Bromine Monoxide Radical
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Bromine Monoxide Radical
Bromine monoxide is a binary inorganic compound of bromine and oxygen with the chemical formula BrO. A free radical, this compound is the simplest of many bromine oxides. The compound is capable of influencing atmospheric chemical processes. Naturally, BrO can be found in volcanic plumes. BrO is similar to the oxygen monofluoride, chlorine monoxide and iodine monoxide radicals. Chemical properties The compound is very effective as a catalyst of the ozone destruction. The chemical reaction of BrO and chlorine dioxide (OClO) results in ozone depletion Ozone depletion consists of two related events observed since the late 1970s: a lowered total amount of ozone in Earth, Earth's upper atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone layer) around Earth's polar ... in the stratosphere. References {{Bromine compounds Bromine compounds Diatomic molecules Oxides Free radicals ...
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Inorganic Compound
An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep Mantle (geology), mantle remain active areas of investigation. All allotropes (structurally different pure forms of an element) and some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, graphene, etc.), carbon monoxide , carbon dioxide , carbides, and salt (chemistry), salts of inorganic anions such as carbonates, cyanides, cyanates, thiocyanates, isothiocyanates, etc. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it cannot occur within life, living things. History ...
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Oxygen Monofluoride
Oxygen monofluoride is an unstable binary inorganic compound radical of fluorine and oxygen with the chemical formula OF. This is the simplest of many oxygen fluorides. Synthesis *OF is a radical that can be formed by thermal of photolytic decomposition of . : *A reaction of fluorine and ozone: : Atmosphere Oxygen- and fluorine-containing radicals like and OF occur in the atmosphere. These, along with other halogen radicals, have been implicated in the destruction of ozone in the atmosphere. However, the oxygen monofluoride radicals are assumed to not play as big a role in the ozone depletion because free fluorine atoms in the atmosphere are believed to react with methane to produce hydrofluoric acid Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. A common concentration is 49% (48–52%) but there are also stronger solutions (e.g. 70%) and pure HF has a boiling p ... which precipitates in rain ...
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Diatomic Molecules
Diatomic molecules () are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen () or oxygen (), then it is said to be homonuclear. Otherwise, if a diatomic molecule consists of two different atoms, such as carbon monoxide () or nitric oxide (), the molecule is said to be heteronuclear. The bond in a homonuclear diatomic molecule is non-polar. The only chemical elements that form stable homonuclear diatomic molecules at standard temperature and pressure (STP) (or at typical laboratory conditions of 1 bar and 25 °C) are the gases hydrogen (), nitrogen (), oxygen (), fluorine (), and chlorine (), and the liquid bromine (). The noble gases (helium, neon, argon, krypton, xenon, and radon) are also gases at STP, but they are monatomic. The homonuclear diatomic gases and noble gases together are called "elemental gases" or "molecular gases", to distinguish them from ...
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Bromine Compounds
Bromine compounds are compounds containing the element bromine (Br). These compounds usually form the −1, +1, +3 and +5 oxidation states. Bromine is intermediate in reactivity between chlorine and iodine, and is one of the most reactive elements. Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X/X couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V). Bromination often leads to higher oxidation states than iodination but lower or equal oxidation states to chlorination. Bromine tends to react with compounds including M–M, M–H, or M–C bonds to form M–Br bonds.Greenwood and Earnshaw, pp. 804–9 Hydrogen bromide The simplest compound of bromine is hydrogen bromide, HBr. It is mainly used in the production of inorganic ...
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Ozone Depletion
Ozone depletion consists of two related events observed since the late 1970s: a lowered total amount of ozone in Earth, Earth's upper atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone layer) around Earth's polar regions. The latter phenomenon is referred to as the #Ozone hole and its causes, ozone hole. There are also springtime polar tropospheric ozone depletion events in addition to these stratospheric events. The main causes of ozone depletion and the ozone hole are manufactured chemicals, especially manufactured halocarbon refrigerants, solvents, propellants, and foam-blowing agents (chlorofluorocarbons (CFCs), HCFCs, Haloalkanes, halons), referred to as ''ozone-depleting substances'' (ODS). These compounds are transported into the stratosphere by Turbulence, turbulent mixing after being emitted from the surface, mixing much faster than the molecules can settle. Once in the stratosphere, they release atoms from the halogen group through photod ...
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Chlorine Dioxide
Chlorine dioxide is a chemical compound with the formula ClO2 that exists as yellowish-green gas above 11 °C, a reddish-brown liquid between 11 °C and −59 °C, and as bright orange crystals below −59 °C. It is usually handled as an aqueous solution. It is commonly used as a bleach. More recent developments have extended its applications in food processing and as a disinfectant. Structure and bonding The molecule ClO2 has an odd number of valence electrons, and therefore it is a Paramagnetism, paramagnetic radical (chemistry), radical. It is an unusual "example of an odd-electron molecule stable toward dimerization" (nitric oxide being another example). ClO2 crystallizes in the orthorhombic List of space groups, Pbca space group. History Chlorine dioxide was first prepared in 1811 by Sir Humphry Davy. In 1933, Lawrence O. Brockway, a graduate student of Linus Pauling, proposed a structure that involved a three-electron bond and two single bond ...
