star garnet
   HOME

TheInfoList



OR:

Garnets () are a group of silicate minerals that have been used since the Bronze Age as
gemstone A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...
s and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in
chemical composition A chemical composition specifies the identity, arrangement, and ratio of the elements making up a compound. Chemical formulas can be used to describe the relative amounts of elements present in a compound. For example, the chemical formula for ...
. The different species are pyrope,
almandine Almandine (), also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia M ...
,
spessartine Spessartine is a nesosilicate, manganese aluminium garnet species, Mn2+3Al2(SiO4)3.Gemological Institute of America, ''GIA Gem Reference Guide'' 1995, This mineral is sometimes mistakenly referred to as ''spessartite''. Spessartine's name is a ...
, grossular (varieties of which are hessonite or cinnamon-stone and tsavorite), uvarovite and
andradite Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12. Andradite includes three varieties: * ''Melanite'': Black in color, referred to as "titanian andradite".solid solution series: pyrope-almandine-spessartine (pyralspite), with the composition range ; and uvarovite-grossular-andradite (ugrandite), with the composition range .


Etymology

The word ''garnet'' comes from the 14th-century Middle English word ''gernet'', meaning 'dark red'. It is borrowed from Old French ''grenate'' from Latin ''granatus,'' from ''granum'' ('grain, seed'). This is possibly a reference to ''mela granatum'' or even ''pomum granatum'' (' pomegranate', ''Punica granatum''), a plant whose fruits contain abundant and vivid red seed covers (
aril An aril (pronounced ), also called an arillus, is a specialized outgrowth from a seed that partly or completely covers the seed. An arillode or false aril is sometimes distinguished: whereas an aril grows from the attachment point of the see ...
s), which are similar in shape, size, and color to some garnet crystals.


Physical properties


Properties

Garnet species are found in every colour, with reddish shades most common. Blue garnets are the rarest and were first reported in the 1990s. Garnet species' light transmission properties can range from the gemstone-quality transparent specimens to the opaque varieties used for industrial purposes as abrasives. The mineral's luster is categorized as
vitreous Vitreous may refer to: Materials * Glass, an amorphous solid material ** Vitreous enamel, a material made by fusing powdered glass to a substrate by firing * Vitreous lustre, a glassy luster or sheen on a mineral surface Biology * Vitreous body, ...
(glass-like) or resinous (amber-like).


Crystal structure

Garnets are nesosilicates having the general formula ''X''3''Y''2()3. The ''X'' site is usually occupied by divalent cations ( Ca, Mg, Fe, Mn)2+ and the ''Y'' site by trivalent cations ( Al, Fe, Cr)3+ in an octahedral/ tetrahedral framework with iO4sup>4− occupying the tetrahedra. Garnets are most often found in the dodecahedral
crystal habit In mineralogy, crystal habit is the characteristic external shape of an individual crystal or crystal group. The habit of a crystal is dependent on its crystallographic form and growth conditions, which generally creates irregularities due to l ...
, but are also commonly found in the trapezohedron habit as well as the hexoctahedral habit. They crystallize in the
cubic Cubic may refer to: Science and mathematics * Cube (algebra), "cubic" measurement * Cube, a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex ** Cubic crystal system, a crystal system w ...
system, having three axes that are all of equal length and perpendicular to each other, but are never actually cubic because, despite being isometric, the and families of planes are depleted. Garnets do not have any cleavage planes, so when they fracture under stress, sharp, irregular (
conchoidal Conchoidal fracture describes the way that brittle materials break or fracture when they do not follow any natural planes of separation. Mindat.org defines conchoidal fracture as follows: "a fracture with smooth, curved surfaces, typically sli ...
) pieces are formed. File:Pyrope cp.jpg, Crystal structure of pyrope garnet. White spheres are oxygen; black, silicon; blue, aluminium; and red, magnesium. File:Pyrope crystal structure.jpg, Same view, with ion sizes reduced to better show all ions File:Pyrope si.jpg, Silicon ion size exaggerated to emphasize silica tetrahedra


Hardness

Because the chemical composition of garnet varies, the atomic bonds in some species are stronger than in others. As a result, this mineral group shows a range of hardness on the
Mohs scale The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by th ...
of about 6.0 to 7.5. The harder species like
almandine Almandine (), also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia M ...
are often used for abrasive purposes.


