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Isentropic Process
In thermodynamics, an isentropic process is an idealized thermodynamic process that is both adiabatic and reversible. The work transfers of the system are frictionless, and there is no transfer of heat or matter. Such an idealized process is useful in engineering as a model of and basis of comparison for real processes.
The word 'isentropic' is occasionally, though not customarily, interpreted in another way, reading it as if its meaning were deducible from its etymology. This is contrary to its original and customarily used definition
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Chemical Potential
In thermodynamics, chemical potential of a species, is a form of energy that can be absorbed or released during a chemical reaction or phase transition due to a change of the particle number of the given species. The chemical potential of a species in a mixture is defined as the rate of change of a free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system. Thus, it is the partial derivative of the free energy with respect to the amount of the species, all other species' concentrations in the mixture remaining constant. The molar chemical potential is also known as partial molar free energy. When both temperature and pressure are held constant, chemical potential is the partial molar Gibbs free energy
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Statistical Mechanics
Statistical mechanics is a branch of theoretical physics that uses
Probability
Probability theory">probability theory to study the average behaviour of a mechanical system whose exact state is uncertain. Statistical mechanics
Statistical mechanics is commonly used to explain the thermodynamic behaviour of large systems. This branch of statistical mechanics, which treats and extends classical thermodynamics, is known as statistical thermodynamics or equilibrium statistical mechanics. Microscopic mechanical laws do not contain concepts such as temperature, heat, or entropy; however, statistical mechanics shows how these concepts arise from the natural uncertainty about the state of a system when that system is prepared in practice
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Chemical Thermodynamics
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics.
Chemical thermodynamics
Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the spontaneity of processes.
The structure of chemical thermodynamics is based on the first two laws of thermodynamics. Starting from the first and second laws of thermodynamics, four equations called the "fundamental equations of Gibbs" can be derived. From these four, a multitude of equations, relating the thermodynamic properties of the thermodynamic system can be derived using relatively simple mathematics
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Quantum Thermodynamics
is the study of the relations between two independent physical theories: thermodynamics and
Quantum thermodynamicsQuantum mechanics">quantum mechanics. The two independent theories address the physical phenomena of light and matter. In 1905 Einstein argued that the requirement of consistency between thermodynamics and electromagnetism leads to the conclusion that light is quantized obtaining the relation . This paper is the dawn of quantum theory. In a few decades quantum theory became established with an independent set of rules. Currently quantum thermodynamics addresses the emergence of thermodynamic laws from quantum mechanics. It differs from
Quantum statistical mechanics">quantum statistical mechanics in the emphasis on dynamical processes out of equilibrium
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Heat
In thermodynamics, heat refers to energy that is transferred from a warmer substance or object to a cooler one
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State Of Matter
In physics, a state of matter is one of the distinct forms in which matter can exist. Four states of matter are observable in everyday life: solid, liquid, gas, and plasma. Many other states are known to exist, such as glass or
Liquid
Liquid crystal">liquid crystal, and some only exist under extreme conditions, such as Bose–Einstein condensates, neutron-degenerate matter, and quark-gluon plasma, which only occur, respectively, in situations of extreme cold, extreme density, and extremely high-energy. Some other states are believed to be possible but remain theoretical for now. For a complete list of all exotic states of matter, see the list of states of matter. Historically, the distinction is made based on qualitative differences in properties. Matter
Matter in the solid state maintains a fixed volume and shape, with component particles (atoms, molecules or ions) close together and fixed into place [...More...] |
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Real Gas
Real gases are non-hypothetical gases whose molecules occupy space and have interactions; consequently, they adhere to gas laws. To understand the behaviour of real gases, the following must be taken into account:
For most applications, such a detailed analysis is unnecessary, and the ideal gas approximation can be used with reasonable accuracy. On the other hand, real-gas models have to be used near the condensation point of gases, near critical points, at very high pressures, to explain the Joule–Thomson effect and in other less usual cases
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Heat Pump And Refrigeration Cycle
Thermodynamic heat pump cycles or refrigeration cycles are the conceptual and mathematical models for heat pumps and refrigerators. A heat pump is a machine or device that moves heat from one location (the "source") at a lower temperature to another location (the "sink" or "heat sink") at a higher temperature using mechanical work or a high-temperature heat source. Thus a heat pump may be thought of as a "heater" if the objective is to warm the heat sink (as when warming the inside of a home on a cold day), or a "refrigerator" if the objective is to cool the heat source (as in the normal operation of a freezer)
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Pressure
Pressure (symbol: p or P) is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled gage pressure) is the pressure relative to the ambient pressure.
Various units are used to express pressure. Some of these derive from a unit of force divided by a unit of area; the SI unit of pressure, the pascal (Pa), for example, is one newton per square metre; similarly, the pound-force per square inch (psi) is the traditional unit of pressure in the imperial and US customary systems.
Pressure
Pressure may also be expressed in terms of standard atmospheric pressure; the Atmosphere
Atmosphere (unit)">atmosphere (atm) is equal to this pressure, and the torr is defined as 1--->⁄ _{760} of this
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Reversible Process (thermodynamics)
In thermodynamics, a reversible process is a process whose direction can be "reversed" by inducing infinitesimal changes to some property of the system via its surroundings, with no increase in entropy. Throughout the entire reversible process, the system is in thermodynamic equilibrium with its surroundings. Since it would take an infinite amount of time for the reversible process to finish, perfectly reversible processes are impossible. However, if the system undergoing the changes responds much faster than the applied change, the deviation from reversibility may be negligible. In a reversible cycle, a cyclical reversible process, the system and its surroundings will be returned to their original states if one half cycle is followed by the other half cycle.
Thermodynamic processes can be carried out in one of two ways: reversibly or irreversibly. Reversibility means the reaction operates continuously at equilibrium
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Irreversible Process
In science, a process that is not reversible is called irreversible. This concept arises frequently in thermodynamics.
In thermodynamics, a change in the thermodynamic state of a system and all of its surroundings cannot be precisely restored to its initial state by infinitesimal changes in some property of the system without expenditure of energy. A system that undergoes an irreversible process may still be capable of returning to its initial state. However, the impossibility occurs in restoring the environment to its own initial conditions. An irreversible process increases the entropy of the universe. Because entropy is a state function, the change in entropy of the system is the same, whether the process is reversible or irreversible
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Conjugate Variables (thermodynamics)
In thermodynamics, the internal energy of a system is expressed in terms of pairs of conjugate variables such as temperature and entropy or pressure and volume. In fact, all thermodynamic potentials are expressed in terms of conjugate pairs. The product of two quantities that are conjugate has units of energy or sometimes power.
For a mechanical system, a small increment of energy is the product of a force times a small displacement. A similar situation exists in thermodynamics. An increment in the energy of a thermodynamic system can be expressed as the sum of the products of certain generalized "forces" that, when unbalanced, cause certain generalized "displacements", and the product of the two is the energy transferred as a result. These forces and their associated displacements are called conjugate variables. The thermodynamic force is always an intensive variable and the displacement is always an extensive variable, yielding an extensive energy transfer
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