Baddeleyite
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Baddeleyite
Baddeleyite is a rare zirconium oxide mineral (ZrO2 or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown. See etymology below. Baddeleyite is a refractory mineral, with a melting point of 2700 °C. Hafnium is a substituting ''impurity'' and may be present in quantities ranging from 0.1 to several percent. It can be found in igneous rocks containing potassium feldspar and plagioclase. Baddeleyite is commonly not found with zircon (ZrSiO4), because it forms in silica-undersaturated rocks, such as mafic rocks. This is because, when silica is free in the system (silica-saturated/oversaturated), zircon is the dominating phase, not baddeleyite. It belongs to the monoclinic-prismatic class, of the P21/c crystal system. It has been used for geochronology. Geologic occurrence Baddeleyite was first found in Sri Lanka in 1892. It can b ...
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Baddeleyite
Baddeleyite is a rare zirconium oxide mineral (ZrO2 or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown. See etymology below. Baddeleyite is a refractory mineral, with a melting point of 2700 °C. Hafnium is a substituting ''impurity'' and may be present in quantities ranging from 0.1 to several percent. It can be found in igneous rocks containing potassium feldspar and plagioclase. Baddeleyite is commonly not found with zircon (ZrSiO4), because it forms in silica-undersaturated rocks, such as mafic rocks. This is because, when silica is free in the system (silica-saturated/oversaturated), zircon is the dominating phase, not baddeleyite. It belongs to the monoclinic-prismatic class, of the P21/c crystal system. It has been used for geochronology. Geologic occurrence Baddeleyite was first found in Sri Lanka in 1892. It can b ...
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Zirconia
Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant. Production, chemical properties, occurrence Zirconia is produced by calcining zirconium compounds, exploiting its high thermostability.Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. Structure Three phases are known: monoclinic below 1170 °C, tetragonal between 1170 °C and 2370 °C, and cubic above 2370 °C. The trend is for higher symmetry at higher temperatures, as is usually the case. A small percentage of the oxides of calcium or yttrium stabilize in the cubic phase. The very rare mineral tazheranite, , ...
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Carbonatite
Carbonatite () is a type of intrusive rock, intrusive or extrusive rock, extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geochemical verification. Carbonatites usually occur as small volcanic plug, plugs within zoned alkalic intrusive complexes, or as dike (geology), dikes, sill (geology), sills, breccias, and vein (geology), veins. They are almost exclusively associated with continental rift-related tectonic settings. It seems that there has been a steady increase in the carbonatitic igneous activity through the Earth's history, from the Archean Eon (geology), eon to the present. Nearly all carbonatite occurrences are intrusives or subvolcanic rock, subvolcanic intrusives. This is because carbonatite lava flows, being composed largely of soluble carbonates, are easily weathered and are therefore unlikely to be preserved in the geologic record. Carbonatite erupti ...
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Zirconium Dioxide
Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant. Production, chemical properties, occurrence Zirconia is produced by calcining zirconium compounds, exploiting its high thermostability.Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. Structure Three phases are known: monoclinic below 1170 °C, tetragonal between 1170 °C and 2370 °C, and cubic above 2370 °C. The trend is for higher symmetry at higher temperatures, as is usually the case. A small percentage of the oxides of calcium or yttrium stabilize in the cubic phase. The very rare mineral tazheranite, , ...
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Tektite
Tektites (from grc, τηκτός , meaning 'molten') are gravel-sized bodies composed of black, green, brown or grey natural glass formed from terrestrial debris ejected during meteorite impacts. The term was coined by Austrian geologist Franz Eduard Suess (1867–1941), son of Eduard Suess. They generally range in size from millimetres to centimetres. Millimetre-scale tektites are known as microtektites.French, B. M. (1998) ''Traces of Catastrophe: A Handbook of Shock-Metamorphic Effects in Terrestrial Meteorite Impact Structures.'' LPI Contribution No. 954. Lunar and Planetary Institute, Houston, Texas. 120 pp.McCall, G. J. H. (2001) ''Tektites in the Geological Record: Showers of Glass from the Sky.'' The Geological Society Publishing House, Bath, United Kingdom. 256 pp. Montanari, A., and C. Koeberl (2000) ''Impact Stratigraphy. The Italian Record.'' Lecture Notes in Earth Sciences Series no. 93. Springer-Verlag, New York, New York. 364 pp. Tektites are characterized by: # ...
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Zirconium
Zirconium is a chemical element with the symbol Zr and atomic number 40. The name ''zirconium'' is taken from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian '' zargun'' (zircon; ''zar-gun'', "gold-like" or "as gold"). It is a lustrous, grey-white, strong transition metal that closely resembles hafnium and, to a lesser extent, titanium. Zirconium is mainly used as a refractory and opacifier, although small amounts are used as an alloying agent for its strong resistance to corrosion. Zirconium forms a variety of inorganic and organometallic compounds such as zirconium dioxide and zirconocene dichloride, respectively. Five isotopes occur naturally, four of which are stable. Zirconium compounds have no known biological role. Characteristics Zirconium is a lustrous, greyish-white, soft, ductile, malleable metal that is solid at room temperature, though it is hard and brittle at lesser purities. In powder form, zirconium is highl ...