Magnetics used in garnet series identification

For gem identification purposes, a pick-up response to a strong
neodymium magnet A hard_disk_drive.html"_;"title="Nickel-plated_neodymium_magnet_on_a_bracket_from_a_hard_disk_drive">Nickel-plated_neodymium_magnet_on_a_bracket_from_a_hard_disk_drive_ file:Nd-magnet.jpg.html" ;"title="hard_disk_drive_.html" ;"title="hard_disk_d ...
separates garnet from all other natural transparent gemstones commonly used in the jewelry trade.
Magnetic susceptibility In electromagnetism, the magnetic susceptibility (Latin: , "receptive"; denoted ) is a measure of how much a material will become magnetized in an applied magnetic field. It is the ratio of magnetization (magnetic moment per unit volume) to the ap ...
measurements in conjunction with refractive index can be used to distinguish garnet species and varieties, and determine the composition of garnets in terms of percentages of end-member species within an individual gem.


Garnet group end member species


Pyralspite garnets – aluminium in ''Y'' site

*
Almandine Almandine (), also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia M ...
: Fe3Al2(SiO4)3 * Pyrope: Mg3Al2(SiO4)3 *
Spessartine Spessartine is a nesosilicate, manganese aluminium garnet species, Mn2+3Al2(SiO4)3.Gemological Institute of America, ''GIA Gem Reference Guide'' 1995, This mineral is sometimes mistakenly referred to as ''spessartite''. Spessartine's name is a ...
: Mn3Al2(SiO4)3


Almandine

Almandine, sometimes incorrectly called almandite, is the modern gem known as carbuncle (though originally almost any red gemstone was known by this name). The term "carbuncle" is derived from the Latin meaning "live coal" or burning charcoal. The name ''Almandine'' is a corruption of Alabanda, a region in Asia Minor where these stones were cut in ancient times. Chemically, almandine is an iron-aluminium garnet with the formula Fe3Al2(SiO4)3; the deep red transparent stones are often called precious garnet and are used as gemstones (being the most common of the gem garnets). Almandine occurs in metamorphic rocks like
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is ...
schists, associated with minerals such as
staurolite Staurolite is a reddish brown to black, mostly opaque, nesosilicate mineral with a white streak. It crystallizes in the monoclinic crystal system, has a Mohs hardness of 7 to 7.5 and the chemical formula: Fe2+2Al9O6(SiO4)4(O,OH)2. Magnesium, zinc ...
, kyanite, andalusite, and others. Almandine has nicknames of Oriental garnet, almandine ruby, and carbuncle.


Pyrope

Pyrope (from the Greek ''pyrōpós'' meaning "firelike") is red in color and chemically an aluminium
silicate In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is al ...
with the formula Mg3Al2(SiO4)3, though the magnesium can be replaced in part by calcium and ferrous iron. The color of pyrope varies from deep red to black. Pyrope and spessartine gemstones have been recovered from the Sloan diamondiferous kimberlites in Colorado, from the Bishop Conglomerate and in a Tertiary age lamprophyre at Cedar Mountain in Wyoming. A variety of pyrope from Macon County, North Carolina is a violet-red shade and has been called ''rhodolite'', Greek for "rose". In chemical composition it may be considered as essentially an isomorphous mixture of pyrope and almandine, in the proportion of two parts pyrope to one part almandine. Pyrope has tradenames some of which are
misnomer A misnomer is a name that is incorrectly or unsuitably applied. Misnomers often arise because something was named long before its correct nature was known, or because an earlier form of something has been replaced by a later form to which the name ...
s; ''Cape ruby'', ''Arizona ruby'', ''California ruby'', ''Rocky Mountain ruby'', and ''Bohemian ruby'' from the Czech Republic. Pyrope is an indicator mineral for high-pressure rocks.
Mantle A mantle is a piece of clothing, a type of cloak. Several other meanings are derived from that. Mantle may refer to: *Mantle (clothing), a cloak-like garment worn mainly by women as fashionable outerwear **Mantle (vesture), an Eastern Orthodox ve ...
-derived rocks (
peridotite Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high prop ...
s and eclogites) commonly contain a pyrope variety.


