1,2-Dichloro-1,1,2-trifluoroethane
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1,2-Dichloro-1,1,2-trifluoroethane
1,2-Dichloro-1,1,2-trifluoroethane is a volatile liquid chlorofluoroalkane composed of carbon, hydrogen, chlorine and fluorine, and with structural formula CClF2CHClF. It is also known as a refrigerant with the designation R-123a. Formation 1,1,2-Trichloro-1,2,2-trifluoroethane can be biotransformed in sewage sludge to 1,2-dichloro-1,1,2-trifluoroethane. Properties The critical temperature Critical or Critically may refer to: *Critical, or critical but stable, medical states **Critical, or intensive care medicine *Critical juncture, a discontinuous change studied in the social sciences. *Critical Software, a company specializing in ... of R-123a is . The rotation of the molecule appears to be hindered by the present of chlorine on each carbon atom, but is eased at higher temperatures. Use Although not deliberately used, R-123a is a significant impurity in its isomer, the widely used 2,2-dichloro-1,1,1-trifluoroethane (R-123). References External links * {{DEFAULTSORT:Dic ...
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Chlorofluoroalkane
Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F). They are produced as volatile derivatives of methane, ethane, and propane. The most common example of a CFC is dichlorodifluoromethane (R-12). R-12, also commonly called Freon, is used as a refrigerant. Many CFCs have been widely used as refrigerants, propellants (in aerosol applications), gaseous fire suppression systems, and solvents. As a result of CFCs contributing to ozone depletion in the upper atmosphere, the manufacture of such compounds has been phased out under the Montreal Protocol, and they are being replaced with other products such as hydrofluorocarbons (HFCs) and hydrofluoroolefins (HFOs) including R-410A, R-134a and R-1234yf. Structure, properties and production As in simpler alkanes, carbons in CFCs bond with tetrahedral symmetry. Because the fluorine and chlorine atoms differ g ...
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1,1,2-Trichloro-1,2,2-trifluoroethane
1,1,2-Trichloro-1,2,2-trifluoroethane, also called trichlorotrifluoroethane (often abbreviated as TCTFE) or CFC-113, is a chlorofluorocarbon. It has the formula . This colorless, volatile liquid is a versatile solvent. Production CFC-113 can be prepared from hexachloroethane and hydrofluoric acid: : This reaction may require catalysts such as antimony, chromium, iron and alumina at high temperatures. Another synthesis method uses HF on tetrachloroethylene instead. Atmospheric reactions CFC-113 is a very unreactive chlorofluorocarbon. It may remain in the atmosphere up to 90 years, sufficiently long that it will cycle out of the troposphere and into the stratosphere. In the stratosphere, CFC-113 can be broken up by ultraviolet radiation (UV, sunlight in the 190-225 nm range), generating chlorine radicals (Cl•), which initiate degradation of ozone requiring only a few minutes: : : This reaction is followed by: : The process regenerates Cl• to destroy more . The Cl• wil ...
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Sewage Sludge
Sewage sludge is the residual, semi-solid material that is produced as a by-product during sewage treatment of industrial or municipal wastewater. The term "septage" also refers to sludge from simple wastewater treatment but is connected to simple on-site sanitation systems, such as septic tanks. After treatment, and dependent upon the quality of sludge produced (for example with regards to heavy metal content), sewage sludge is most commonly either disposed of in landfills, dumped in the ocean or applied to land for its fertilizing properties, as pioneered by the product Milorganite. The term " Biosolids" is often used as an alternative to the term sewage sludge in the United States, particularly in conjunction with reuse of sewage sludge as fertilizer after sewage sludge treatment. Biosolids can be defined as organic wastewater solids that can be reused after stabilization processes such as anaerobic digestion and composting. Opponents of sewage sludge reuse reject this t ...
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Critical Temperature
Critical or Critically may refer to: *Critical, or critical but stable, medical states **Critical, or intensive care medicine *Critical juncture, a discontinuous change studied in the social sciences. *Critical Software, a company specializing in mission and business critical information systems *Critical theory, a school of thought that critiques society and culture by applying knowledge from the social sciences and the humanities *Critically endangered, a risk status for wild species *Criticality (status), the condition of sustaining a nuclear chain reaction Art, entertainment, and media *Critical (novel), ''Critical'' (novel), a medical thriller written by Robin Cook *Critical (TV series), ''Critical'' (TV series), a Sky 1 TV series *Critical (Person of Interest), "Critical" (''Person of Interest''), an episode of the American television drama series ''Person of Interest'' *"Critical", a song by Abhi the Nomad from the album ''Abhi vs the Universe'', 2021 *"Critical", a 1999 sin ...
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2,2-dichloro-1,1,1-trifluoroethane
2,2-Dichloro-1,1,1-trifluoroethane or HCFC-123 is considered as an alternative to CFC-11 in low pressure refrigeration and HVAC systems, and should not be used in foam blowing processes or solvent applications. It is also the primary component of the Halotron I fire-extinguishing mixture. Its ozone depletion potential is ODP = 0.012, and global warming potential is GWP = 76. HCFC-123 will eventually be phased out under the current schedule of the Montreal Protocol. It was discontinued in new HVAC equipment in 2020 in developed countries but will still be produced for service use of HVAC equipment until 2030. Developing countries can continue to use It in new equipment until 2030 and will be produced for use in service there until 2040. HCFC-123 is used in large tonnage centrifugal chiller applications, and is the most efficient refrigerant currently in use in the marketplace for HVAC applications. HCFC-123 is also used as a testing agent for bypass leakage of carbon adsorbers in ...
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Hydrochlorofluorocarbons
Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F). They are produced as volatile derivatives of methane, ethane, and propane. The most common example of a CFC is dichlorodifluoromethane (R-12). R-12, also commonly called Freon, is used as a refrigerant. Many CFCs have been widely used as refrigerants, propellants (in aerosol applications), gaseous fire suppression systems, and solvents. As a result of CFCs contributing to ozone depletion in the upper atmosphere, the manufacture of such compounds has been phased out under the Montreal Protocol, and they are being replaced with other products such as hydrofluorocarbons (HFCs) and hydrofluoroolefins (HFOs) including R-410A, R-134a and R-1234yf. Structure, properties and production As in simpler alkanes, carbons in CFCs bond with tetrahedral symmetry. Because the fluorine and chlorine atoms differ g ...
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