Copper-silver ionization
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Copper-silver ionization is a disinfection process, primarily used to control ''
Legionella ''Legionella'' is a genus of pathogenic gram-negative bacteria that includes the species '' L. pneumophila'', causing legionellosis (all illnesses caused by ''Legionella'') including a pneumonia-type illness called Legionnaires' disease and a mil ...
'', the bacteria responsible for Legionnaires' disease. There is strong evidence that treating water supplies in hospitals with this technique decreases the risk.


Effectiveness

Ionization can be an effective process to control ''Legionella'' in potable water distribution systems found in health facilities, hotels, nursing homes, and large buildings. In 2003, ionization became the first such hospital disinfection process to have fulfilled a proposed four-step modality evaluation; by then it had been adopted by over 100 hospitals. "(1) Demonstrated efficacy of ''Legionella'' eradication in vitro using laboratory assays, (2) anecdotal experiences in preventing legionnaires' disease in individual hospitals, (3) controlled studies in individual hospitals, and (4) validation in confirmatory reports from multiple hospitals during a prolonged time." Additional studies indicate ionization is superior to thermal eradication. A 2011 review found copper-silver ionization to be the only Legionella control technology which has been validated through a proposed four-step modality evaluation (need reference or description of "modality" in this context since it does not apply in all situations).


Guidelines

Copper-silver ionization technology is recognized by the World Health Organization (WHO), the
U.S. Environmental Protection Agency The Environmental Protection Agency (EPA) is an Independent agencies of the United States government, independent executive agency of the United States federal government tasked with environmental protection matters. President Richard Nixon pro ...
(EPA) to control ''
Legionella ''Legionella'' is a genus of pathogenic gram-negative bacteria that includes the species '' L. pneumophila'', causing legionellosis (all illnesses caused by ''Legionella'') including a pneumonia-type illness called Legionnaires' disease and a mil ...
'' within potable water distribution networks found in hospitals, hotels and other large type facilities. The level of ions generated has been reported to be usually below EPA Safe Water Drinking Act Lead and Copper Rule AL for copper. The AL for copper in potable water is 1.3 ppm (Cu) and the SCL for silver is 0.1 ppm (Ag) (which is the same as 100 ppb). It is important to collect and handle samples correctly in order to get accurate results. Suboptimal timing of specimen shipment for testing at reference laboratories may contribute to silver concentration above recommendations. Industry leaders who manufacture copper-silver ionization technology recommend a copper concentration of 0.2 to 0.8 ppm and a silver concentration of 10 to 80 ppb, which are compliant with EPA drinking water standards.


Europe

The British Health and Safety Commission regulates U.K. ionization, advising regular system monitoring to ensure ions reach all water circuits. Also, copper in drinking water is limited to 2 ppm (mg/L) by the
European Community The European Economic Community (EEC) was a regional organization created by the Treaty of Rome of 1957,Today the largely rewritten treaty continues in force as the ''Treaty on the functioning of the European Union'', as renamed by the Lisb ...
whereas ''Legionella'' control only requires 0.2 to 0.8 ppm in concentration...well below the permissible limits. Headquarters (ECH) in
Brussels Brussels (french: Bruxelles or ; nl, Brussel ), officially the Brussels-Capital Region (All text and all but one graphic show the English name as Brussels-Capital Region.) (french: link=no, Région de Bruxelles-Capitale; nl, link=no, Bruss ...
, Belgium, and silver is not prescribed by the ECH. The EU limits copper to 1.0 ppm—lower than the USA copper AL of 1.3 ppm. The EU does not have any guidelines for ionic silver concentrations—the US SCL is 0.1 ppm (100 ppb). In February 2012, the European Commission issued a non-inclusion decision regarding the use of copper as a biocide in Europe. This decision was based on a failure of industry to supply the commission with required information regarding copper and was not based on health or efficacy concerns. In response to this decision, five member states—Spain, the UK, Norway, Poland, and the Netherlands—have applied to the commission to allow for the continued use of copper as a biocide in their respective nations. In addition, the UK authority, the HSE, has issued a statement stating that the derogation application for the UK has been informally granted. Industry has responded by forming a Taskforce to ensure full and long term compliance with the regulatory issues facing copper in the EU.