Spessartine

Spessartine or spessartite is manganese aluminium garnet, Mn3Al2(SiO4)3. Its name is derived from Spessart in Bavaria. It occurs most often in skarns, granite
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...
and allied rock types, and in certain low grade metamorphic phyllites. Spessartine of an orange-yellow is found in Madagascar. Violet-red spessartines are found in
rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...
s in Colorado


Pyrope–spessartine (blue garnet or color-change garnet)

Blue pyrope–spessartine garnets were discovered in the late 1990s in Bekily, Madagascar. This type has also been found in parts of the United States, Russia, Kenya, Tanzania, and Turkey. It changes color from blue-green to purple depending on the color temperature of viewing light, as a result of the relatively high amounts of
vanadium Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
(about 1 wt.% V2O3). Other varieties of color-changing garnets exist. In daylight, their color ranges from shades of green, beige, brown, gray, and blue, but in incandescent light, they appear a reddish or purplish/pink color. This is the rarest type of garnet. Because of its color-changing quality, this kind of garnet resembles
alexandrite The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula Be Al2 O4. The name chrysoberyl is derived from the Greek words χρυσός ''chrysos'' and βήρυλλος ''beryllos'', meaning "a gold-white spar". Despite ...
.


Ugrandite group – calcium in ''X'' site

*
Andradite Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12. Andradite includes three varieties: * ''Melanite'': Black in color, referred to as "titanian andradite".Grossular: Ca3Al2(SiO4)3 * Uvarovite: Ca3Cr2(SiO4)3


Andradite

Andradite is a calcium-iron garnet, Ca3Fe2(SiO4)3, is of variable composition and may be red, yellow, brown, green or black. The recognized varieties are
demantoid Demantoid is the green gemstone variety of the mineral andradite, a member of the garnet group of Minerals. Andradite is a calcium- and iron-rich garnet. The chemical formula is Ca3Fe2(SiO4)3 with chromium substitution as the cause of the dema ...
(green), melanite (black), and topazolite (yellow or green). Andradite is found in skarns and in deep-seated igneous rocks like
syenite Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). Some syenites contain larger proport ...
as well as serpentines and greenschists. Demantoid is one of the most prized of garnet varieties.


Grossular

Grossular is a calcium-aluminium garnet with the formula Ca3Al2(SiO4)3, though the calcium may in part be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the botanical name for the
gooseberry Gooseberry ( or (American and northern British) or (southern British)) is a common name for many species of ''Ribes'' (which also includes currants), as well as a large number of plants of similar appearance. The berries of those in the genu ...
, ''grossularia'', in reference to the green garnet of this composition that is found in Siberia. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Because of its inferior hardness to zircon, which the yellow crystals resemble, they have also been called ''hessonite'' from the Greek meaning inferior. Grossular is found in skarns, contact metamorphosed limestones with vesuvianite, diopside, wollastonite and wernerite. Grossular garnet from Kenya and Tanzania has been called tsavorite. Tsavorite was first described in the 1960s in the Tsavo area of Kenya, from which the gem takes its name.


