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Abietic Acid
Abietic acid (also known as ''abietinic acid'' or ''sylvic acid'') is an organic compound that occurs widely in trees. It is the primary component of resin acid, is the primary irritant in pine wood and resin, isolated from rosin (via isomerization) and is the most abundant of several closely related organic acids that constitute most of rosin, the solid portion of the oleoresin of coniferous trees. Its ester or salt is called an ''abietate''.Lars-Hugo Norlin "Tall Oil" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. Preparation Abietic acid is extracted from tree rosin. The pure material is a colorless solid, but commercial samples are usually a glassy or partly crystalline yellowish solid that melts at temperatures as low as . It belongs to the abietane diterpene group of organic compounds derived from four isoprene units. It is used in lacquers, varnishes, and soaps, and for the analysis of resins and the preparation of metal resinates. It is foun ...
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Merck Index
''The Merck Index'' is an encyclopedia of chemicals, drugs and biologicals with over 10,000 monograph on single substances or groups of related compounds published online by the Royal Society of Chemistry. History The first edition of the Merck's Index was published in 1889 by the German chemical company Emanuel Merck and was primarily used as a sales catalog for Merck's growing list of chemicals it sold. The American subsidiary was established two years later and continued to publish it. During World War I the US government seized Merck's US operations and made it a separate American "Merck" company that continued to publish the Merck Index. In 2012 the Merck Index was licensed to the Royal Society of Chemistry. An online version of The Merck Index, including historic records and new updates not in the print edition, is commonly available through research libraries. It also includes an appendix with monographs on organic named reactions. The 15th edition was published in A ...
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Varnish
Varnish is a clear transparent hard protective coating or film. It is not a stain. It usually has a yellowish shade from the manufacturing process and materials used, but it may also be pigmented as desired, and is sold commercially in various shades. Varnish is primarily used as a wood finish where, stained or not, the distinctive tones and grains in the wood are intended to be visible. Varnish finishes are naturally glossy, but satin/semi-gloss and flat sheens are available. History The word "varnish" comes from Mediaeval Latin ''vernix'', meaning odorous resin, itself derived from Middle Greek ''berōnikón'' or ''beroníkē'', meaning amber or amber-colored glass. A false etymology traces the word to the Greek '' Berenice'', the ancient name of modern Benghazi in Libya, where the first varnishes in the Mediterranean area were supposedly used and where resins from the trees of now-vanished forests were sold. Early varnishes were developed by mixing resin—pine sap, fo ...
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Resin Acids
Resin acid refers to mixtures of several related carboxylic acids, primarily abietic acid, found in tree resins. Nearly all resin acids have the same basic skeleton: three fused rings having the empirical formula C19H29COOH. Resin acids are tacky, yellowish gums that are water-insoluble. They are used to produce soaps for diverse applications, but their use is being displaced increasingly by synthetic acids such as 2-ethylhexanoic acid or petroleum-derived naphthenic acids. Botanical analysis Resin acids are protectants and wood preservatives that are produced by parenchymatous epithelial cells that surround the resin ducts in trees from temperate coniferous forests. The resin acids are formed when two-carbon and three-carbon molecules couple with isoprene building units to form monoterpenes (volatile), sesquiterpenes (volatile), and diterpenes (nonvolatile) structures. Pines contain numerous vertical and radial resin ducts scattered throughout the entire wood. The accumulation o ...
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Heat Treatment
Heat treating (or heat treatment) is a group of industrial process, industrial, thermal and metalworking, metalworking processes used to alter the physical property, physical, and sometimes chemical property, chemical, properties of a material. The most common application is metallurgy, metallurgical. Heat treatments are also used in the manufacture of many other materials, such as glass. Heat treatment involves the use of heating or chilling, normally to extreme temperatures, to achieve the desired result such as hardening or softening of a material. Heat treatment techniques include annealing (metallurgy), annealing, case hardening, precipitation strengthening, tempering (metallurgy), tempering, carburizing, normalizing and quenching. Although the term ''heat treatment'' applies only to processes where the heating and cooling are done for the specific purpose of altering properties intentionally, heating and cooling often occur incidentally during other manufacturing processes s ...
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Oxidation
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogenation, C=C (and other) bon ...
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Rosin Acids
Resin acid refers to mixtures of several related carboxylic acids, primarily abietic acid, found in tree resins. Nearly all resin acids have the same basic skeleton: three fused rings having the empirical formula C19H29COOH. Resin acids are tacky, yellowish gums that are water-insoluble. They are used to produce soaps for diverse applications, but their use is being displaced increasingly by synthetic acids such as 2-ethylhexanoic acid or petroleum-derived naphthenic acids. Botanical analysis Resin acids are protectants and wood preservatives that are produced by parenchymatous epithelial cells that surround the resin ducts in trees from temperate coniferous forests. The resin acids are formed when two-carbon and three-carbon molecules couple with isoprene building units to form monoterpenes (volatile), sesquiterpenes (volatile), and diterpenes (nonvolatile) structures. Pines contain numerous vertical and radial resin ducts scattered throughout the entire wood. The accumulation o ...
