Chaoite, or white carbon, is a

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...

described as an allotrope of

carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon mak ...

whose existence is disputed. It was discovered in shock-fused graphite

gneiss Gneiss ( ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. Gneiss forms at higher temperatures a ...

from the

Ries Ries is the German word for a unit of paper ream, derived from the Arabic word ''rizma''. The term can refer to: Geography * Nördlinger Ries, a large circular depression in western Bavaria, Germany. * Ries (Graz), a district of the city of Gr ...

crater in Bavaria. It has been described as slightly harder than graphite, with a reflection colour of grey to white. From its electron diffraction pattern, the mineral has been considered to have a

carbyne In organic chemistry, a carbyne is a general term for any compound whose structure consists of an electrically neutral carbon atom connected by a single covalent bond and has three non-bonded electrons. The carbon atom has either one or thre ...

structure, the

linear acetylenic carbon Linear acetylenic carbon (LAC), also known as carbyne or Linear Carbon Chain (LCC), is an allotrope of carbon that has the chemical structure as a repeat unit, with alternating single and triple bonds. It would thus be the ultimate member of t ...

allotrope of carbon. A later report has called this identification, and the very existence of carbyne phases, into question, arguing that the new reflections in the diffraction pattern are due to clay impurities.

Synthetic material

It has been claimed that an identical form can be prepared from graphite by sublimation at 2700-3000 K or by irradiating it with a laser in high vacuum. This substance has been termed ''ceraphite''. A review cautions that "in spite of these seemingly definitive reports … several other groups have tried unsuccessfully to reproduce these experiments. Independent confirmatory work is obviously needed … and at the present time white graphite appears to be the carbon analog of

polywater Polywater was a hypothesized polymerized form of water that was the subject of much scientific controversy during the late 1960s. By 1969 the popular press had taken notice and sparked fears of a "polywater gap" in the US. Increased press attent ...

".D.W. McKee, Annu. Rev. Mater. Sci. 1973, 3, 195

Occurrence and discovery

Chaoite was first described from Möttingen, Ries Crater,

Nördlingen Nördlingen (; Swabian: ''Nearle'' or ''Nearleng'') is a town in the Donau-Ries district, in Swabia, Bavaria, Germany, with a population of approximately 20,674. It is located approximately east of Stuttgart, and northwest of Munich. It was b ...

Bavaria Bavaria ( ; ), officially the Free State of Bavaria (german: Freistaat Bayern, link=no ), is a state in the south-east of Germany. With an area of , Bavaria is the largest German state by land area, comprising roughly a fifth of the total lan ...

, Germany and approved by the IMA in 1969. The mineral was named for USGS petrologist Edward C. T. Chao (1919-2008). At the type locality in Bavaria chaoite occurs in graphite bearing

that has undergone

shock metamorphism Shock metamorphism or impact metamorphism describes the effects of shock-wave related deformation and heating during impact events. The formation of similar features during explosive volcanism is generally discounted due to the lack of metamorp ...

. It has also been reported from meteorites including the Goalpara meteorite in

Assam Assam (; ) is a state in northeastern India, south of the eastern Himalayas along the Brahmaputra and Barak River valleys. Assam covers an area of . The state is bordered by Bhutan and Arunachal Pradesh to the north; Nagaland and Manipur ...

, the Dyalpur meteorite in

Uttar Pradesh Uttar Pradesh (; , 'Northern Province') is a state in northern India. With over 200 million inhabitants, it is the most populated state in India as well as the most populous country subdivision in the world. It was established in 1950 ...

India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...

and the

Popigai impact structure The Popigai impact structure is the eroded remnant of an impact crater in northern Siberia, Russia. It is tied with the Manicouagan structure as the fourth largest verified impact structure on Earth. A large bolide impact created the diameter ...

in the Anabarskii massif of Eastern

Siberia Siberia ( ; rus, Сибирь, r=Sibir', p=sʲɪˈbʲirʲ, a=Ru-Сибирь.ogg) is an extensive region, geographical region, constituting all of North Asia, from the Ural Mountains in the west to the Pacific Ocean in the east. It has been a ...

. Minerals associated with chaoite include: graphite,

zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of t ...

rutile Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at visib ...

, pseudobrookite,

magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With th ...

, nickeliferous

pyrrhotite Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S (x = 0 to 0.2). It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it i ...

and baddeleyite.

Synthetic material

Occurrence and discovery

See also

References

Further reading