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Dachiardite-K
Dachiardite-K is a rare zeolite-group mineral with the formula K4(Si20Al4O48)•13H2O. It is the potassium-analogue of dachiardite-Ca and dachiardite-Na, as suggested by the suffix "-K". Dachiardite honors Italian geologist and mineralogist Antonio D'Achiardi. Occurrence and association Dachiardite-K was discovered in opal-chalcedony veins in Eastern Rhodopes, Bulgaria. It is associated with barite, calcite, clinoptilolite-Ca, clinoptilolite-K, celadonite, dachiardite-Ca, dachiardite-Na, ferrierite-K, ferrierite-Mg, ferrierite-Na, mordenite, and smectite A smectite (; ; ) is a mineral mixture of various swelling sheet silicates (phyllosilicates), which have a three-layer 2:1 (TOT) structure and belong to the clay minerals. Smectites mainly consist of montmorillonite, but can often contain secon .... References Zeolites Tectosilicates Silicate minerals Potassium minerals Aluminium minerals Monoclinic minerals {{mineral-stub ...
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Tectosilicate
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, the crystalline forms of silica (silicon dioxide, ) are usually considered to be tectosilicates, and they are classified as such in the Dana system (75.1). However, the Nickel-Strunz system classifies them as oxide minerals (4.DA). Silica is found in nature as the mineral quartz, and its polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from sea ...
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Calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on Scratch hardness, scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses. Other polymorphs of calcium carbonate are the minerals aragonite and vaterite. Aragonite will change to calcite over timescales of days or less at temperatures exceeding 300 °C, and vaterite is even less stable. Etymology Calcite is derived from the German , a term from the 19th century that came from the Latin word for Lime (material), lime, (genitive ) with the suffix ''-ite'' used to name minerals. It is thus a Doublet (linguistics), doublet of the word ''wikt:chalk, chalk''. When applied by archaeology, archaeologists and ...
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Potassium Minerals
Potassium is a chemical element; it has symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to form flaky white potassium peroxide in only seconds of exposure. It was first isolated from potash, the ashes of plants, from which its name derives. In the periodic table, potassium is one of the alkali metals, all of which have a single valence electron in the outer electron shell, which is easily removed to create an ion with a positive charge (which combines with anions to form salts). In nature, potassium occurs only in ionic salts. Elemental potassium reacts vigorously with water, generating sufficient heat to ignite hydrogen emitted in the reaction, and burning with a lilac- colored flame. It is found dissolved in seawater (which is 0.04% potassium by weight), and occurs in many minerals such as orthoclase, a common constituent of granites and ot ...
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Zeolites
Zeolites are a group of several Microporous material, microporous, crystalline aluminosilicate minerals commonly used as commercial adsorption, adsorbents and Catalysis, catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. The term was originally coined in 1756 by Sweden, Swedish mineralogy, mineralogist Axel Fredrik Cronstedt, who observed that rapidly heating a material, believed to have been stilbite, produced large amounts of steam from water that had been Adsorption, adsorbed by the material. Based on this, he called the material ''zeolite'', from the Greek language, Greek , meaning "to boil" and , meaning "stone". Zeolites occur naturally, but are also produced industrially on a large scale. , 253 unique zeolite frameworks have been identified, and over 40 naturally occurring zeolite frameworks are known. Every new zeolite structure that is obtained is examined by the International Zeolite Associa ...
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Smectite
A smectite (; ; ) is a mineral mixture of various swelling sheet silicates (phyllosilicates), which have a three-layer 2:1 (TOT) structure and belong to the clay minerals. Smectites mainly consist of montmorillonite, but can often contain secondary minerals such as quartz and calcite. Terminology In clay mineralogy, smectite is synonym of montmorillonite (also the name of a pure clay mineral phase) to indicate a class of swelling clays. The term smectite is commonly used in Europe and in the UK while the term montmorillonite is preferred in North America, but both terms are equivalent and can be used interchangeably. For industrial and commercial applications, the term bentonite is mostly used in place of smectite or montmorillonite. Mineralogical structure The 2:1 layer (TOT) structure consists of two Silicon dioxide, silica (SiO2) Tetrahedral molecular geometry, tetrahedral (T) layers which are electrostatically cross-linked via an Al2O3 (gibbsite), or Fe2O3, Octahedral mo ...
