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Deep Geological Repository
A deep geological repository is a way of storing hazardous or radioactive waste within a stable geologic environment, typically 200–1,000 m below the surface of the earth. It entails a combination of waste form, waste package, engineered seals and geology that is suited to provide a high level of long-term isolation and containment without future maintenance. This is intended to prevent radioactive dangers. A number of mercury, cyanide and arsenic waste repositories are operating worldwide including Canada ( Giant Mine) and Germany (potash mines in Herfa-Neurode and Zielitz). Radioactive waste storage sites are under construction with the Onkalo in Finland being the most advanced. Principles and background Highly toxic waste that cannot be further recycled must be stored in isolation, to avoid contamination of air, ground and underground water. Deep geological repository is a type of long-term storage that isolates waste in geological structures that are expected to be st ...
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Nuclear Reprocessing
Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the reprocessed plutonium was recycled back into MOX nuclear fuel for thermal reactors. The reprocessed uranium, also known as the spent fuel material, can in principle also be re-used as fuel, but that is only economical when uranium supply is low and prices are high. Nuclear reprocessing may extend beyond fuel and include the reprocessing of other nuclear reactor material, such as Zircaloy cladding. The high radioactivity of spent nuclear material means that reprocessing must be highly controlled and carefully executed in advanced facilities by specialized personnel. Numerous processes exist, with the chemical based PUREX process dominating. Alternatives include heating to drive off volatile elements, burning via oxidation, and fluoride vola ...
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Underground Research Laboratory
The Underground Research Laboratory was a test site for deep geological repository of nuclear waste operated by Atomic Energy of Canada Limited's (AECL's) Whiteshell Laboratories near Lac du Bonnet in Manitoba, Canada. The site was built inside a large granite batholith, typical of the Canadian Shield. The site was selected in 1980, construction began in 1982 and it opened in 1985. No radioactive material was stored at the site, it was used purely for measurements of water exchange, rock movement, and other issues that would affect the safety of such materials. The site was also used by a variety of international users. As part of the wider wind-down of AECL activities, the decision was made to close the URL in 2003. Cleanup work began in 2006 and completed in 2010. The site continues to host a single international experiment measuring water leakage through a massive clay plug. History Nuclear Fuel Waste Management Program Through the 1970s the issue of storing nuclear waste becam ...
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Clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide. Clays develop plasticity (physics), plasticity when wet but can be hardened through Pottery#Firing, firing. Clay is the longest-known ceramic material. Prehistoric humans discovered the useful properties of clay and used it for making pottery. Some of the earliest pottery shards have been radiocarbon dating, dated to around 14,000 BCE, and Clay tablet, clay tablets were the first known writing medium. Clay is used in many modern industrial processes, such as paper making, cement production, and chemical filtration, filtering. Between one-half and two-thirds of the world's population live or work in buildings made with clay, often baked into brick, as an essenti ...
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Borehole
A borehole is a narrow shaft bored in the ground, either vertically or horizontally. A borehole may be constructed for many different purposes, including the extraction of water ( drilled water well and tube well), other liquids (such as petroleum), or gases (such as natural gas). It may also be part of a geotechnical investigation, environmental site assessment, mineral exploration, temperature measurement, as a pilot hole for installing piers or underground utilities, for geothermal installations, or for underground storage of unwanted substances, e.g. in carbon capture and storage. Importance Engineers and environmental consultants use the term ''borehole'' to collectively describe all of the various types of holes drilled as part of a geotechnical investigation or environmental site assessment (a so-called Phase II ESA). This includes holes advanced to collect soil samples, water samples or rock cores, to advance ''in situ'' sampling equipment, or to install monitor ...
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Ground Water
Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available fresh water in the world is groundwater. A unit of rock or an unconsolidated deposit is called an ''aquifer'' when it can yield a usable quantity of water. The depth at which soil pore spaces or fractures and voids in rock become completely saturated with water is called the ''water table''. Groundwater is recharged from the surface; it may discharge from the surface naturally at springs and seeps, and can form oases or wetlands. Groundwater is also often withdrawn for agricultural, municipal, and industrial use by constructing and operating extraction wells. The study of the distribution and movement of groundwater is ''hydrogeology'', also called groundwater hydrology. Typically, groundwater is thought of as water flowing through shallow aquifers, but, in the technical sense, it can also contain soil mois ...
