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Coldness
In statistical thermodynamics, thermodynamic beta, also known as coldness, is the reciprocal of the thermodynamic temperature of a system:\beta = \frac (where is the temperature and is Boltzmann constant). Thermodynamic beta has units reciprocal to that of energy (in SI units, reciprocal joules, beta= \textrm^). In non-thermal units, it can also be measured in byte per joule, or more conveniently, gigabyte per nanojoule; 1 K−1 is equivalent to about 13,062 gigabytes per nanojoule; at room temperature: = 300K, β ≈ ≈ ≈ . The conversion factor is 1 GB/nJ = 8\ln2\times 10^ J−1. Description Thermodynamic beta is essentially the connection between the information theory and statistical mechanics interpretation of a physical system through its entropy and the thermodynamics associated with its energy. It expresses the response of entropy to an increase in energy. If a small amount of energy is added to the system, then ''β'' describes the amount the system will ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Negative Temperature
Certain system (thermodynamics), systems can achieve negative thermodynamic temperature; that is, their Thermodynamic temperature, temperature can be expressed as a negative number, negative quantity on the Kelvin or Rankine scale, Rankine scales. This should be distinguished from temperatures expressed as negative numbers on non-thermodynamic Celsius scale, Celsius or Fahrenheit scales, which are nevertheless higher than absolute zero. A system with a truly negative temperature on the Kelvin scale is ''hotter'' than any system with a positive temperature. If a negative-temperature system and a positive-temperature system come in contact, heat will flow from the negative- to the positive-temperature system. A standard example of such a system is population inversion in laser physics. Thermodynamic systems with unbounded phase space cannot achieve negative temperatures: adding heat always increases their entropy. The possibility of a decrease in entropy as energy increases requir ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Energy
Energy () is the physical quantity, quantitative physical property, property that is transferred to a physical body, body or to a physical system, recognizable in the performance of Work (thermodynamics), work and in the form of heat and light. Energy is a Conservation law, conserved quantity—the law of conservation of energy states that energy can be Energy transformation, converted in form, but not created or destroyed. The unit of measurement for energy in the International System of Units (SI) is the joule (J). Forms of energy include the kinetic energy of a moving object, the potential energy stored by an object (for instance due to its position in a Classical field theory, field), the elastic energy stored in a solid object, chemical energy associated with chemical reactions, the radiant energy carried by electromagnetic radiation, the internal energy contained within a thermodynamic system, and rest energy associated with an object's rest mass. These are not mutual ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ising Model
The Ising model (or Lenz–Ising model), named after the physicists Ernst Ising and Wilhelm Lenz, is a mathematical models in physics, mathematical model of ferromagnetism in statistical mechanics. The model consists of discrete variables that represent Nuclear magnetic moment, magnetic dipole moments of atomic "spins" that can be in one of two states (+1 or −1). The spins are arranged in a Graph (abstract data type), graph, usually a lattice (group), lattice (where the local structure repeats periodically in all directions), allowing each spin to interact with its neighbors. Neighboring spins that agree have a lower energy than those that disagree; the system tends to the lowest energy but heat disturbs this tendency, thus creating the possibility of different structural phases.The two-dimensional square-lattice Ising model is one of the simplest statistical models to show a phase transition. Though it is a highly simplified model of a magnetic material, the Ising model can sti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Canonical Ensemble
In statistical mechanics, a canonical ensemble is the statistical ensemble that represents the possible states of a mechanical system in thermal equilibrium with a heat bath at a fixed temperature. The system can exchange energy with the heat bath, so that the states of the system will differ in total energy. The principal thermodynamic variable of the canonical ensemble, determining the probability distribution of states, is the absolute temperature (symbol: ). The ensemble typically also depends on mechanical variables such as the number of particles in the system (symbol: ) and the system's volume (symbol: ), each of which influence the nature of the system's internal states. An ensemble with these three parameters, which are assumed constant for the ensemble to be considered canonical, is sometimes called the ensemble. The canonical ensemble assigns a probability to each distinct microstate given by the following exponential: :P = e^, where is the total energy of t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boltzmann Distribution
In statistical mechanics and mathematics, a Boltzmann distribution (also called Gibbs distribution Translated by J.B. Sykes and M.J. Kearsley. See section 28) is a probability distribution or probability measure that gives the probability that a system will be in a certain state as a function of that state's energy and the temperature of the system. The distribution is expressed in the form: :p_i \propto \exp\left(- \frac \right) where is the probability of the system being in state , is the exponential function, is the energy of that state, and a constant of the distribution is the product of the Boltzmann constant and thermodynamic temperature . The symbol \propto denotes proportionality (see for the proportionality constant). The term ''system'' here has a wide meaning; it can range from a collection of 'sufficient number' of atoms or a single atom to a macroscopic system such as a natural gas storage tank. Therefore, the Boltzmann distribution can be used to sol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rational Thermodynamics