Process

Copper-silver ionization disperses positively charged
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
and
silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
s into the water system. The ions bond
electrostatic Electrostatics is a branch of physics that studies electric charges at rest ( static electricity). Since classical times, it has been known that some materials, such as amber, attract lightweight particles after rubbing. The Greek word for amb ...
ally with negative sites on bacterial cell walls and denature proteins. Over the long term, the presence of copper and silver ions destroy
biofilm A biofilm comprises any syntrophic consortium of microorganisms in which cells stick to each other and often also to a surface. These adherent cells become embedded within a slimy extracellular matrix that is composed of extracellular ...
s and slimes that can harbor ''
Legionella ''Legionella'' is a genus of pathogenic gram-negative bacteria that includes the species '' L. pneumophila'', causing legionellosis (all illnesses caused by ''Legionella'') including a pneumonia-type illness called Legionnaires' disease and a mil ...
'', the bacteria responsible for Legionnaires' disease (legionellosis). It can take 30 to 45 days for the copper and silver ions to penetrate a biofilm. Flow cells (part of the ionization unit) should be cleaned periodically to maintain the system. In a hospital that is not defined as a public water system, this task may be delegated to the facility's utility engineers. If a hospital is defined as a public water system, the maintenance personnel may be required to have a State-issued water treatment license. In the US, different states have specific regulations for hospitals and drinking water treatment that should be reviewed before going forward with installation of copper-silver ionization.
Forensic scientist Forensic science, also known as criminalistics, is the application of science to criminal and civil laws, mainly—on the criminal side—during criminal investigation, as governed by the legal standards of admissible evidence and criminal ...
Randy Fornshell of the Sedgwick County Regional Forensic Science Center explains that copper-silver ionization is a modern implementation of the
ancient Greek Ancient Greek includes the forms of the Greek language used in ancient Greece and the ancient world from around 1500 BC to 300 BC. It is often roughly divided into the following periods: Mycenaean Greek (), Dark Ages (), the Archaic p ...
practice of reducing bacteria in wine vessels by lining them with silver, and controlling algae and fungi with copper. Fornshell notes that copper-silver ionization has been effective in swimming pools (it is an alternative to chlorine) and is becoming adopted by larger municipalities. Replacing chlorination with copper-silver ionization to keep water safe was one response of Frederick Memorial Hospital,
Frederick, Maryland Frederick is a city in and the county seat of Frederick County, Maryland. It is part of the Baltimore–Washington Metropolitan Area. Frederick has long been an important crossroads, located at the intersection of a major north–south Native ...
, to new requirements in the 2001 ''Guidelines for Design and Construction of Hospital and Healthcare Facilities'', issued by the
American Institute of Architects The American Institute of Architects (AIA) is a professional organization for architects in the United States. Headquartered in Washington, D.C., the AIA offers education, government advocacy, community redevelopment, and public outreach to su ...
. Ionization is in many cases installed because more convenient and cost-effective than other approaches. This implies that Maryland does not identify systems that post-treat potable water as public water systems and require them to maintain a residual of chlorine or chloramine in their distribution system, as required for treated surface water in the Safe Drinking Water Act.


Regulations

It is possible to operate copper-silver ionization without exceeding the copper Action Level (AL) and silver secondary maximum contaminant levels (SMCLs) set by the
U.S. Environmental Protection Agency The Environmental Protection Agency (EPA) is an Independent agencies of the United States government, independent executive agency of the United States federal government tasked with environmental protection matters. President Richard Nixon pro ...
in the Safe Water Drinking Act's Lead and Copper Rule (Title 40, Code of Federal Regulations, 40 CFR) in Part 141, Subpart I; and 40 CFR Part 143, respectively.


See also

* Occupational hygiene


References

{{Reflist Bacterial diseases Industrial hygiene