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Transuranic Elements
The transuranium (or transuranic) elements are the chemical elements with atomic number greater than 92, which is the atomic number of uranium. All of them are radioactively unstable and decay into other elements. Except for neptunium and plutonium, which have been found in trace amounts in nature, none occur naturally on Earth and they are synthetic. Overview Of the elements with atomic numbers 1 to 92, most can be found in nature, having stable isotopes (such as oxygen) or very long-lived radioisotopes (such as uranium), or existing as common decay products of the decay of uranium and thorium (such as radon). The exceptions are technetium, promethium, astatine, and francium; all four occur in nature, but only in very minor branches of the uranium and thorium decay chains, and thus all save francium were first discovered by synthesis in the laboratory rather than in nature. All elements with higher atomic numbers have been first discovered in the laboratory, with neptunium a ...
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Plutonium
Plutonium is a chemical element; it has symbol Pu and atomic number 94. It is a silvery-gray actinide metal that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibits six allotropes and four oxidation states. It reacts with carbon, halogens, nitrogen, silicon, and hydrogen. When exposed to moist air, it forms oxides and hydrides that can expand the sample up to 70% in volume, which in turn flake off as a powder that is pyrophoric. It is radioactive and can accumulate in bones, which makes the handling of plutonium dangerous. Plutonium was first synthesized and isolated in late 1940 and early 1941, by deuteron bombardment of uranium-238 in the cyclotron at the University of California, Berkeley. First, neptunium-238 (half-life 2.1 days) was synthesized, which then beta-decayed to form the new element with atomic number 94 and atomic weight 238 (half-life 88 years). Since uranium had been named after the planet Uranus ...
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Oklo
Oklo is a region near Franceville in the Haut-Ogooué Province of Gabon. Several natural nuclear fission reactors were discovered in the uranium mines in the region in 1972. History Gabon was a French colony when prospectors from the Commissariat à l'énergie atomique (the industrial parts, which later became Orano Cycle) discovered uranium in the remote region in 1956. France immediately opened mines operated by Comuf () near Mounana village to exploit the vast mineral resources, and the state of Gabon was given a minority share in the company. For 40 years, France mined uranium in Gabon. Once extracted, the uranium was used for electricity production in France and much of Europe. Today the uranium deposits are exhausted, and the mine is no longer active. Currently, mine reclamation work is ongoing in the region affected by the mine operations. Natural nuclear fission reactor Some of the mined uranium was found to have a lower concentration of uranium-235 than expect ...
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Natural Nuclear Fission Reactor
A natural nuclear fission reactor is a uranium deposit where self-sustaining nuclear chain reactions occur. The idea of a nuclear reactor existing ''in situ'' within an ore body moderated by groundwater was briefly explored by Paul Kuroda in 1956. The existence of an extinct or fossil nuclear fission reactor, where self-sustaining nuclear reactions have occurred in the past, are established by analysis of isotope ratios of uranium and of the fission products (and the stable daughter nuclides of those fission products). The first discovery of such a reactor happened in 1972 in Oklo, Gabon, by researchers from the French Alternative Energies and Atomic Energy Commission (CEA) when chemists performing quality control for the French nuclear industry noticed sharp depletions of fissile in gaseous uranium made from Gabonese ore. Oklo is the only location where this phenomenon is known to have occurred, and consists of 16 sites with patches of centimeter-sized ore layers. There, ...
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Quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical formula of Silicon dioxide, SiO2. Quartz is, therefore, classified structurally as a Silicate mineral#Tectosilicates, framework silicate mineral and compositionally as an oxide mineral. Quartz is the second most abundant mineral in Earth's continental crust, behind feldspar. Quartz exists in two forms, the normal α-quartz and the high-temperature β-quartz, both of which are chiral. The transformation from α-quartz to β-quartz takes place abruptly at . Since the transformation is accompanied by a significant change in volume, it can easily induce microfracturing of ceramics or rocks passing through this temperature threshold. There are many different varieties of quartz, several of which are classifi ...
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