Efimov state
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The Efimov effect is an effect in the
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistr ...
of few-body systems predicted by the Russian
theoretical physicist Theoretical physics is a branch of physics that employs mathematical models and abstractions of physical objects and systems to rationalize, explain and predict natural phenomena. This is in contrast to experimental physics, which uses experime ...
V. N. Efimov in 1970. Efimov’s effect is where three identical
boson In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer spi ...
s interact, with the prediction of an infinite series of excited three-body energy levels when a two-body state is exactly at the dissociation threshold. One corollary is that there exist bound states (called Efimov states) of three bosons even if the two-particle attraction is too weak to allow two bosons to form a pair. A (three-particle) Efimov state, where the (two-body) sub-systems are unbound, is often depicted symbolically by the
Borromean rings In mathematics, the Borromean rings are three simple closed curves in three-dimensional space that are topologically linked and cannot be separated from each other, but that break apart into two unknotted and unlinked loops when any one of the t ...
. This means that if one of the particles is removed, the remaining two fall apart. In this case, the Efimov state is also called a Borromean state.


Theory

Efimov predicted that, as the pair interactions among three identical bosons approach resonance—that is, as the binding energy of some two-body bound state approaches zero or the
scattering length The scattering length in quantum mechanics describes low-energy scattering. For potentials that decay faster than 1/r^3 as r\to \infty, it is defined as the following low-energy limit (mathematics), limit: : \lim_ k\cot\delta(k) =- \frac\;, wher ...
of such a state becomes infinite—the three-body
spectrum A spectrum (plural ''spectra'' or ''spectrums'') is a condition that is not limited to a specific set of values but can vary, without gaps, across a continuum. The word was first used scientifically in optics to describe the rainbow of colors ...
exhibits an infinite sequence of bound states N=0,1,2,\ldots whose scattering lengths a_ and binding energies E_N each form a
geometric progression In mathematics, a geometric progression, also known as a geometric sequence, is a sequence of non-zero numbers where each term after the first is found by multiplying the previous one by a fixed, non-zero number called the ''common ratio''. For ex ...
:a_=a_0\lambda^N :E_=E_0\lambda^ where the common ratio :\lambda=\mathrm^=22.69438\ldots is a universal constant (OEIS ). Here :s_0=1.0062378\ldots is the order of th
imaginary-order modified Bessel function
of the second kind \tilde_(r/a) that describes the radial dependence of the wavefunction. By virtue of the resonance-determined boundary conditions, it is the unique positive value of s satisfying the transcendental equation :-s\cosh\left.\tfrac\right.+\tfrac\sinh\left.\tfrac\right.=0.


Experimental results

In 2005, for the first time the research group of
Rudolf Grimm Rudolf Grimm (born 10 November 1961) is an experimental physicist from Austria. His work centres on ultracold atoms and quantum gases. He was the first scientist worldwide who, with his team, succeeded in realizing a Bose–Einstein condensation ...
and Hanns-Christoph Nägerl from the Institute for Experimental Physics at the University of Innsbruck experimentally confirmed such a state in an ultracold gas of caesium atoms. In 2006, they published their findings in the scientific journal Nature. Further experimental proof for the existence of the Efimov state has been given recently by independent groups. Almost 40 years after Efimov's purely theoretical prediction, the characteristic periodic behavior of the states has been confirmed. The most accurate experimental value of the scaling factor of the states has been determined by the experimental group of Rudolf Grimm at Innsbruck University as 21.0(1.3), being very close to Efimov's original prediction. The interest in the "universal phenomena" of cold atomic gases is still growing, especially because of the long-awaited experimental results. The discipline of universality in cold atomic gases near the Efimov states is sometimes referred to as "Efimov physics". In 2014, the experimental group of Cheng Chin of the
University of Chicago The University of Chicago (UChicago, Chicago, U of C, or UChi) is a private university, private research university in Chicago, Illinois. Its main campus is located in Chicago's Hyde Park, Chicago, Hyde Park neighborhood. The University of Chic ...
and the group of Matthias Weidemüller of the
University of Heidelberg } Heidelberg University, officially the Ruprecht Karl University of Heidelberg, (german: Ruprecht-Karls-Universität Heidelberg; la, Universitas Ruperto Carola Heidelbergensis) is a public research university in Heidelberg, Baden-Württemberg, ...
have observed Efimov states in an ultracold mixture of
lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid ...
and caesium atoms, which extends Efimov's original picture of three identical bosons. An Efimov state existing as an excited state of a helium trimer was observed in an experiment in 2015.{{cite journal, last1=Kunitski, first1=Maksim, last2=Zeller, first2=Stefan, last3=Voigtsberger, first3=Jörg, last4=Kalinin, first4=Anton, last5= Schmidt, first5=Lothar Ph. H., last6=Schöffler, first6=Markus, last7=Czasch, first7=Achim, last8=Schöllkopf, first8=Wieland, last9=Grisenti, first9=Robert E., last10=Jahnke, first10=Till, last11=Blume, first11=Dörte, last12=Dörner, first12=Reinhard, title=Observation of the Efimov state of the helium trimer , journal=Science, date=May 2015, volume=348, issue=6234, pages=551–555, doi=10.1126/science.aaa5601, pmid=25931554, arxiv=1512.02036, bibcode=2015Sci...348..551K, s2cid=206635093


Usage

The Efimov states are independent of the underlying physical interaction and can in principle be observed in all quantum mechanical systems (i.e. molecular, atomic, and nuclear). The states are very special because of their "non-classical" nature: The size of each three-particle Efimov state is much larger than the force-range between the individual particle pairs. This means that the state is purely quantum mechanical. Similar phenomena are observed in two-neutron halo-nuclei, such as lithium-11; these are called Borromean nuclei. (Halo nuclei could be seen as special Efimov states, depending on the subtle definitions.)


See also

* Three-body force


References


External links


Press release about the experimental confirmation (2006.03.16)


* ttp://journals.aps.org/prl/abstract/10.1103/PhysRevLett.112.190401 Observation of the Second Triatomic Resonance in Efimov’s Scenario (2014.05.15) Quantum mechanics