Rubidium (
37Rb) has 36
isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numb ...
s, with naturally occurring rubidium being composed of just two isotopes;
85Rb (72.2%) and the
radioactive
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
87Rb (27.8%). Normal mixes of rubidium are radioactive enough to fog
photographic film in approximately 30 to 60 days.
87Rb has a
half-life
Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable at ...
of . It readily substitutes for
potassium
Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...
in
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
s, and is therefore fairly widespread.
87Rb has been used extensively in
dating rocks;
87Rb decays to stable
strontium-87 by emission of a
beta particle (an electron ejected from the nucleus). During
fractional crystallization, Sr tends to become concentrated in
plagioclase
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...
, leaving Rb in the liquid phase. Hence, the Rb/Sr ratio in residual
magma
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
may increase over time, resulting in rocks with increasing Rb/Sr ratios with increasing
differentiation. The highest ratios (10 or higher) occur in
pegmatites. If the initial amount of Sr is known or can be extrapolated, the age can be determined by measurement of the Rb and Sr concentrations and the
87Sr/
86Sr ratio. The dates indicate the true age of the minerals only if the rocks have not been subsequently altered. See
rubidium–strontium dating
The rubidium-strontium dating method is a radiometric dating technique, used by scientists to determine the age of rocks and minerals from their content of specific isotopes of rubidium (87Rb) and strontium (87Sr, 86Sr). One of the two naturally ...
for a more detailed discussion.
Other than
87Rb, the longest-lived
radioisotope
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...
s are
83Rb with a half-life of 86.2 days,
84Rb with a half-life of 33.1 days, and
86Rb with a half-life of 18.642 days. All other radioisotopes have half-lives less than a day.
82Rb is used in some
cardiac
The heart is a muscular organ in most animals. This organ pumps blood through the blood vessels of the circulatory system. The pumped blood carries oxygen and nutrients to the body, while carrying metabolic waste such as carbon dioxide to t ...
positron emission tomography scans to assess
myocardial perfusion. It has a
half-life
Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable at ...
of 1.273 minutes. It does not exist naturally, but can be made from the decay of
82Sr.
List of isotopes
, -
,
71Rb
, style="text-align:right" , 37
, style="text-align:right" , 34
, 70.96532(54)#
,
,
p
,
70Kr
, 5/2−#
,
,
, -
,
72Rb
, style="text-align:right" , 37
, style="text-align:right" , 35
, 71.95908(54)#
, <1.5 μs
, p
,
71Kr
, 3+#
,
,
, -
, style="text-indent:1em" ,
72mRb
, colspan="3" style="text-indent:2em" , 100(100)# keV
, 1# μs
, p
,
71Kr
, 1−#
,
,
, -
,
73Rb
, style="text-align:right" , 37
, style="text-align:right" , 36
, 72.95056(16)#
, <30 ns
, p
,
72Kr
, 3/2−#
,
,
, -
,
74Rb
, style="text-align:right" , 37
, style="text-align:right" , 37
, 73.944265(4)
, 64.76(3) ms
,
β+
,
74Kr
, (0+)
,
,
, -
,
75Rb
, style="text-align:right" , 37
, style="text-align:right" , 38
, 74.938570(8)
, 19.0(12) s
, β
+
,
75Kr
, (3/2−)
,
,
, -
, rowspan=2,
76Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 39
, rowspan=2, 75.9350722(20)
, rowspan=2, 36.5(6) s
, β
+
,
76Kr
, rowspan=2, 1(−)
, rowspan=2,
, rowspan=2,
, -
, β
+,
α (3.8×10
−7%)
,
72Se
, -
, style="text-indent:1em" ,
76mRb
, colspan="3" style="text-indent:2em" , 316.93(8) keV
, 3.050(7) μs
,
,
, (4+)
,
,
, -
,
77Rb
, style="text-align:right" , 37
, style="text-align:right" , 40
, 76.930408(8)
, 3.77(4) min
, β
+
,
77Kr
, 3/2−
,
,
, -
,
78Rb
, style="text-align:right" , 37
, style="text-align:right" , 41
, 77.928141(8)
, 17.66(8) min
, β
+
, ''
78Kr''
, 0(+)
,
,
, -
, rowspan=2 style="text-indent:1em" ,
78mRb
, rowspan=2 colspan="3" style="text-indent:2em" , 111.20(10) keV
, rowspan=2, 5.74(5) min
, β
+ (90%)
, ''
78Kr''
, rowspan=2, 4(−)
, rowspan=2,
, rowspan=2,
, -
,
