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Aqueous Homogeneous Reactor
Aqueous homogeneous reactors (AHR) are a type of nuclear reactor in which soluble nuclear salts (usually uranium sulfate or uranium nitrate) are dissolved in water. The fuel is mixed with the coolant and the moderator, thus the name "homogeneous" ("of the same physical state"). The water can be either heavy water or ordinary (light) water, both of which need to be very pure. Their self-controlling features and ability to handle very large increases in reactivity make them unique among reactors, and possibly safest. At Santa Susana, California, Atomics International performed a series of tests titled The Kinetic Energy Experiments. In the late 1940s, control rods were loaded on springs and then flung out of the reactor in milliseconds. Reactor power shot up from ~100 watts to over ~1,000,000 watts with no problems observed. Aqueous homogeneous reactors were sometimes called "water boilers" (not to be confused with boiling water reactors), as the water inside appears to boi ...
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Aqueous Homogeneous Reactor At ORNL
An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be represented as . The word ''aqueous'' (which comes from ''aqua'') means pertaining to, related to, similar to, or dissolved in, water. As water is an excellent solvent and is also naturally abundant, it is a ubiquitous solvent in chemistry. Since water is frequently used as the solvent in experiments, the word solution refers to an aqueous solution, unless the solvent is specified. A ''non-aqueous solution'' is a solution in which the solvent is a liquid, but is not water. (See also Solvent and Inorganic nonaqueous solvent.) Characteristics Substances that are ''hydrophobic'' ('water-fearing') do not dissolve well in water, whereas those that are ''hydrophilic'' ('water-friendly') do. An example of a hydrophilic substance is sodium chlor ...
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Oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is Earth's most abundant element, and after hydrogen and helium, it is the third-most abundant element in the universe. At standard temperature and pressure, two atoms of the element bind to form dioxygen, a colorless and odorless diatomic gas with the formula . Diatomic oxygen gas currently constitutes 20.95% of the Earth's atmosphere, though this has changed considerably over long periods of time. Oxygen makes up almost half of the Earth's crust in the form of oxides.Atkins, P.; Jones, L.; Laverman, L. (2016).''Chemical Principles'', 7th edition. Freeman. Many major classes of organic molecules in living organisms contain oxygen atoms, such as proteins, nucleic acids, carbohydrates, ...
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Los Alamos National Laboratory
Los Alamos National Laboratory (often shortened as Los Alamos and LANL) is one of the sixteen research and development laboratories of the United States Department of Energy (DOE), located a short distance northwest of Santa Fe, New Mexico, in the American southwest. Best known for its central role in helping develop the first atomic bomb, LANL is one of the world's largest and most advanced scientific institutions. Los Alamos was established in 1943 as Project Y, a top-secret site for designing nuclear weapons under the Manhattan Project during World War II.The site was variously called Los Alamos Laboratory and Los Alamos Scientific Laboratory. Chosen for its remote yet relatively accessible location, it served as the main hub for conducting and coordinating nuclear research, bringing together some of the world's most famous scientists, among them numerous Nobel Prize winners. The town of Los Alamos, directly north of the lab, grew extensively through this period. A ...
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Enrico Fermi
Enrico Fermi (; 29 September 1901 – 28 November 1954) was an Italian (later naturalized American) physicist and the creator of the world's first nuclear reactor, the Chicago Pile-1. He has been called the "architect of the nuclear age" and the "architect of the atomic bomb". He was one of very few physicists to excel in both theoretical physics and experimental physics. Fermi was awarded the 1938 Nobel Prize in Physics for his work on induced radioactivity by neutron bombardment and for the discovery of transuranium elements. With his colleagues, Fermi filed several patents related to the use of nuclear power, all of which were taken over by the US government. He made significant contributions to the development of statistical mechanics, quantum theory, and nuclear and particle physics. Fermi's first major contribution involved the field of statistical mechanics. After Wolfgang Pauli formulated his exclusion principle in 1925, Fermi followed with a paper in which ...
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Uranyl Sulfate
Uranyl sulfate describes a family of inorganic compounds with the formula UO2SO4(H2O)n. These salts consist of sulfate, the uranyl ion, and water. They are lemon-yellow solids. Uranyl sulfates are intermediates in some extraction methods used for uranium ores. These compounds can also take the form of an anhydrous salt. Structure The structure of UO2(SO4)(H2O)3.5 is illustrative of the uranyl sulfates. The ''trans''-UO22+ centers are encased in a pentagonal bipyramidal coordination sphere. In the pentagonal plane are five oxygen ligands derived from sulfate and aquo ligands. The compound is a coordination polymer. Uses Aside from the large scale use in mining, uranyl sulfate finds some use as a negative stain in microscopy and tracer in biology. The Aqueous Homogeneous Reactor experiment, constructed in 1951, circulated a fuel composed of 565 grams of U-235 enriched to 14.7% in the form of uranyl sulfate. The acid process of milling uranium ores involves precipitating uranyl s ...