Uvarovite

Uvarovite is a calcium chromium garnet with the formula Ca3Cr2(SiO4)3. This is a rather rare garnet, bright green in color, usually found as small crystals associated with
chromite Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging to the spinel group. The element magnesium can s ...
in
peridotite Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high prop ...
, serpentinite, and kimberlites. It is found in crystalline marbles and schists in the Ural mountains of Russia and Outokumpu, Finland. Uvarovite is named for Count Uvaro, a Russian imperial statesman.


Less common species

*Calcium in ''X'' site **
Goldmanite Goldmanite is a green or greenish-brown silicate mineral of the garnet group with a chemical formula of . Discovery It was first described in 1964 for an occurrence in the Laguna District, Cibola County, New Mexico and is named after Marcus Isaa ...
: **Kimzeyite: **Morimotoite: **Schorlomite: *Hydroxide bearing – calcium in ''X'' site **
Hydrogrossular Hydrogrossular is a calcium aluminium garnet series (formula: Ca3Al2(SiO4)3−''x''(OH)4''x'', with hydroxide (OH) partially replacing silica (SiO4)). The endmembers of the hydrogarnet family (grossular, hibschite, and katoite) depend on the deg ...
: ***Hibschite: (where x is between 0.2 and 1.5) ***Katoite: (where x is greater than 1.5) *Magnesium or manganese in ''X'' site **
Knorringite Knorringite is a mineral species belonging to the garnet group, and forms a series with the species pyrope. It was discovered in 1968 in the Kao kimberlite pipe in the Butha-Buthe District of Lesotho and is named after Oleg Von Knorring, a profess ...
: **
Majorite Majorite is a type of garnet mineral found in the mantle of the Earth. Its chemical formula is Mg3(MgSi)(SiO4)3. It is distinguished from other garnets in having Si in octahedral as well as tetrahedral coordination. Majorite was first described ...
: **
Calderite Calderite is a mineral in the garnet group with the chemical formula ( Mn2+, Ca)3( Fe3+, Al)2( Si O4)3. It is dark reddish brown to dark yellowish in color and generally granular massive in form. It was named for geologist James Calder who w ...
:


Knorringite

Knorringite is a magnesium-chromium garnet species with the formula Mg3Cr2(SiO4)3. Pure endmember knorringite never occurs in nature. Pyrope rich in the knorringite component is only formed under high pressure and is often found in kimberlites. It is used as an indicator mineral in the search for diamonds.


Garnet structural group

*Formula: X3Z2(TO4)3 (X = Ca, Fe, etc., Z = Al, Cr, etc., T = Si, As, V, Fe, Al) **All are cubic or strongly pseudocubic. *IMA/CNMNC – Nickel-Strunz – Mineral subclass: 09.A Nesosilicate ** Nickel-Strunz classification: 09.AD.25 *References:
Mindat.org Mindat.org is a non-commercial online database, claiming to be the largest mineral database and mineralogy, mineralogical reference website on the Internet. It is used by professional mineralogists, geologists, and amateur mineral collecting, mi ...
; mineral name, chemical formula and space group (American Mineralogist Crystal Structure Database) of the IMA Database of Mineral Properties/ RRUFF Project, Univ. of Arizona, was preferred most of the time. Minor components in formulae have been left out to highlight the dominant chemical endmember that defines each species.