Rational thermodynamics is a school of thought in statistical thermodynamics developed in the 1960s. Its introduction is attributed to Clifford Truesdell, and Walter Noll. The aim was to develop a mathematical model of thermodynamics that would go beyond the traditional "thermodynamics of irreversible processes" or TIP developed in the late 19th to early 20th centuries. Truesdell's "flamboyant style" and "satirical verve" caused controversy between "rational thermodynamics" and proponents of traditional thermodynamics.Müller, Ingo (2007). ''A History of Thermodynamics: the Doctrine of Energy and Entropy''. Springer. "Truesdell’s outspoken partisanship of rational thermodynamics and his flamboyant style fuelled some lively controversies between adherents of TIP and the protagonists of rational thermodynamics, chiefly Truesdell himself. His attacks on Onsagerism were advanced with much satirical verve, that makes them fun to read for those who were not targeted. However, the defe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fundamental Assumption Of Statistical Mechanics
Fundamental may refer to: * Foundation of reality * Fundamental frequency, as in music or phonetics, often referred to as simply a "fundamental" * Fundamentalism, the belief in, and usually the strict adherence to, the simple or "fundamental" ideas based on faith in a system of thought * '' Fundamentals: Ten Keys to Reality'', a 2021 popular science book by Frank Wilczek * '' The Fundamentals'', a set of books important to Christian fundamentalism * Any of a number of fundamental theorems identified in mathematics, such as: ** Fundamental theorem of algebra, a theorem regarding the factorization of polynomials ** Fundamental theorem of arithmetic, a theorem regarding prime factorization * Fundamental analysis, the process of reviewing and analyzing a company's financial statements to make better economic decisions Music * Fun-Da-Mental, a rap group * ''Fundamental'' (Bonnie Raitt album), 1998 * ''Fundamental'' (Pet Shop Boys album), 2006 * ''Fundamental'' (Puya album) or the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microstate (statistical Mechanics)
In statistical mechanics, a microstate is a specific configuration of a system that describes the precise positions and momenta of all the individual particles or components that make up the system. Each microstate has a certain probability of occurring during the course of the system's thermal fluctuations. In contrast, the macrostate of a system refers to its macroscopic properties, such as its temperature, pressure, volume and density. Treatments on statistical mechanics define a macrostate as follows: a particular set of values of energy, the number of particles, and the volume of an isolated thermodynamic system is said to specify a particular macrostate of it. In this description, microstates appear as different possible ways the system can achieve a particular macrostate. A macrostate is characterized by a probability distribution of possible states across a certain statistical ensemble of all microstates. This distribution describes the probability of finding the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Partial Derivative
In mathematics, a partial derivative of a function of several variables is its derivative with respect to one of those variables, with the others held constant (as opposed to the total derivative, in which all variables are allowed to vary). Partial derivatives are used in vector calculus and differential geometry. The partial derivative of a function f(x, y, \dots) with respect to the variable x is variously denoted by It can be thought of as the rate of change of the function in the x-direction. Sometimes, for the partial derivative of z with respect to x is denoted as \tfrac. Since a partial derivative generally has the same arguments as the original function, its functional dependence is sometimes explicitly signified by the notation, such as in: f'_x(x, y, \ldots), \frac (x, y, \ldots). The symbol used to denote partial derivatives is ∂. One of the first known uses of this symbol in mathematics is by Marquis de Condorcet from 1770, who used it for partial differ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microcanonical Ensemble
In statistical mechanics, the microcanonical ensemble is a statistical ensemble that represents the possible states of a mechanical system whose total energy is exactly specified. The system is assumed to be isolated in the sense that it cannot exchange energy or particles with its environment, so that (by conservation of energy) the energy of the system does not change with time. The primary macroscopic variables of the microcanonical ensemble are the total number of particles in the system (symbol: ), the system's volume (symbol: ), as well as the total energy in the system (symbol: ). Each of these is assumed to be constant in the ensemble. For this reason, the microcanonical ensemble is sometimes called the ensemble. In simple terms, the microcanonical ensemble is defined by assigning an equal probability to every microstate whose energy falls within a range centered at . All other microstates are given a probability of zero. Since the probabilities must add up to 1, the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamics
Thermodynamics is a branch of physics that deals with heat, Work (thermodynamics), work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantity, physical quantities but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to various topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering, and mechanical engineering, as well as other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the thermodynamic efficiency, efficiency of early steam engines, particularly through the work of French physicist Nicolas Léonard Sadi Carnot, Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