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Anorthosite
Anorthosite () is a phaneritic, intrusive igneous rock characterized by its composition: mostly plagioclase feldspar (90–100%), with a minimal mafic component (0–10%). Pyroxene, ilmenite, magnetite, and olivine are the mafic minerals most commonly present. Anorthosites are of enormous geologic interest, because it is still not fully understood how they form. Most models involve separating plagioclase crystals based on their density. Plagioclase crystals are usually less dense than magma; so, as plagioclase crystallizes in a magma chamber, the plagioclase crystals float to the top, concentrating there. Anorthosite on Earth can be divided into five types: # Archean-age anorthosites # Proterozoic anorthosite (also known as massif or massif-type anorthosite) – the most abundant type of anorthosite on Earth # Layers within Layered Intrusions (e.g., Bushveld and Stillwater intrusions) # Mid-ocean ridge and transform fault anorthosites # Anorthosite xenoliths in other rocks ...
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Sill (geology)
In geology, a sill is a tabular sheet intrusion that has intruded between older layers of sedimentary rock, beds of volcanic lava or tuff, or along the direction of foliation in metamorphic rock. A ''sill'' is a ''concordant intrusive sheet'', meaning that a sill does not cut across preexisting rock beds. Stacking of sills builds a sill complex . and a large magma chamber at high magma flux. In contrast, a dike is a discordant intrusive sheet, which does cut across older rocks. Sills are fed by dikes, except in unusual locations where they form in nearly vertical beds attached directly to a magma source. The rocks must be brittle and fracture to create the planes along which the magma intrudes the parent rock bodies, whether this occurs along preexisting planes between sedimentary or volcanic beds or weakened planes related to foliation in metamorphic rock. These planes or weakened areas allow the intrusion of a thin sheet-like body of magma paralleling the existing bedding pla ...
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Gabbro
Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is chemically equivalent to rapid-cooling, fine-grained basalt. Much of the Earth's oceanic crust is made of gabbro, formed at mid-ocean ridges. Gabbro is also found as plutons associated with continental volcanism. Due to its variant nature, the term ''gabbro'' may be applied loosely to a wide range of intrusive rocks, many of which are merely "gabbroic". By rough analogy, gabbro is to basalt as granite is to rhyolite. Etymology The term "gabbro" was used in the 1760s to name a set of rock types that were found in the ophiolites of the Apennine Mountains in Italy. It was named after Gabbro, a hamlet near Rosignano Marittimo in Tuscany. Then, in 1809, the German geologist Christian Leopold von Buch used the term more restrictively in his descri ...
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Crystal System
In crystallography, a crystal system is a set of point groups (a group of geometric symmetries with at least one fixed point). A lattice system is a set of Bravais lattices. Space groups are classified into crystal systems according to their point groups, and into lattice systems according to their Bravais lattices. Crystal systems that have space groups assigned to a common lattice system are combined into a crystal family. The seven crystal systems are triclinic, monoclinic, orthorhombic, tetragonal, trigonal, hexagonal, and cubic. Informally, two crystals are in the same crystal system if they have similar symmetries (albeit there are many exceptions). Classifications Crystals can be classified in three ways: lattice systems, crystal systems and crystal families. The various classifications are often confused: in particular the trigonal crystal system is often confused with the rhombohedral lattice system, and the term "crystal system" is sometimes used to mean "latti ...
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Dike (geology)
A dike or dyke, in Geology, geological usage, is a sheet of rock that is formed in a Fracture (geology), fracture of a pre-existing rock body. Dikes can be either Intrusive rock, magmatic or Sedimentary rock, sedimentary in origin. Magmatic dikes form when magma flows into a crack then solidifies as a sheet intrusion, either cutting across layers of rock or through a contiguous mass of rock. Clastic dikes are formed when sediment fills a pre-existing crack.Essentials of Geology, 3rd Ed, Stephen Marshak Magmatic dikes A magmatic dike is a sheet of igneous rock that cuts across older rock beds. It is formed when magma fills a fracture in the older beds and then cools and solidifies. The dike rock is usually more resistant to weathering than the surrounding rock, so that erosion exposes the dike as a natural wall or ridge. It is from these natural walls that dikes get their name. Dikes preserve a record of the fissures through which most mafic magma (fluid magma low in silica) reac ...
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Diabase
Diabase (), also called dolerite () or microgabbro, is a mafic, holocrystalline, subvolcanic rock equivalent to volcanic basalt or plutonic gabbro. Diabase dikes and sills are typically shallow intrusive bodies and often exhibit fine-grained to aphanitic chilled margins which may contain tachylite (dark mafic glass). ''Diabase'' is the preferred name in North America, while ''dolerite'' is the preferred name in the rest of the English-speaking world, where sometimes the name ''diabase'' refers to altered dolerites and basalts. Some geologists prefer to avoid confusion by using the name ''microgabbro''. The name ''diabase'' comes from the French ', and ultimately from the Greek - meaning "act of crossing over, transition". Petrography Diabase normally has a fine but visible texture of euhedral lath-shaped plagioclase crystals (62%) set in a finer matrix of clinopyroxene, typically augite (20–29%), with minor olivine (3% up to 12% in olivine diabase), magnetite (2%), an ...
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