Synthetic garnets

Also known as rare-earth garnets. The crystallographic structure of garnets has been expanded from the prototype to include chemicals with the general formula ''A''3''B''2(''C''O4)3. Besides silicon, a large number of elements have been put on the ''C'' site, including
germanium Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors s ...
,
gallium Gallium is a chemical element with the symbol Ga and atomic number 31. Discovered by French chemist Paul-Émile Lecoq de Boisbaudran in 1875, Gallium is in group 13 of the periodic table and is similar to the other metals of the group (aluminiu ...
, aluminum,
vanadium Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
and iron. Yttrium aluminium garnet (YAG), Y3Al2(AlO4)3, is used for
synthetic Synthetic things are composed of multiple parts, often with the implication that they are artificial. In particular, 'synthetic' may refer to: Science * Synthetic chemical or compound, produced by the process of chemical synthesis * Synthetic o ...
gemstones. Due to its fairly high refractive index, YAG was used as a diamond simulant in the 1970s until the methods of producing the more advanced simulant cubic zirconia in commercial quantities were developed. When doped with neodymium (Nd3+), YAG may be used as the
lasing medium The active laser medium (also called gain medium or lasing medium) is the source of optical gain within a laser. The gain results from the stimulated emission of photons through electronic or molecular transitions to a lower energy state from a ...
in Nd:YAG lasers. When doped with erbium, it can be used as the lasing medium in Er:YAG lasers. When doped with gadolinium, it can be used as the lasing medium in Gd:YAG lasers. These doped YAG lasers are used in medical procedures including
laser skin resurfacing Photorejuvenation is a skin treatment that uses lasers, intense pulsed light, or photodynamic therapy to treat skin conditions and remove effects of photoaging such as wrinkles, spots, and textures. The process induces controlled wounds to the ski ...
, dentistry, and ophthalmology. Interesting magnetic properties arise when the appropriate elements are used. In yttrium iron garnet (YIG), Y3Fe2(FeO4)3, the five iron(III) ions occupy two octahedral and three tetrahedral sites, with the yttrium(III) ions coordinated by eight oxygen ions in an irregular cube. The iron ions in the two coordination sites exhibit different
spins The spins (as in having "the spins")Diane Marie Leiva. ''The Florida State University College of Education''Women's Voices on College Drinking: The First-Year College Experience"/ref> is an adverse reaction of intoxication that causes a state of v ...
, resulting in
magnetic Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particle ...
behavior. YIG is a ferrimagnetic material having a Curie temperature of 550  K. Yttrium iron garnet can be made into YIG spheres, which serve as magnetically tunable
filters Filter, filtering or filters may refer to: Science and technology Computing * Filter (higher-order function), in functional programming * Filter (software), a computer program to process a data stream * Filter (video), a software component tha ...
and
resonators A resonator is a device or system that exhibits resonance or resonant behavior. That is, it naturally oscillates with greater amplitude at some frequencies, called resonant frequencies, than at other frequencies. The oscillations in a resonator ...
for microwave frequencies.
Lutetium aluminium garnet Lutetium aluminum garnet (commonly abbreviated LuAG, molecular formula Lu3Al5O12) is an inorganic compound with a unique crystal structure primarily known for its use in high-efficiency laser devices. LuAG is also useful in the synthesis of transpa ...
(LuAG), , is an inorganic compound with a unique crystal structure primarily known for its use in high-efficiency laser devices. LuAG is also useful in the synthesis of transparent ceramics. LuAG is particularly favored over other crystals for its high density and thermal conductivity; it has a relatively small lattice constant in comparison to the other rare-earth garnets, which results in a higher density producing a crystal field with narrower linewidths and greater energy level splitting in absorption and emission. Terbium gallium garnet (TGG), , is a
Faraday rotator A Faraday rotator is a polarization rotator based on the Faraday effect, a magneto-optic effect involving transmission of light through a material when a longitudinal static magnetic field is present. The state of polarization (such as the axis of ...
material with excellent transparency properties and is very resistant to laser damage. TGG can be used in optical isolators for laser systems, in optical circulators for fiber optic systems, in
optical modulator An optical modulator is a device which is used to modulate a beam of light. The beam may be carried over free space, or propagated through an optical waveguide ( optical fibre). Depending on the parameter of a light beam which is manipulated, mod ...
s, and in current and
magnetic field A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
sensors. Another example is gadolinium gallium garnet (GGG), which is synthesized for use as a substrate for liquid-phase epitaxy of magnetic garnet films for bubble memory and magneto-optical applications.


