|
Burke–Schumann Flame
In combustion, a Burke–Schumann flame is a type of diffusion flame, established at the mouth of the two concentric ducts, by issuing fuel and oxidizer from the two region respectively. It is named after S.P. Burke and T.E.W. Schumann, who were able to predict the flame height and flame shape using their simple analysis of infinitely fast chemistry (which is now called as Burke–Schumann limit) in 1928 at the First symposium on combustion. Mathematical description Consider a cylindrical duct with axis along z direction with radius a through which fuel is fed from the bottom and the tube mouth is located at z=0. Oxidizer is fed along the same axis, but in the concentric tube of radius b outside the fuel tube. Let the mass fraction in the fuel tube be Y_ and the mass fraction of the oxygen in the outside duct be Y_. Fuel and oxygen mixing occurs in the region z>0. The following assumptions were made in the analysis: * The average velocity is parallel to axis (z direction) of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. The study of combustion is known as combustion science. Combustion is often a complicated sequence of elementary reaction, elementary Radical (chemistry), radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diffusion Flame
In combustion, a diffusion flame is a flame in which the oxidizer and fuel are separated before burning. Contrary to its name, a diffusion flame involves both diffusion and convection processes. The name diffusion flame was first suggested by S.P. Burke and T.E.W. Schumann in 1928, to differentiate from premixed flame where fuel and oxidizer are premixed prior to burning. The diffusion flame is also referred to as nonpremixed flame. The burning rate is however still limited by the rate of diffusion. Diffusion flames tend to burn slower and to produce more soot than premixed flames because there may not be sufficient oxidizer for the reaction to go to completion, although there are some exceptions to the rule. The soot typically produced in a diffusion flame becomes incandescent from the heat of the flame and lends the flame its readily identifiable orange-yellow color. Diffusion flames tend to have a less-localized flame front than premixed flames. The contexts for diffusion ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Burke–Schumann Limit
In combustion, Burke–Schumann limit, or large Damköhler number limit, is the limit of infinitely fast chemistry (or in other words, infinite Damköhler number), named after S.P. Burke and T.E.W. Schumann, due to their pioneering work on Burke–Schumann flame. One important conclusion of infinitely fast chemistry is the non-co-existence of fuel and oxidizer simultaneously except in a thin reaction sheet. The inner structure of the reaction sheet is described by Liñán's equation. Limit description In a typical non-premixed combustion (fuel and oxidizer are separated initially), mixing of fuel and oxidizer takes place based on the mechanical time scale t_mdictated by the convection/diffusion (the relative importance between convection and diffusion depends on the Reynolds number) terms. Similarly, chemical reaction takes certain amount of time t_c to consume reactants. For one-step irreversible chemistry with Arrhenius rate, this chemical time is given by :t_c = \left(B e^\ri ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Proceedings Of The Combustion Institute
The ''Proceedings of the Combustion Institute'' are the proceedings of the biennial Combustion Symposium put on by The Combustion Institute. The publication contains the most significant contributions in fundamentals and applications, fundamental research of combustion science and combustion phenomena. Research papers and invited topical reviews are included on topics of reaction kinetics, soot, PAH and other large molecules, diagnostics, laminar flames, turbulent flames, heterogenous combustion, spray and droplet combustion, detonations, explosions and supersonic combustion, fire research, stationary combustion systems, internal combustion engine and gas turbine combustion, and new technology concepts. The editors-in-chief are Daniel C. Haworth (Pennsylvania State University) and Terese Løvås ( no) (Norwegian University of Science and Technology). History The need for development of automotive engines, fuels, and aviation formed the basis for the organization which became Th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fuel Mass Fraction
In combustion physics, fuel mass fraction is the ratio of fuel mass flow to the total mass flow of a fuel mixture. If an air flow is fuel free, the fuel mass fraction is zero; in pure fuel without trapped gases, the ratio is unity. As fuel is burned in a combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ... process, the fuel mass fraction is reduced. The definition reads as :Y_F = \frac where *m_F is the mass of the fuel in the mixture *m_ is the total mass of the mixture References Chemical physics Combustion Engineering ratios {{physics-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mass Fraction (chemistry)
In chemistry, the mass fraction of a substance within a mixture is the ratio w_i (alternatively denoted Y_i) of the mass m_i of that substance to the total mass m_\text of the mixture. Expressed as a formula, the mass fraction is: : w_i = \frac . Because the individual masses of the ingredients of a mixture sum to m_\text, their mass fractions sum to unity: : \sum_^ w_i = 1. Mass fraction can also be expressed, with a denominator of 100, as percentage by mass (in commercial contexts often called ''percentage by weight'', abbreviated ''wt.%'' or ''% w/w''; see mass versus weight). It is one way of expressing the composition of a mixture in a dimensionless size; mole fraction (percentage by moles, mol%) and volume fraction ( percentage by volume, vol%) are others. When the prevalences of interest are those of individual chemical elements, rather than of compounds or other substances, the term ''mass fraction'' can also refer to the ratio of the mass of an element to the tot ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arrhenius Law
