives a black streak. It is a brittle material that cannot be scratched with a knife. The thin, flat, tabular crystals, when joined in groups, are called “cockscombs”. In marcasite jewellery, pyrite used as a gemstone is called “marcasite” ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Jacques-Louis Bournon
Jacques-Louis, Comte de Bournon FRS, FGS (21 January 1751 – 24 August 1825) was a French soldier and mineralogist who came to England after the French Revolution. He gained prominence in the scientific community, being elected a fellow of the Royal Society and was a founding member of the Geological Society before returning to France after the Bourbon Restoration. Early life The eldest of four children, Jacques-Louis, Comte de Bournon was born in Metz on 21 January 1751. His father was Jacques de Bournon, the Seigneur of Retonfey and Gras and his mother was Marie-Anne Martinet of Nibouville. His interest in geology began with his father's cabinet of minerals and expanded as he travelled extensively in his youth. He began studying crystallography under Jean-Baptiste L. Romé de l'Isle in Paris. Military career He became an officer in the Regiment de Toul; his military career prospered and he eventually reached the rank of lieutenant which found him serving as artill ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Stability
In chemistry, chemical stability is the thermodynamic stability of a chemical system. Thermodynamic stability occurs when a system is in its lowest energy state, or in chemical equilibrium with its environment. This may be a dynamic equilibrium in which individual atoms or molecules change form, but their overall number in a particular form is conserved. This type of chemical thermodynamic equilibrium will persist indefinitely unless the system is changed. Chemical systems might undergo changes in the phase of matter or a set of chemical reactions. State A is said to be more thermodynamically stable than state B if the Gibbs free energy of the change from A to B is positive. Versus reactivity Thermodynamic stability applies to a particular system. The reactivity of a chemical substance is a description of how it might react across a variety of potential chemical systems and, for a given system, how fast such a reaction could proceed. Chemical substances or states can persist ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemisorption
Chemisorption is a kind of adsorption which involves a chemical reaction between the surface and the adsorbate. New chemical bonds are generated at the adsorbent surface. Examples include macroscopic phenomena that can be very obvious, like corrosion, and subtler effects associated with heterogeneous catalysis, where the catalyst and reactants are in different phases. The strong interaction between the adsorbate and the substrate surface creates new types of electronic bonds. In contrast with chemisorption is physisorption, which leaves the chemical species of the adsorbate and surface intact. It is conventionally accepted that the energetic threshold separating the binding energy of "physisorption" from that of "chemisorption" is about 0.5 eV per adsorbed species. Due to specificity, the nature of chemisorption can greatly differ, depending on the chemical identity and the surface structural properties. The bond between the adsorbate and adsorbent in chemisorption is either ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Disclination
In crystallography, a disclination is a line defect in which rotational symmetry is violated. In analogy with dislocations in crystals, the term, ''disinclination'', for liquid crystals first used by Frederick Charles Frank and since then has been modified to its current usage, ''disclination''. It is a defect in the orientation of director whereas a dislocation is a defect in positional order. Example in two dimensions In 2D, disclinations and dislocations are point defects instead of line defects as in 3D. They are topological defects and play a central role in melting of 2D crystals within the KTHNY theory, based on two Kosterlitz–Thouless transitions. Equally sized discs (spheres, particles, atoms) form a hexagonal crystal as dense packing in two dimensions. In such a crystal, each particle has six nearest neighbors. Local strain and twist (for example induced by thermal motion) can cause configurations where discs (or particles) have a coordination number different of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