Geological importance

The mineral garnet is commonly found in metamorphic and to a lesser extent, igneous rocks. Most natural garnets are compositionally zoned and contain inclusions. Its crystal lattice structure is stable at high pressures and temperatures and is thus found in green-schist facies metamorphic rocks including gneiss, hornblende schist, and mica schist. The composition that is stable at the pressure and temperature conditions of Earth's mantle is pyrope, which is often found in
peridotites Peridotite ( ) is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high prop ...
and kimberlites, as well as the serpentines that form from them. Garnets are unique in that they can record the pressures and temperatures of peak metamorphism and are used as geobarometers and geothermometers in the study of
geothermobarometry Geothermobarometry is the science of measuring the previous pressure and temperature history of a metamorphic or intrusive igneous rocks. Geothermobarometry is a combination of ''geobarometry'', where a pressure of mineral formation is resolved, an ...
which determines "P-T Paths", Pressure-Temperature Paths. Garnets are used as an index mineral in the delineation of isograds in metamorphic rocks. Compositional zoning and inclusions can mark the change from growth of the crystals at low temperatures to higher temperatures. Garnets that are not compositionally zoned more than likely experienced ultra high temperatures (above 700 °C) that led to diffusion of major elements within the crystal lattice, effectively homogenizing the crystal or they were never zoned. Garnets can also form metamorphic textures that can help interpret structural histories. In addition to being used to devolve conditions of metamorphism, garnets can be used to date certain geologic events. Garnet has been developed as a U-Pb geochronometer, to date the age of crystallization as well as a thermochronometer in the (U-Th)/He system to date timing of cooling below a closure temperature. Garnets can be chemically altered and most often alter to serpentine, talc, and
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous ac ...
.


Uses


Gemstones

Red garnets were the most commonly used gemstones in the Late Antique Roman world, and the Migration Period art of the "
barbarian A barbarian (or savage) is someone who is perceived to be either Civilization, uncivilized or primitive. The designation is usually applied as a generalization based on a popular stereotype; barbarians can be members of any nation judged by som ...
" peoples who took over the territory of the Western Roman Empire. They were especially used inlaid in gold cells in the cloisonné technique, a style often just called garnet cloisonné, found from
Anglo-Saxon The Anglo-Saxons were a Cultural identity, cultural group who inhabited England in the Early Middle Ages. They traced their origins to settlers who came to Britain from mainland Europe in the 5th century. However, the ethnogenesis of the Anglo- ...
England, as at
Sutton Hoo Sutton Hoo is the site of two early medieval cemeteries dating from the 6th to 7th centuries near the English town of Woodbridge. Archaeologists have been excavating the area since 1938, when a previously undisturbed ship burial containing a ...
, to the Black Sea. Thousands of Tamraparniyan gold, silver and red garnet shipments were made in the
old world The "Old World" is a term for Afro-Eurasia that originated in Europe , after Europeans became aware of the existence of the Americas. It is used to contrast the continents of Africa, Europe, and Asia, which were previously thought of by the ...
, including to Rome, Greece, the Middle East,
Serica Serica (, grc, Σηρικά) was one of the easternmost countries of Asia known to the Ancient Greek and Roman geographers. It is generally taken as referring to North China North China, or Huabei () is a List of regions of China, geogr ...
and Anglo Saxons; recent findings such as the Staffordshire Hoard and the pendant of the
Winfarthing Winfarthing is a village and civil parish in the English county of Norfolk. It is located 6 km north of the town of Diss, 20 km east of the town of Thetford, and 30 km south of the city of Norwich. The civil parish has an area of and in the ...
Woman skeleton of Norfolk confirm an established gem trade route with South India and Tamraparni (ancient
Sri Lanka Sri Lanka (, ; si, ශ්‍රී ලංකා, Śrī Laṅkā, translit-std=ISO (); ta, இலங்கை, Ilaṅkai, translit-std=ISO ()), formerly known as Ceylon and officially the Democratic Socialist Republic of Sri Lanka, is an ...
), known from antiquity for its production of gemstones. Pure crystals of garnet are still used as gemstones. The gemstone varieties occur in shades of green, red, yellow, and orange. In the US it is known as the
birthstone A birthstone is a gemstone A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rock ...
for January. Gemological Institute of America, ''GIA Gem Reference Guide'' 1995, The garnet family is one of the most complex in the gem world. It is not a single species, but is composed of multiple species and varieties. It is the
state mineral Leaders of states in the U.S. which have significant mineral deposits often create a state mineral, rock, stone or gemstone to promote interest in their natural resources, history, tourism, etc. Not every state has an official state mineral, rock, ...
of Connecticut, New York's gemstone, and star garnet (garnet with rutile asterisms) is the state gemstone of Idaho.