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Iodine Monoxide
Iodine monoxide is a binary inorganic compound of iodine and oxygen with the chemical formula IO•. A free radical, this compound is the simplest of many iodine oxides. It is similar to the oxygen monofluoride, chlorine monoxide and bromine monoxide radicals. Synthesis Iodine monoxide can be obtained by the reaction between iodine and oxygen: : Chemical properties Iodine monoxide decomposes to its prime elements: : Iodine monoxide reacts with nitric oxide: : Atmosphere Atmospheric iodine atoms (e.g. from iodomethane) can react with ozone to produce the iodine monoxide radical: : This process can contribute to ozone depletion Ozone depletion consists of two related events observed since the late 1970s: a lowered total amount of ozone in Earth, Earth's upper atmosphere, and a much larger springtime decrease in stratospheric ozone (the ozone layer) around Earth's polar .... References {{Iodine compounds Iodine compounds Diatomic molecules Oxides Free radicals ...
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Chlorine Monoxide
Chlorine monoxide is a chemical radical with the chemical formula ClO•. It plays an important role in the process of ozone depletion. In the stratosphere, chlorine atoms react with ozone molecules to form chlorine monoxide and oxygen. :Cl• + O3 → ClO• + O2 This reaction causes the depletion of the ozone layer. The resulting ClO• radicals can further react: : ClO• + O• → Cl• + O2 regenerating the chlorine radical. In this way, the overall reaction for the decomposition of ozone is catalyzed by chlorine, as ultimately chlorine remains unchanged. The overall reaction is: :O• + O3 → 2 O2 There has been a significant impact of the use of CFCs on the upper stratosphere, although many countries have agreed to ban the use of CFCs. The nonreactive nature of CFCs allows them to pass into the stratosphere, where they undergo photo-dissociation to form Cl radicals. These then readily form chlorine monoxide, and this cycle can continue until two radicals react to f ...
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Cambridge University Press
Cambridge University Press was the university press of the University of Cambridge. Granted a letters patent by King Henry VIII in 1534, it was the oldest university press in the world. Cambridge University Press merged with Cambridge Assessment to form Cambridge University Press and Assessment under Queen Elizabeth II's approval in August 2021. With a global sales presence, publishing hubs, and offices in more than 40 countries, it published over 50,000 titles by authors from over 100 countries. Its publications include more than 420 academic journals, monographs, reference works, school and university textbooks, and English language teaching and learning publications. It also published Bibles, runs a bookshop in Cambridge, sells through Amazon, and has a conference venues business in Cambridge at the Pitt Building and the Sir Geoffrey Cass Sports and Social Centre. It also served as the King's Printer. Cambridge University Press, as part of the University of Cambridge, was a ...
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Bromine
Bromine is a chemical element; it has chemical symbol, symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived , referring to its sharp and pungent smell. Elemental bromine is very reactive and thus does not occur as a free element in nature. Instead, it can be isolated from colourless soluble crystalline mineral halide Ionic salt, salts analogous to table salt, a property it shares with the other halogens. While it is rather rare in the Earth's crust, the high solubility of the bromide ion (Br) has caused its Bromine cycle, accumulation in the oceans. Commercially the element is easily extracted from brine evaporation ponds, mostly in the United States and Israel. The mass of bromine in the oce ...
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Harvard University
Harvard University is a Private university, private Ivy League research university in Cambridge, Massachusetts, United States. Founded in 1636 and named for its first benefactor, the History of the Puritans in North America, Puritan clergyman John Harvard (clergyman), John Harvard, it is the oldest institution of higher learning in the United States. Its influence, wealth, and rankings have made it one of the most prestigious universities in the world. Harvard was founded and authorized by the Massachusetts General Court, the governing legislature of Colonial history of the United States, colonial-era Massachusetts Bay Colony. While never formally affiliated with any Religious denomination, denomination, Harvard trained Congregationalism in the United States, Congregational clergy until its curriculum and student body were gradually secularized in the 18th century. By the 19th century, Harvard emerged as the most prominent academic and cultural institution among the Boston B ...
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Bromine Oxide
Bromine can form several different oxides: * Dibromine monoxide (Br2O) * Bromine dioxide (BrO2) * Dibromine trioxide (Br2O3) * Dibromine pentoxide (Br2O5) * Tribromine octoxide (Br3O8) Also, a number of ions are bromine oxides: * Hypobromite (BrO−) * Bromous acid, Bromite (BrO2−) * Bromate (BrO3−) * Perbromate (BrO4−) And the bromine monoxide radical: * Bromine monoxide radical, Bromine oxide (BrO) See also

* Oxygen fluoride * Chlorine oxide * Iodine oxide {{Chemistry index Bromine compounds Oxides ...
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