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Bose–Einstein Statistics
In quantum statistics, Bose–Einstein statistics (B–E statistics) describes one of two possible ways in which a collection of non-interacting identical particles may occupy a set of available discrete energy states at thermodynamic equilibrium. The aggregation of particles in the same state, which is a characteristic of particles obeying Bose–Einstein statistics, accounts for the cohesive streaming of laser light and the frictionless creeping of superfluid helium. The theory of this behaviour was developed (1924–25) by Satyendra Nath Bose, who recognized that a collection of identical and indistinguishable particles could be distributed in this way. The idea was later adopted and extended by Albert Einstein in collaboration with Bose. Bose–Einstein statistics apply only to particles that do not follow the Pauli exclusion principle restrictions. Particles that follow Bose-Einstein statistics are called bosons, which have integer values of spin. In contrast, particles ...
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Particle Statistics
Particle statistics is a particular description of multiple particles in statistical mechanics. A key prerequisite concept is that of a statistical ensemble (an idealization comprising the state space of possible states of a system, each labeled with a probability) that emphasizes properties of a large system as a whole at the expense of knowledge about parameters of separate particles. When an ensemble describes a system of particles with similar properties, their number is called the particle number and usually denoted by ''N''. Classical statistics In classical mechanics, all particles ( fundamental and composite particles, atoms, molecules, electrons, etc.) in the system are considered distinguishable. This means that individual particles in a system can be tracked. As a consequence, switching the positions of any pair of particles in the system leads to a different configuration of the system. Furthermore, there is no restriction on placing more than one particle in any given ...
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Quantum
In physics, a quantum (: quanta) is the minimum amount of any physical entity (physical property) involved in an interaction. The fundamental notion that a property can be "quantized" is referred to as "the hypothesis of quantization". This means that the magnitude of the physical property can take on only discrete values consisting of integer multiples of one quantum. For example, a photon is a single quantum of light of a specific frequency (or of any other form of electromagnetic radiation). Similarly, the energy of an electron bound within an atom is quantized and can exist only in certain discrete values. Atoms and matter in general are stable because electrons can exist only at discrete energy levels within an atom. Quantization is one of the foundations of the much broader physics of quantum mechanics. Quantization of energy and its influence on how energy and matter interact (quantum electrodynamics) is part of the fundamental framework for understanding and describing ...
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Thermodynamic Temperature
Thermodynamic temperature, also known as absolute temperature, is a physical quantity which measures temperature starting from absolute zero, the point at which particles have minimal thermal motion. Thermodynamic temperature is typically expressed using the Kelvin scale, where the unit of measurement is the ''kelvin'' (unit symbol: K). The Kelvin scale uses the same degree interval as the Celsius scale but is offset so that 0 K corresponds to absolute zero. For comparison, a temperature of 295 K corresponds to 21.85 °C and 71.33 °F. Another absolute scale of temperature is the Rankine scale, which is based on the Fahrenheit degree interval. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between Work (thermodynamics), thermodynamic work and Heat, heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are now understood as man ...
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Boltzmann Constant
The Boltzmann constant ( or ) is the proportionality factor that relates the average relative thermal energy of particles in a ideal gas, gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin (K) and the molar gas constant, in Planck's law of black-body radiation and Boltzmann's entropy formula, and is used in calculating Johnson–Nyquist noise, thermal noise in resistors. The Boltzmann constant has Dimensional analysis, dimensions of energy divided by temperature, the same as entropy and heat capacity. It is named after the Austrian scientist Ludwig Boltzmann. As part of the 2019 revision of the SI, the Boltzmann constant is one of the seven "Physical constant, defining constants" that have been defined so as to have exact finite decimal values in SI units. They are used in various combinations to define the seven SI base units. The Boltzmann constant is defined to be exactly joules per kelvin, with the effect of defining the SI unit ke ...
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Photon Gas
In physics, a photon gas is a gas-like collection of photons, which has many of the same properties of a conventional gas like hydrogen or neon – including pressure, temperature, and entropy. The most common example of a photon gas in equilibrium is the black-body radiation. Photons are part of a family of particles known as bosons, particles that follow Bose–Einstein statistics and with integer spin. A gas of bosons with only one type of particle is uniquely described by three state functions such as the temperature, volume, and the number of particles. However, for a black body, the energy distribution is established by the interaction of the photons with matter, usually the walls of the container, and the number of photons is not conserved. As a result, the chemical potential of the black-body photon gas is zero at thermodynamic equilibrium. The number of state variables needed to describe a black-body state is thus reduced from three to two (e.g. temperature and volume). ...