Industrial uses

Garnet sand is a good abrasive, and a common replacement for silica sand in sand blasting. Alluvial garnet grains which are rounder are more suitable for such blasting treatments. Mixed with very high pressure water, garnet is used to cut
steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...
and other materials in water jets. For water jet cutting, garnet extracted from hard rock is suitable since it is more angular in form, therefore more efficient in cutting. Garnet paper is favored by cabinetmakers for finishing bare wood. Garnet sand is also used for
water filtration A water filter removes impurities by lowering contamination of water using a fine physical barrier, a chemical process, or a biological process. Filters cleanse water to different extents, for purposes such as: providing agricultural irrigation ...
media. As an abrasive, garnet can be broadly divided into two categories; blasting grade and water jet grade. The garnet, as it is mined and collected, is crushed to finer grains; all pieces which are larger than 60 mesh (250 micrometers) are normally used for sand blasting. The pieces between 60 mesh (250 micrometers) and 200 mesh (74 micrometers) are normally used for water jet cutting. The remaining garnet pieces that are finer than 200 mesh (74 micrometers) are used for glass polishing and lapping. Regardless of the application, the larger grain sizes are used for faster work and the smaller ones are used for finer finishes. There are different kinds of abrasive garnets which can be divided based on their origin. The largest source of abrasive garnet today is garnet-rich beach sand which is quite abundant on Indian and
Australia Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
n coasts and the main producers today are Australia and India. This material is particularly popular due to its consistent supplies, huge quantities and clean material. The common problems with this material are the presence of ilmenite and chloride compounds. Since the material has been naturally crushed and ground on the beaches for past centuries, the material is normally available in fine sizes only. Most of the garnet at the Tuticorin beach in south India is 80 mesh, and ranges from 56 mesh to 100 mesh size. ''River garnet'' is particularly abundant in Australia. The river sand garnet occurs as a placer deposit. ''Rock garnet'' is perhaps the garnet type used for the longest period of time. This type of garnet is produced in America, China and western India. These crystals are crushed in mills and then purified by wind blowing, magnetic separation, sieving and, if required, washing. Being freshly crushed, this garnet has the sharpest edges and therefore performs far better than other kinds of garnet. Both the river and the beach garnet suffer from the tumbling effect of hundreds of thousands of years which rounds off the edges.
Gore Mountain Garnet Gore Mountain Garnet, found in the Adirondack Mountains in New York, contains the world's largest garnets. The rock that holds these garnets, garnet amphibolite, is sometimes referred to as 'black ore' or 'dark ore.' This rock formation formed d ...
from Warren County, New York, USA is a significant source of rock garnet for use as an industrial abrasive.


