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Equilibrium (thermodynamics)
Thermodynamic equilibrium is a notion of thermodynamics with axiomatic status referring to an internal State variables, state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable Thermodynamic system#Walls, walls. In thermodynamic equilibrium, there are no net macroscopic Flow (mathematics), flows of mass nor of energy within a system or between systems. In a system that is in its own state of internal thermodynamic equilibrium, not only is there an absence of macroscopic change, but there is an “absence of any ''tendency'' toward change on a macroscopic scale.” Systems in mutual thermodynamic equilibrium are simultaneously in mutual Thermal equilibrium, thermal, Mechanical equilibrium, mechanical, Chemical equilibrium, chemical, and Radiative equilibrium, radiative equilibria. Systems can be in one kind of mutual equilibrium, while not in others. In thermodynamic equilibrium, all kinds of equi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamics
Thermodynamics is a branch of physics that deals with heat, Work (thermodynamics), work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantity, physical quantities but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to various topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering, and mechanical engineering, as well as other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the thermodynamic efficiency, efficiency of early steam engines, particularly through the work of French physicist Nicolas Léonard Sadi Carnot, Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dynamic Equilibrium
In chemistry, a dynamic equilibrium exists once a reversible reaction occurs. Substances initially transition between the reactants and products at different rates until the forward and backward reaction rates eventually equalize, meaning there is no net change. Reactants and products are formed at such a rate that the concentration of neither changes. It is a particular example of a system in a steady state. Examples In a new bottle of soda, the concentration of carbon dioxide in the liquid phase has a particular value. If half of the liquid is poured out and the bottle is sealed, carbon dioxide will leave the liquid phase at an ever-decreasing rate, and the partial pressure of carbon dioxide in the gas phase will increase until equilibrium is reached. At that point, due to thermal motion, a molecule of CO2 may leave the liquid phase, but within a very short time another molecule of CO2 will pass from the gas to the liquid, and vice versa. At equilibrium, the rate of tran ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Edward A
Edward is an English male name. It is derived from the Anglo-Saxon name ''Ēadweard'', composed of the elements '' ēad'' "wealth, fortunate; prosperous" and '' weard'' "guardian, protector”. History The name Edward was very popular in Anglo-Saxon England, but the rule of the Norman and Plantagenet dynasties had effectively ended its use amongst the upper classes. The popularity of the name was revived when Henry III named his firstborn son, the future Edward I, as part of his efforts to promote a cult around Edward the Confessor, for whom Henry had a deep admiration. Variant forms The name has been adopted in the Iberian peninsula since the 15th century, due to Edward, King of Portugal, whose mother was English. The Spanish/Portuguese forms of the name are Eduardo and Duarte. Other variant forms include French Édouard, Italian Edoardo and Odoardo, German, Dutch, Czech and Romanian Eduard and Scandinavian Edvard. Short forms include Ed, Eddy, Eddie, Ted, Teddy a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Process
Classical thermodynamics considers three main kinds of thermodynamic processes: (1) changes in a system, (2) cycles in a system, and (3) flow processes. (1) A Thermodynamic process is a process in which the thermodynamic state of a system is changed. A change in a system is defined by a passage from an initial to a final state of thermodynamic equilibrium. In classical thermodynamics, the actual course of the process is not the primary concern, and often is ignored. A state of thermodynamic equilibrium endures unchangingly unless it is interrupted by a thermodynamic operation that initiates a thermodynamic process. The equilibrium states are each respectively fully specified by a suitable set of thermodynamic state variables, that depend only on the current state of the system, not on the path taken by the processes that produce the state. In general, during the actual course of a thermodynamic process, the system may pass through physical states which are not describable as th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ralph H
Ralph (pronounced or ) is a male name of English origin, derived from the Old English ''Rædwulf'' and Old High German ''Radulf'', cognate with the Old Norse ''Raðulfr'' (''rað'' "counsel" and ''ulfr'' "wolf"). The most common forms are: * Ralph, the common variant form in English, which takes either of the given pronunciations. * Rafe, variant form which is less common; this spelling is always pronounced . * Raif, a very rare variant. Raif Rackstraw from H.M.S. Pinafore * Ralf, the traditional variant form in Dutch, German, Swedish, and Polish. * Ralfs, the traditional variant form in Latvian. * Raoul, the traditional variant form in French. * Raúl, the traditional variant form in Spanish. * Raul, the traditional variant form in Portuguese and Italian. * Raül, the traditional variant form in Catalan. * Rádhulbh, the traditional variant form in Irish. First name Middle Ages * Ralph the Timid (died 1057), pre-Conquest Norman earl of Hereford, England * Ralp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zeroth Law Of Thermodynamics
