Kanoite
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Kanoite is a light pinkish brown
silicate mineral Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...
that is found in
metamorphic rocks Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
. It is an
inosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...
and has a chemical formula of .Handbook of Mineralogy
/ref> It is a member of pyroxene group and
clinopyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
subgroup.Physical Properties of Kanoite. In Kanoite Mineral Data.
''Barthelmy, D. (1997-2010)''.


Crystallography

Kanoite crystallizes in the
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...
crystal system In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices. Space groups are classified into crystal systems according to their poin ...
. Its Hermann–Mauguin Symbol is 2/m. Under this crystal system, the three axes of the crystal are all different in length. The a and the b axes are perpendicular, and b and c axes are perpendicular. The a and c axes make an oblique shape. The axial ratio for kanoite is a:b:c =1.0894:1:0.5884 and the cell dimensions are: a = 9.73, b = 8.93 and c = 5.26 Å with Z = 4. Kanoite has a 2-fold axis and a mirror plane. Kanoite is birefringent. It occurs as a mineral has 3 different indices of refraction. When the light passes through the Kanoite medium, the light splits due to unequal reflection from the crystal faces. As kanoite is birefringent, it is also anisotropic. In an anisotropic mineral, the velocity of light differs as the direction of the crystal changes.


Discovery and occurrence

Kanoite is a rare mineral which was found in Tatehira mine, Kumaishi,
Oshima Peninsula The Oshima Peninsula (渡島 半島 ''Oshima-hantō'') is the southernmost part of Hokkaidō, the northernmost of the Japanese islands. Where the peninsula starts is open to interpretation. A more generous interpretation is to draw a line southea ...
,
Hokkaido is Japan's second largest island and comprises the largest and northernmost prefecture, making up its own region. The Tsugaru Strait separates Hokkaidō from Honshu; the two islands are connected by the undersea railway Seikan Tunnel. The lar ...
, Japan in 1977. In the type locality kanoite occurs along a
joint A joint or articulation (or articular surface) is the connection made between bones, ossicles, or other hard structures in the body which link an animal's skeletal system into a functional whole.Saladin, Ken. Anatomy & Physiology. 7th ed. McGraw- ...
that cuts a
pyroxmangite Pyroxmangite has the general chemical formula of MnSiO3. It is the high-pressure, low-temperature dimorph of rhodonite. It was first described in 1913 and named for the mineral group, pyroxenes, and is known as the manganese member. It forms a ...
-
cummingtonite Cummingtonite ( ) is a metamorphic amphibole with the chemical composition , magnesium iron silicate hydroxide. Monoclinic cummingtonite is compositionally similar and polymorphic with orthorhombic anthophyllite, which is a much more common ...
metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock ( protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
in a manganese ore deposit. The region has undergone
contact metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of che ...
as
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
intruded the area. It was named to honor Hiroshi Kano, a petrology professor at
Akita University is a Japanese national university in Akita City, Japan. Established in 1949, it comprises four graduate schools and four undergraduate faculties. History Akita University was established in 1949 by the merger of Akita Normal School (established ...
in Japan. It has also been reported from Broken Hill,
New South Wales ) , nickname = , image_map = New South Wales in Australia.svg , map_caption = Location of New South Wales in AustraliaCoordinates: , subdivision_type = Country , subdivision_name = Australia , established_title = Before federation , es ...
, Australia, the
Semail Ophiolite The Samail Ophiolite (also spelled Semail Ophiolite) of the Hajar Mountains of Oman and the United Arab Emirates is a large slab of oceanic crust, made of volcanic rocks and ultramafic rocks from the Earth's upper mantle, that was overthrust ont ...
in
Oman Oman ( ; ar, عُمَان ' ), officially the Sultanate of Oman ( ar, سلْطنةُ عُمان ), is an Arabian country located in southwestern Asia. It is situated on the southeastern coast of the Arabian Peninsula, and spans the mouth of ...
, and the Balmat–Edwards zinc district,
Saint Lawrence County, New York St. Lawrence County is a county in the U.S. state of New York. As of the 2020 census, the population was 108,505. The county seat is Canton. The county is named for the Saint Lawrence River, which in turn was named for the Christian saint La ...
.


References

{{reflist *Gnos, E., Armbruster, T., and Nyfeler, D. (1996) Kanoite, donpeacorite and tirodite: Mn-Mg-silicates from a manganiferous quartzite in the United Arab Emirates. European Journal of Mineralogy, 8, 251-261. *Kobayashi, H. (1977) Kanoite, (Mn2+;Mg)2 i2O6 a new clinopyroxene in the metamorphic rock from Tatehira, Oshima Peninsula, Hokkaido, Japan. The Journal of the Geological Society of Japan, 83, 537-542. *Arlt, T. and Armbruster, T. (1997) The temperature dependent P21/c-C2/c phase transition in the clinopyroxene kanoite MnMg i2O6 a single-crystal X-ray and optical study. European Journal of Mineralogy, 9, 953–964. *Akimoto, S. and Syono, Y. (1972) High pressure transformations in MnSiO3. American Mineralogist, 57, 76–84. *Mineral Data Publishing, 2001, “Kanoite.” http://rruff.geo.arizona.edu/doclib/hom/kanoite.pdf. Accessed 21 October 2010. *Ralph, Jolyon and Chau, Ida, 5 November 2010, “Kanoite.” http://www.mindat.org/min-2154.html. Accessed 1 November 2010. *Barthelmy, David, 1997-2010, “Kanoite Mineral Data.” http://www.webmineral.com/data/Kanoite.shtml. Accessed 7 November 2010. *Weisstein, Eric, 1996-2007, “Birefringence.” http://scienceworld.wolfram.com/physics/Birefringence.html. Accessed 7 November 2010. Inosilicates Magnesium minerals Manganese(II) minerals Monoclinic minerals Minerals in space group 14 Pyroxene group