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Chemical Potential
In thermodynamics, the chemical potential of a Chemical specie, species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a species in a mixture is defined as the rate of change of Thermodynamic free energy, free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system. Thus, it is the partial derivative of the free energy with respect to the amount of the species, all other species' concentrations in the mixture remaining constant. When both temperature and pressure are held constant, and the number of particles is expressed in moles, the chemical potential is the partial Molar concentration, molar Gibbs free energy. At chemical equilibrium or in phase equilibrium, the total sum of the product of chemical potentials and stoichiometric coefficients is zero, as the free en ...
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Energy
Energy () is the physical quantity, quantitative physical property, property that is transferred to a physical body, body or to a physical system, recognizable in the performance of Work (thermodynamics), work and in the form of heat and light. Energy is a Conservation law, conserved quantity—the law of conservation of energy states that energy can be Energy transformation, converted in form, but not created or destroyed. The unit of measurement for energy in the International System of Units (SI) is the joule (J). Forms of energy include the kinetic energy of a moving object, the potential energy stored by an object (for instance due to its position in a Classical field theory, field), the elastic energy stored in a solid object, chemical energy associated with chemical reactions, the radiant energy carried by electromagnetic radiation, the internal energy contained within a thermodynamic system, and rest energy associated with an object's rest mass. These are not mutual ...
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Degenerate Energy Level
In quantum mechanics, an energy level is degenerate if it corresponds to two or more different measurable states of a quantum system. Conversely, two or more different states of a quantum mechanical system are said to be degenerate if they give the same value of energy upon measurement. The number of different states corresponding to a particular energy level is known as the ''degree of degeneracy'' (or simply the ''degeneracy'') of the level. It is represented mathematically by the Hamiltonian (quantum mechanics), Hamiltonian for the system having more than one linear independence, linearly independent eigenstate with the same energy eigenvalue. When this is the case, energy alone is not enough to characterize what state the system is in, and other quantum numbers are needed to characterize the exact state when distinction is desired. In classical mechanics, this can be understood in terms of different possible trajectories corresponding to the same energy. Degeneracy plays a fu ...
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Photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless particles that can move no faster than the speed of light measured in vacuum. The photon belongs to the class of boson particles. As with other elementary particles, photons are best explained by quantum mechanics and exhibit wave–particle duality, their behavior featuring properties of both waves and particles. The modern photon concept originated during the first two decades of the 20th century with the work of Albert Einstein, who built upon the research of Max Planck. While Planck was trying to explain how matter and electromagnetic radiation could be in thermal equilibrium with one another, he proposed that the energy stored within a material object should be regarded as composed of an integer number of discrete, equal-sized parts. To explain the pho ...
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Maxwell–Boltzmann Statistics
In statistical mechanics, Maxwell–Boltzmann statistics describes the distribution of classical material particles over various energy states in thermal equilibrium. It is applicable when the temperature is high enough or the particle density is low enough to render quantum effects negligible. The expected number of particles with energy \varepsilon_i for Maxwell–Boltzmann statistics is : \langle N_i \rangle = \frac = \frac\,g_i e^, where: * \varepsilon_i is the energy of the ''i''th energy level, * \langle N_i \rangle is the average number of particles in the set of states with energy \varepsilon_i, * g_i is the degeneracy of energy level ''i'', that is, the number of states with energy \varepsilon_i which may nevertheless be distinguished from each other by some other means,For example, two simple point particles may have the same energy, but different momentum vectors. They may be distinguished from each other on this basis, and the degeneracy will be the number of po ...
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White Dwarf
A white dwarf is a Compact star, stellar core remnant composed mostly of electron-degenerate matter. A white dwarf is very density, dense: in an Earth sized volume, it packs a mass that is comparable to the Sun. No nuclear fusion takes place in a white dwarf; what light it radiates is from its residual heat. The nearest known white dwarf is Sirius B, at 8.6 light years, the smaller component of the Sirius binary star. There are currently thought to be eight white dwarfs among the hundred star systems nearest the Sun. The unusual faintness of white dwarfs was first recognized in 1910. The name ''white dwarf'' was coined by Willem Jacob Luyten in 1922. White dwarfs are thought to be the final stellar evolution, evolutionary state of stars whose mass is not high enough to become a neutron star or black hole. This includes over 97% of the stars in the Milky Way. After the hydrogen-stellar nucleosynthesis, fusing period of a main sequence, main-sequence star of Stellar mass, lo ...
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Wavefunction
In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi (letter), psi, respectively). Wave functions are complex number, complex-valued. For example, a wave function might assign a complex number to each point in a region of space. The Born rule provides the means to turn these complex probability amplitudes into actual probabilities. In one common form, it says that the squared modulus of a wave function that depends upon position is the probability density function, probability density of measurement in quantum mechanics, measuring a particle as being at a given place. The integral of a wavefunction's squared modulus over all the system's degrees of freedom must be equal to 1, a condition called ''normalization''. Since the wave function is complex-valued, only its relative phase and relative magnitud ...
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