The zeroth law of thermodynamics is one of the four principal laws of thermodynamics. It provides an independent definition of temperature without reference to entropy, which is defined in the second law. The law was established by Ralph H. Fowler in the 1930s, long after the first, second, and third laws had been widely recognized. The zeroth law states that if two thermodynamic systems are both in thermal equilibrium with a third system, then the two systems are in thermal equilibrium with each other.Buchdahl, H.A. (1966). ''The Concepts of Classical Thermodynamics'', Cambridge University Press, Cambridge, p. 29: "... if each of two systems is in equilibrium with a third system then they are in equilibrium with each other." Two systems are said to be in thermal equilibrium if they are linked by a wall permeable only to heat, and they do not change over time. Another formulation by James Clerk Maxwell is "All heat is of the same kind". Another statement of the law is "All dia ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
George Uhlenbeck
George Eugene Uhlenbeck (December 6, 1900 – October 31, 1988) was a Dutch-American theoretical physicist, known for his significant contributions to quantum mechanics and statistical mechanics. He co-developed the concept of electron spin, alongside Samuel Goudsmit, in 1925. The formalization of Langevin equation for the Brownian motion as a stochastic process, is known as the Ornstein–Uhlenbeck process, derived in 1930 from his work with Leonard Ornstein. I. I. Rabi said that Uhlenbeck and Goudsmit's omission for the Nobel Prize in Physics "will always be a mystery to me". Background and education George Uhlenbeck was the son of Eugenius and Anne Beeger Uhlenbeck. He attended the Hogere Burgerschool (High School) in The Hague, from which he graduated in 1918. He subsequently entered Delft University of Technology as a student in chemical engineering. During the next year, he transferred to Leiden University, to study physics and mathematics, and he earned his bachelor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Max Planck
Max Karl Ernst Ludwig Planck (; ; 23 April 1858 – 4 October 1947) was a German Theoretical physics, theoretical physicist whose discovery of energy quantum, quanta won him the Nobel Prize in Physics in 1918. Planck made many substantial contributions to theoretical physics, but his fame as a physicist rests primarily on his role as the originator of Quantum mechanics, quantum theory and one of the founders of modern physics, which revolutionized understanding of atomic and Subatomic particle, subatomic processes. He is known for the Planck constant, which is of foundational importance for quantum physics, and which he used to derive a set of Unit of measurement, units, today called Planck units, expressed only in terms of fundamental physical constants. Planck was twice president of the German scientific institution Kaiser Wilhelm Society. In 1948, it was renamed the Max Planck Society (Max-Planck-Gesellschaft) and nowadays includes 83 institutions representing a wide range ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Forces
In physics, a force is an influence that can cause an object to change its velocity unless counterbalanced by other forces. In mechanics, force makes ideas like 'pushing' or 'pulling' mathematically precise. Because the magnitude and direction of a force are both important, force is a vector quantity. The SI unit of force is the newton (N), and force is often represented by the symbol . Force plays an important role in classical mechanics. The concept of force is central to all three of Newton's laws of motion. Types of forces often encountered in classical mechanics include elastic, frictional, contact or "normal" forces, and gravitational. The rotational version of force is torque, which produces changes in the rotational speed of an object. In an extended body, each part applies forces on the adjacent parts; the distribution of such forces through the body is the internal mechanical stress. In the case of multiple forces, if the net force on an extended body is zero t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Potential
In thermodynamics, the chemical potential of a Chemical specie, species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a species in a mixture is defined as the rate of change of Thermodynamic free energy, free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system. Thus, it is the partial derivative of the free energy with respect to the amount of the species, all other species' concentrations in the mixture remaining constant. When both temperature and pressure are held constant, and the number of particles is expressed in moles, the chemical potential is the partial Molar concentration, molar Gibbs free energy. At chemical equilibrium or in phase equilibrium, the total sum of the product of chemical potentials and stoichiometric coefficients is zero, as the free en ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pressure
Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and even by industry. Further, both spellings are often used ''within'' a particular industry or country. Industries in British English-speaking countries typically use the "gauge" spelling. is the pressure relative to the ambient pressure. Various #Units, units are used to express pressure. Some of these derive from a unit of force divided by a unit of area; the International System of Units, SI unit of pressure, the Pascal (unit), pascal (Pa), for example, is one newton (unit), newton per square metre (N/m2); similarly, the Pound (force), pound-force per square inch (Pound per square inch, psi, symbol lbf/in2) is the traditional unit of pressure in the imperial units, imperial and United States customary units, US customary systems. Pressure ma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Equilibrium
In a chemical reaction, chemical equilibrium is the state in which both the Reagent, reactants and Product (chemistry), products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the Thermodynamic system, system. This state results when the forward reaction proceeds at the same rate as the Reversible reaction, reverse reaction. The reaction rates of the forward and backward reactions are generally not zero, but they are equal. Thus, there are no net changes in the concentrations of the reactants and products. Such a state is known as dynamic equilibrium. It is the subject of study of ''equilibrium chemistry''. Historical introduction The Concept learning, concept of chemical equilibrium was developed in 1803, after Claude Louis Berthollet, Berthollet found that some chemical reactions are Reversible reaction, reversible. For any reaction mixture to exist at equilibrium, the reaction rate, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