Cultural significance

Garnet is the
birthstone A birthstone is a gemstone A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rock ...
of January. It is also the birthstone of
Aquarius Aquarius may refer to: Astrology * Aquarius (astrology), an astrological sign * Age of Aquarius, a time period in the cycle of astrological ages Astronomy * Aquarius (constellation) * Aquarius in Chinese astronomy Arts and entertainment ...
and Capricorn in
tropical astrology The tropics are the regions of Earth surrounding the Equator. They are defined in latitude by the Tropic of Cancer in the Northern Hemisphere at N and the Tropic of Capricorn in the Southern Hemisphere at S. The tropics are also referred to ...
. In Persia this birth gem was considered a talisman from nature's forces like storm and lightning. It was widely accepted that garnet could signal approaching danger by turning pale.


United States

Garnet is
New York State's New York, officially the State of New York, is a state in the Northeastern United States. It is often called New York State to distinguish it from its largest city, New York City. With a total area of , New York is the 27th-largest U.S. state ...
official gemstone, Connecticut has
almandine Almandine (), also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia M ...
garnet as its state gemstone, Idaho has star garnet as its state gemstone, and Vermont has grossular garnet as its state gemstone. Since 2003 New York State has ranked first in industrial garnet-production in the United States. Since there are just a few companies that account for all U.S. industrial garnet production, published detailed production statistics for New York State are not available. However, generally speaking, Barton Mines in Warren County is the largest U.S. garnet producer.


Collections

The New York State Museum in Albany, NY houses specimens from significant sites across the state, including 93 mineral species from the Balmat-Edwards mining district in St. Lawrence, super garnets from the Barton Mine in the Adirondack Mountains, and Herkimer diamonds from Herkimer County, New York


Oldest garnet mine

The largest garnet mine in the world is located Near North Creek New York and is operated by Barton Mines Corporation who supplies about 90% of the world's garnet. Barton Mines Corporation is the first and oldest industrial garnet mining operation in the world and the second oldest continuous mining operation in the United States under the same management and mining the same product throughout its history. The Gore Mountain Mine of the Barton Mines Corporation was first mined under the direction of H. H. Barton, Sr. in 1878 to produce garnet as the primary product.


Largest garnet crystal

The open-pit Barton Garnet Mine, located at Gore Mountain in the Adirondack Highlands, yields the world's largest single crystals of garnet; diameters range from 5 to 35 cm and commonly average 10–18 cm. Gore Mountain garnets are unique in many respects, and considerable effort has been made to determine the timing of garnet growth. The first dating was that of Basu et al. (1989), who used plagioclase-hornblende-garnet to produce a Sm/Nd isochron that yielded an age of 1059 ± 19 Ma. Mezger et al. (1992) conducted their own Sm/Nd investigation using hornblende and the drilled core of a 50 cm garnet to produce an isochron age of 1051 ± 4 Ma. Connelly (2006) utilized 7 different fractions of a Gore Mountain garnet to obtain a Lu-Hf isochron age of 1046.6 ± 6 Ma. We therefore conclude with confidence that the garnets formed at 1049 ± 5 Ma, the average of the three determinations. This is also the local age of peak metamorphism in the 1090–1040 Ma Ottawan phase of the Grenvillian orogeny and serves as a critical data point in ascertaining the evolution of the megacrystic garnet deposits.


See also

*
Abrasive blasting Sandblasting, sometimes known as abrasive blasting, is the operation of forcibly propelling a stream of abrasive material against a surface under high pressure to smooth a rough surface, roughen a smooth surface, shape a surface or remove su ...


References


Further reading

* Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Manual of Mineralogy'', 20th ed., Wiley, * ''Color Encyclopedia of Gemstones'',


External links

*http://www.gemstonemagnetism.com contains a comprehensive section about garnets and garnet magnetism.
USGS Garnet locations – USA
*http://gemstone.org/education/gem-by-gem/154-garnet *http://www.mindat.org/min-10272.html
Blog post on garnets
on the Law Library of Congress's blog *https://www.birthstone.guide/garnet-birthstone-meaning Garnet birthstone stories {{Authority control Magnesium minerals Symbols of Connecticut Symbols of Vermont Cubic minerals Minerals in space group 230 * * Industrial minerals