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Mordenite
Mordenite is a zeolite mineral with the chemical formula . and it is one of the six most abundant zeolites and is used commercially. It was first described in 1864 by Henry How. He named it after the small community of Morden, Nova Scotia, Canada, along the Bay of Fundy, where it was first found. Mordenite is orthorhombic (a,b,c unequal & all angles 90 degree). It crystallizes in the form of fibrous aggregates, masses, and vertically striated prismatic crystals. It may be colorless, white, or faintly yellow or pink. It has Mohs hardness of 5 and a density of 2.1 g/cm3. When it forms well developed crystals they are hairlike; very long, thin, and delicate. Mordenite’s molecular structure is a framework containing chains of five-membered rings of linked silicate and aluminate tetrahedra (four oxygen atoms arranged at the points of a triangular pyramid about a central silicon or aluminium atom). Its high ratio of silicon to aluminum atoms makes it more resistant to attack b ...
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Ferrierite
The ferrierite group of zeolite minerals (the FER structure) consists of four very similar species: ferrierite-magnesium, Mg, ferrierite-sodium, Na, ferrierite-ammonium, NH4 and ferrierite-potassium, K, based on the dominant cation in the A location. ferrierite-Mg and ferrierite-K are orthorhombic minerals and ferrierite-Na is monoclinic with highly variable cationic composition . Calcium and other ions are often also present. They are found in vitreous to pearly, often radiating, spherical aggregates of thin blade-shaped transparent to translucent crystals. Ferrierite typically occurs as an alteration mineral in basaltic rocks and in tuffaceous sediments. In North America, it is found at Kamloops Lake, Kamloops Lake, BC, Canada (the original Type locality (geology), type locality) and Leavitt, California, Leavitt Lake, California. Ferrierite was named for Canadian geologist and mining engineer Walter Frederick Ferrier (1865–1950). Synthetic ferrierite Synthetic ferrierites hav ...
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Celadonite
Celadonite is a mica group mineral, a phyllosilicate of potassium, iron in both oxidation states, aluminium and hydroxide with formula . It crystallizes in the monoclinic system and usually forms massive aggregates of prismatic crystallites or, more commonly, in dull clay masses. It is soft with a Mohs hardness of 2 and a specific gravity of 3. It forms vesicle fillings and linings in altered basaltic lavas. Early research suggests this mineral has ties to weakly metamorphosed plutonic rocks during formation, and is also found with montmorillonite clays or zeolite crystals. Association with zeolites may indicate these minerals favor the same underlying conditions of crystal growth. It was first described in 1847 on Monte Baldo, near Verona, Italy. The name is from the French ''celadon,'' for sea-green. It is one of two minerals, along with glauconite, used in making the pigment known as green earth, which was an important pigment for the decoration of Joseon buildings (so mu ...
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Clinoptilolite
Clinoptilolite is a natural zeolite composed of a microporous arrangement of silica and alumina tetrahedra. It has the complex formula . It forms as white, green to reddish tabular monoclinic tectosilicate crystals with a Mohs hardness of 3.5 to 4 and a specific gravity of 2.1 to 2.2. It commonly occurs as a devitrification product of volcanic glass shards in tuff and as vesicle fillings in basalts, andesites and rhyolites. It was described in 1969 from an occurrence in the Barstow Formation, San Bernardino County, California. Sodium levels in clinoptilolite are generally higher than potassium levels, as is the case with the San Bernardino Barstow Formation, but there are sources that are potassium-rich and have minimal sodium. It forms a series with heulandite: *Clinoptilolite-Ca – heulandite-Ca solid solution series *Clinoptilolite-K – heulandite-K solid solution series *Clinoptilolite-Na – heulandite-Na solid solution series Use of clinoptilolite in industry and acade ...
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