Ventilation air methane thermal oxidizer
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Ventilation air methane thermal oxidizers (or VAMTOX) are a type of processing equipment used for greenhouse gas abatement related to
underground mining Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the economic vi ...
operations that destroys gaseous
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Ea ...
at a high temperature.


Principle

Ventilation Air Methane Thermal Oxidizers are used to destroy methane in the exhaust air of underground
coal mine Coal mining is the process of extracting coal from the ground. Coal is valued for its energy content and since the 1880s has been widely used to generate electricity. Steel and cement industries use coal as a fuel for extraction of iron from ...
shafts. Methane is a greenhouse gas that burns to form
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
(CO2) and water vapour. Carbon dioxide is 25 times less potent than methane when emitted into the atmosphere with regards to
global warming In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
. Concentrations of methane in ventilation exhaust air of coal and
trona Trona (trisodium hydrogendicarbonate dihydrate, also sodium sesquicarbonate dihydrate, Na2CO3•2NaHCO3•3H2O) is a non-marine evaporite mineral. It is mined as the primary source of sodium carbonate in the United States, where it has replaced ...
mines are very dilute; typically below 1% and often below 0.5%. Flow rates are so high that ventilation air methane constitutes the largest source of
methane emissions Increasing methane emissions are a major contributor to the rising concentration of greenhouse gases in Earth's atmosphere, and are responsible for up to one-third of near-term global heating. During 2019, about 60% (360 million tons) of methane r ...
at most mines. This methane emission wastes energy and contributes significantly to global greenhouse gas (GHG) emissions.


Operation

Thermal oxidation In microfabrication, thermal oxidation is a way to produce a thin layer of oxide (usually silicon dioxide) on the surface of a wafer. The technique forces an oxidizing agent to diffuse into the wafer at high temperature and react with it. The ra ...
is the most widely accepted air pollution control technologies used in industrial applications. Ventilation Air Methane Thermal Oxidizers are commonly referred to as a VAMTOX. They are very specific and extremely efficient – energy recovery efficiency can reach 95%. This is achieved through the storage of heat in dense ceramic stoneware. Ventilation Air Methane Thermal Oxidizers are used for the very low methane concentrations operate continuously. These systems can destroy 95-98+% methane (CH4) that would otherwise be emitted. Ventilation Air Methane Thermal Oxidizers can be designed with hot gas bypass systems, re-circulation heat exchangers that convert heat into energy, and oxygen monitoring to reduce any possible carbon monoxide and/or nitrous oxide production. Methane streams allow the VAMTOX to operate at reduced or zero fuel usage, which makes these systems ideal for mine shaft ventilation operations. VAMTOX systems have a system of valves and dampers that direct the methane flow across the ceramic bed. On system start up, the system preheats and raises the temperature of the heat exchange material in the oxidizer bed to or above the auto-oxidation temperature of methane (1,000 °C or 1,832 °F). Then the preheating system is turned off and mine exhaust air is introduced. When the methane-filled air reaches the preheated bed, it oxidizes and releases heat. This heat is transferred to the bed, thereby maintaining its temperature to support continued operation. The oxidation process is flameless. Once the bed is preheated, the process needs no auxiliary energy so long as adequate inflow methane concentrations are maintained. The VAMTOX system exhaust gases can be used to raise steam, which can provide electrical power through a turbine generator.


References

Works cited

USEPA, 2003 Assessment of the Worldwide Market Potential for Oxidizing Coal Mine Ventilation Air Methane" July 2003" * "Mattus, R, 2007. In Full Operation – The World’s First VAM Power Plant, presented at the Methane to Markets Partnership Expo, Beijing, China, October 30 – November 1, 2007" *"Hamilton et al., 2007. State of the Voluntary Carbon Markets 2007: Picking Up Steam, Hamilton, K, Bayon, R, Turner, G, and Higgins, D, New Carbon Finance and The Ecosystem Marketplace, July 2007" *"12th U.S./North American Mine Ventilation Symposium 2008 – Wallace (ed) " *"Watson R.T. et al., "IPCC Third Assessment Report – Climate Change 2001", Intergovernmental Panel on Climate Change, Geneva, Switzerland, 2001"


External links


Air Methane Thermal Oxidizer System" American Environmental Fabrication & Supply, Sept. 2010"Assessment of the Worldwide Market Potential for Oxidizing Coal Mine Ventilation Air Methane" U.S EPA, Sept. 2009Thermal oxidation of coal mine ventilation methane" 2008 Mine Ventilation Symposium, Jul. 2008"Capture and use of coal mine ventilation-air methane" U.S. Department of Energy National Energy Technology Laboratory, April 2008
{{DEFAULTSORT:Ventilation Air Methane Thermal Oxidizer Air pollution Energy recovery