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates. The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the Van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and reverse reactions. This equation has a vast and important application in determining the rate of chemical reactions and for calculation of energy of activation. Arrhenius provided a physical justification and interpretation for the formula. Laidler, K. J. (1987) ''Chemical Kinetics'', Third Edition, Harper & Row, p. 42 Currently, it is best seen as an empirical relationship.Kenneth Connors, Chemical Kinetics, 1990, VCH Publishers It can be used to model the temperature variation of diffusion coefficients, population of crystal vacancies, creep rates, and many other thermally induced processes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lewis Number
In fluid dynamics and thermodynamics, the Lewis number (denoted ) is a dimensionless number defined as the ratio of thermal diffusivity to mass diffusivity. It is used to characterize fluid flows where there is simultaneous heat and mass transfer. The Lewis number puts the thickness of the thermal boundary layer in relation to the concentration boundary layer. The Lewis number is defined as :\mathrm = \frac = \frac . where: * is the thermal diffusivity, * is the mass diffusivity, * is the thermal conductivity, * is the density, * is the mixture-averaged diffusion coefficient, * is the specific heat capacity at constant pressure. In the field of fluid mechanics, many sources define the Lewis number to be the inverse of the above definition. The Lewis number can also be expressed in terms of the Prandtl number () and the Schmidt number (): :\mathrm = \frac It is named after Warren K. Lewis (1882–1975), who was the first head of the Chemical Engineering Department at MIT. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermal Diffusivity
In thermodynamics, thermal diffusivity is the thermal conductivity divided by density and specific heat capacity at constant pressure. It is a measure of the rate of heat transfer inside a material and has SI, SI units of m2/s. It is an intensive property. Thermal diffusivity is usually denoted by lowercase alpha (), but , , (kappa), , , D_T are also used. The formula is \alpha = \frac, where : is thermal conductivity (W/(m·K)), : is specific heat capacity (J/(kg·K)), : is density (kg/m3). Together, can be considered the volumetric heat capacity (J/(m3·K)). Thermal diffusivity is a positive coefficient in the heat equation: \frac = \alpha \nabla^2 T. One way to view thermal diffusivity is as the ratio of the time derivative of temperature to its Second derivative#Generalization to higher dimensions, curvature, quantifying the rate at which temperature concavity is "smoothed out". In a substance with high thermal diffusivity, heat moves rapidly through it because the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mixture Fraction
Mixture fraction (Z) is a quantity used in combustion studies that measures the mass fraction of one stream of a mixture formed by two feed streams, one the fuel stream and the other the oxidizer stream. Both the feed streams are allowed to have inert gases. The mixture fraction definition is usually normalized such that it approaches unity in the fuel stream and zero in the oxidizer stream. The mixture-fraction variable is commonly used as a replacement for the physical coordinate normal to the flame surface, in nonpremixed combustion. Definition Assume a two-stream problem having one portion of the boundary the fuel stream with fuel mass fraction Y_F=Y_ and another portion of the boundary the oxidizer stream with oxidizer mass fraction Y_=Y_. For example, if the oxidizer stream is air and the fuel stream contains only the fuel, then Y_=0.232 and Y_=1. In addition, assume there is no oxygen in the fuel stream and there is no fuel in the oxidizer stream. Let s be the mass of oxyge ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Shvab–Zeldovich Formulation
The Shvab–Zeldovich formulation is an approach to remove the chemical-source terms from the conservation equations for energy and chemical species by linear combinations of independent variables, when the conservation equations are expressed in a common form. Expressing conservation equations in common form often limits the range of applicability of the formulation. The method was first introduced by V. A. Shvab in 1948 and by Yakov Zeldovich in 1949. Method For simplicity, assume combustion takes place in a single global irreversible reaction \sum_^N \nu_i' \real_i \rightarrow \sum_^N \nu_i'' \real_i where \real_i is the ith chemical species of the total N species and \nu_i' and \nu_i'' are the stoichiometric coefficients of the reactants and products, respectively. Then, it can be shown from the law of mass action that the rate of moles produced per unit volume of any species \omega is constant and given by \omega = \frac where w_i is the mass of species i produced or consum ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bessel Function Of The First Kind
Bessel functions, named after Friedrich Bessel who was the first to systematically study them in 1824, are canonical solutions of Bessel's differential equation x^2 \frac + x \frac + \left(x^2 - \alpha^2 \right)y = 0 for an arbitrary complex number \alpha, which represents the ''order'' of the Bessel function. Although \alpha and -\alpha produce the same differential equation, it is conventional to define different Bessel functions for these two values in such a way that the Bessel functions are mostly smooth functions of \alpha. The most important cases are when \alpha is an integer or half-integer. Bessel functions for integer \alpha are also known as cylinder functions or the cylindrical harmonics because they appear in the solution to Laplace's equation in cylindrical coordinates. #Spherical Bessel functions, Spherical Bessel functions with half-integer \alpha are obtained when solving the Helmholtz equation in spherical coordinates. Applications Bessel's equation arise ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