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Musical Instruments
A musical instrument is a device created or adapted to make musical sounds. In principle, any object that produces sound can be considered a musical instrument—it is through purpose that the object becomes a musical instrument. A person who plays a musical instrument is known as an instrumentalist. The history of musical instruments dates to the beginnings of human culture. Early musical instruments may have been used for rituals, such as a horn to signal success on the hunt, or a drum in a religious ceremony. Cultures eventually developed composition and performance of melodies for entertainment. Musical instruments evolved in step with changing applications and technologies. The date and origin of the first device considered a musical instrument is disputed. The oldest object that some scholars refer to as a musical instrument, a simple flute, dates back as far as 50,000 - 60,000 years. Some consensus dates early flutes to about 40,000 years ago. However, most historians ...
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Ships
A ship is a large watercraft that travels the world's oceans and other sufficiently deep waterways, carrying cargo or passengers, or in support of specialized missions, such as defense, research, and fishing. Ships are generally distinguished from boats, based on size, shape, load capacity, and purpose. Ships have supported exploration, trade, warfare, migration, colonization, and science. After the 15th century, new crops that had come from and to the Americas via the European seafarers significantly contributed to world population growth. Ship transport is responsible for the largest portion of world commerce. The word ''ship'' has meant, depending on the era and the context, either just a large vessel or specifically a ship-rigged sailing ship with three or more masts, each of which is square-rigged. As of 2016, there were more than 49,000 merchant ships, totaling almost 1.8 billion dead weight tons. Of these 28% were oil tankers, 43% were bulk carriers, and 13% were ...
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Caulking
Caulk or, less frequently, caulking is a material used to seal joints or seams against leakage in various structures and piping. The oldest form of caulk consisted of fibrous materials driven into the wedge-shaped seams between boards on wooden boats or ships. Cast iron sewerage pipe were formerly caulked in a similar way. Riveted seams in ships and boilers were formerly sealed by hammering the metal. Modern caulking compounds are flexible sealing compounds used to close up gaps in buildings and other structures against water, air, dust, insects, or as a component in firestopping. In the tunnelling industry, caulking is the sealing of joints in segmental precast concrete tunnels, commonly by using concrete. Historical uses Wooden shipbuilding Traditional caulking (also spelled calking) on wooden vessels uses fibers of cotton and oakum (hemp) soaked in pine tar. These fibers are driven into the wedge-shaped seam between planks, with a caulking mallet and a broad chisel-l ...
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Pinus Sylvestris
''Pinus sylvestris'', the Scots pine (UK), Scotch pine (US) or Baltic pine, is a species of tree in the pine family Pinaceae that is native to Eurasia. It can readily be identified by its combination of fairly short, blue-green leaves and orange-red bark. Description ''Pinus sylvestris'' is an evergreen coniferous tree growing up to in height and in trunk diameter when mature, exceptionally over tall and in trunk diameter on very productive sites. The tallest on record is a tree over 210 years old tree growing in Estonia which stands at . The lifespan is normally 150–300 years, with the oldest recorded specimens in Lapland, Northern Finland over 760 years. The bark is thick, flaky and orange-red when young to scaly and gray-brown in maturity, sometimes retaining the former on the upper portion.Trees for LifeSpecies profile: Scots pine/ref> The habit of the mature tree is distinctive due to its long, bare and straight trunk topped by a rounded or flat-topped mass ...
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Pinus Strobus
''Pinus strobus'', commonly called the eastern white pine, northern white pine, white pine, Weymouth pine (British), and soft pine is a large pine native to eastern North America. It occurs from Newfoundland, Canada west through the Great Lakes region to southeastern Manitoba and Minnesota, United States, and south along the Appalachian Mountains and upper Piedmont to northernmost Georgia and perhaps very rarely in some of the higher elevations in northeastern Alabama. It is considered rare in Indiana. The Native American Haudenosaunee named it the "Tree of Peace". It is known as the "Weymouth pine" in the United Kingdom, after Captain George Weymouth of the British Royal Navy, who brought its seeds to England from Maine in 1605. Distribution ''P. strobus'' is found in the nearctic temperate broadleaf and mixed forests biome of eastern North America. It prefers well-drained or sandy soils and humid climates, but can also grow in boggy areas and rocky highlands. In mi ...
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Pinus Kesiya
''Pinus kesiya'' (Khasi pine, Benguet pine or three-needled pine) is one of the most widely distributed pines in Asia. Its range extends south and east from the Khasi Hills in the northeast Indian state of Meghalaya, to northern Thailand, Philippines, Burma, Cambodia, Laos, southernmost China, and Vietnam. It is an important plantation species elsewhere in the world, including in southern Africa and South America. The common name "Khasi pine" is from the Khasi hills in India, and "Benguet pine" is from the landlocked province of Benguet in Luzon, Philippines, where it is the dominant species of the Luzon tropical pine forests. The Benguet pine is sometimes treated as a separate species, ''Pinus insularis''; however, the current opinion is to treat these as conspecific with ''P. kesiya''. The city of Baguio is nicknamed "The City of Pines", as it is noted for large stands of this tree. Description ''Pinus kesiya'' is a tree reaching up to tall with a straight, cylindrical ...
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