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Nuclear Reaction
In nuclear physics and nuclear chemistry, a nuclear reaction is a process in which two nuclei, or a nucleus and an external subatomic particle, collide to produce one or more new nuclides. Thus, a nuclear reaction must cause a transformation of at least one nuclide to another. If a nucleus interacts with another nucleus or particle and they then separate without changing the nature of any nuclide, the process is simply referred to as a type of nuclear scattering, rather than a nuclear reaction. In principle, a reaction can involve more than two particles colliding, but because the probability of three or more nuclei to meet at the same time at the same place is much less than for two nuclei, such an event is exceptionally rare (see triple alpha process for an example very close to a three-body nuclear reaction). The term "nuclear reaction" may refer either to a change in a nuclide induced by collision with another particle or to a spontaneous change of a nuclide without ...
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Fission Products
Nuclear fission products are the atomic fragments left after a large atomic nucleus undergoes nuclear fission. Typically, a large nucleus like that of uranium fissions by splitting into two smaller nuclei, along with a few neutrons, the release of heat energy (kinetic energy of the nuclei), and gamma rays. The two smaller nuclei are the ''fission products''. (See also Fission products (by element)). About 0.2% to 0.4% of fissions are ternary fissions, producing a third light nucleus such as helium-4 (90%) or tritium (7%). The fission products themselves are usually unstable and therefore radioactive. Due to being relatively neutron-rich for their atomic number, many of them quickly undergo beta decay. This releases additional energy in the form of beta particles, antineutrinos, and gamma rays. Thus, fission events normally result in beta and gamma radiation, even though this radiation is not produced directly by the fission event itself. The produced radionuclides have va ...
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Acid
In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a sequence of database operations that satisfies the ACID properties (which can be perceived as a single logical operation on the data) is called a ''transaction''. For example, a transfer of funds from one bank account to another, even involving multiple changes such as debiting one account and crediting another, is a single transaction. In 1983, Andreas Reuter and Theo Härder coined the acronym ''ACID'', building on earlier work by Jim Gray who named atomicity, consistency, and durability, but not isolation, when characterizing the transaction concept. These four properties are the major guarantees of the transaction paradigm, which has influenced many aspects of development in database systems. According to Gray and Reuter, the IBM Inf ...
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World War II
World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the World War II by country, vast majority of the world's countries—including all of the great powers—forming two opposing military alliances: the Allies of World War II, Allies and the Axis powers. World War II was a total war that directly involved more than 100 million Military personnel, personnel from more than 30 countries. The major participants in the war threw their entire economic, industrial, and scientific capabilities behind the war effort, blurring the distinction between civilian and military resources. Air warfare of World War II, Aircraft played a major role in the conflict, enabling the strategic bombing of population centres and deploying the Atomic bombings of Hiroshima and Nagasaki, only two nuclear weapons ever used in war. World War II was by far the List of wars by death toll, deadliest conflict in hu ...
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Uranyl Nitrate
Uranyl nitrate is a water-soluble yellow uranium salt with the formula . The hexa-, tri-, and dihydrates are known. The compound is mainly of interest because it is an intermediate in the preparation of nuclear fuels. Uranyl nitrate can be prepared by reaction of uranium salts with nitric acid. It is soluble in water, ethanol, and acetone. As determined by neutron diffraction, the uranyl center is characteristically linear with short U=O distances. In the equatorial plane of the complex are six U-O bonds to bidentate nitrate and two water ligands. At 245 pm, these U-O bonds are much longer than the U=O bonds of the uranyl center. Uses Processing of nuclear fuels Uranyl nitrate is important for nuclear reprocessing. It is the compound of uranium that results from dissolving the decladded spent nuclear fuel rods or yellowcake in nitric acid, for further separation and preparation of uranium hexafluoride for isotope separation for preparing of enriched uranium. A special featur ...
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Thorium
Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high melting point. Thorium is an electropositive actinide whose chemistry is dominated by the +4 oxidation state; it is quite reactive and can ignite in air when finely divided. All known thorium isotopes are unstable. The most stable isotope, 232Th, has a half-life of 14.05 billion years, or about the age of the universe; it decays very slowly via alpha decay, starting a decay chain named the thorium series that ends at stable 208 Pb. On Earth, thorium and uranium are the only significantly radioactive elements that still occur naturally in large quantities as primordial elements. Thorium is estimated to be over three times as abundant as uranium in the Earth's crust, and is chiefly refined from monazite sands as a by-product of e ...
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Uranium-233
Uranium-233 (233U or U-233) is a fissile isotope of uranium that is bred from thorium-232 as part of the thorium fuel cycle. Uranium-233 was investigated for use in nuclear weapons and as a reactor fuel. It has been used successfully in experimental nuclear reactors and has been proposed for much wider use as a nuclear fuel. It has a half-life of 160,000 years. Uranium-233 is produced by the neutron irradiation of thorium-232. When thorium-232 absorbs a neutron, it becomes thorium-233, which has a half-life of only 22 minutes. Thorium-233 decays into protactinium-233 through beta decay. Protactinium-233 has a half-life of 27 days and beta decays into uranium-233; some proposed molten salt reactor designs attempt to physically isolate the protactinium from further neutron capture before beta decay can occur, to maintain the neutron economy (if it misses the 233U window, the next fissile target is 235U, meaning a total of 4 neutrons needed to trigger fission). 23 ...
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