IT (10%)
,
78Rb
, -
,
79Rb
, style="text-align:right" , 37
, style="text-align:right" , 42
, 78.923989(6)
, 22.9(5) min
, β
+
,
79Kr
, 5/2+
,
,
, -
,
80Rb
, style="text-align:right" , 37
, style="text-align:right" , 43
, 79.922519(7)
, 33.4(7) s
, β
+
,
80Kr
, 1+
,
,
, -
, style="text-indent:1em" ,
80mRb
, colspan="3" style="text-indent:2em" , 494.4(5) keV
, 1.6(2) μs
,
,
, 6+
,
,
, -
,
81Rb
, style="text-align:right" , 37
, style="text-align:right" , 44
, 80.918996(6)
, 4.570(4) h
, β
+
,
81Kr
, 3/2−
,
,
, -
, rowspan=2 style="text-indent:1em" ,
81mRb
, rowspan=2 colspan="3" style="text-indent:2em" , 86.31(7) keV
, rowspan=2, 30.5(3) min
, IT (97.6%)
,
81Rb
, rowspan=2, 9/2+
, rowspan=2,
, rowspan=2,
, -
, β
+ (2.4%)
,
81Kr
, -
,
82 Rb
, style="text-align:right" , 37
, style="text-align:right" , 45
, 81.9182086(30)
, 1.273(2) min
, β
+
,
82Kr
, 1+
,
,
, -
, rowspan=2 style="text-indent:1em" ,
82mRb
, rowspan=2 colspan="3" style="text-indent:2em" , 69.0(15) keV
, rowspan=2, 6.472(5) h
, β
+ (99.67%)
,
82Kr
, rowspan=2, 5−
, rowspan=2,
, rowspan=2,
, -
, IT (.33%)
,
82Rb
, -
,
83Rb
, style="text-align:right" , 37
, style="text-align:right" , 46
, 82.915110(6)
, 86.2(1) d
,
EC
,
83Kr
, 5/2−
,
,
, -
, style="text-indent:1em" ,
83mRb
, colspan="3" style="text-indent:2em" , 42.11(4) keV
, 7.8(7) ms
, IT
,
83Rb
, 9/2+
,
,
, -
, rowspan=2,
84Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 47
, rowspan=2, 83.914385(3)
, rowspan=2, 33.1(1) d
, β
+ (96.2%)
,
84Kr
, rowspan=2, 2−
, rowspan=2,
, rowspan=2,
, -
, β
− (3.8%)
,
84Sr
, -
, rowspan=2 style="text-indent:1em" ,
84mRb
, rowspan=2 colspan="3" style="text-indent:2em" , 463.62(9) keV
, rowspan=2, 20.26(4) min
, IT (>99.9%)
,
84Rb
, rowspan=2, 6−
, rowspan=2,
, rowspan=2,
, -
, β
+ (<.1%)
,
84Kr
, -
,
85Rb
[ Fission product]
, style="text-align:right" , 37
, style="text-align:right" , 48
, 84.911789738(12)
, colspan=3 align=center, Stable
, 5/2−
, 0.7217(2)
,
, -
, rowspan=2,
86Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 49
, rowspan=2, 85.91116742(21)
, rowspan=2, 18.642(18) d
, β
− (99.9948%)
,
86Sr
, rowspan=2, 2−
, rowspan=2,
, rowspan=2,
, -
, EC (.0052%)
,
86Kr
, -
, style="text-indent:1em" ,
86mRb
, colspan="3" style="text-indent:2em" , 556.05(18) keV
, 1.017(3) min
, IT
,
86Rb
, 6−
,
,
, -
,
87Rb
[ Primordial radionuclide][Used in ]rubidium–strontium dating
The rubidium-strontium dating method is a radiometric dating technique, used by scientists to determine the age of rocks and minerals from their content of specific isotopes of rubidium (87Rb) and strontium (87Sr, 86Sr). One of the two naturally ...
, style="text-align:right" , 37
, style="text-align:right" , 50
, 86.909180527(13)
, 4.923(22)×10
10 y
, β
−
,
87Sr
, 3/2−
, 0.2783(2)
,
, -
,
88Rb
, style="text-align:right" , 37
, style="text-align:right" , 51
, 87.91131559(17)
, 17.773(11) min
, β
−
,
88Sr
, 2−
,
,
, -
,
89Rb
, style="text-align:right" , 37
, style="text-align:right" , 52
, 88.912278(6)
, 15.15(12) min
, β
−
,
89Sr
, 3/2−
,
,
, -
,
90Rb
, style="text-align:right" , 37
, style="text-align:right" , 53
, 89.914802(7)
, 158(5) s
, β
−
,
90Sr
, 0−
,
,
, -
, rowspan=2 style="text-indent:1em" ,
90mRb
, rowspan=2 colspan="3" style="text-indent:2em" , 106.90(3) keV
, rowspan=2, 258(4) s
, β
− (97.4%)
,
90Sr
, rowspan=2, 3−
, rowspan=2,
, rowspan=2,
, -
, IT (2.6%)
,
90 Rb
, -
,
91Rb
, style="text-align:right" , 37
, style="text-align:right" , 54
, 90.916537(9)
, 58.4(4) s
, β
−
,
91Sr
, 3/2(−)
,
,
, -
, rowspan=2,
92Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 55
, rowspan=2, 91.919729(7)
, rowspan=2, 4.492(20) s
, β
− (99.98%)
,
92Sr
, rowspan=2, 0−
, rowspan=2,
, rowspan=2,
, -
, β
−,
n (.0107%)
,
91Sr
, -
, rowspan=2,
93Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 56
, rowspan=2, 92.922042(8)
, rowspan=2, 5.84(2) s
, β
− (98.65%)
,
93Sr
, rowspan=2, 5/2−
, rowspan=2,
, rowspan=2,
, -
, β
−, n (1.35%)
,
92Sr
, -
, style="text-indent:1em" ,
93mRb
, colspan="3" style="text-indent:2em" , 253.38(3) keV
, 57(15) μs
,
,
, (3/2−,5/2−)
,
,
, -
, rowspan=2,
94Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 57
, rowspan=2, 93.926405(9)
, rowspan=2, 2.702(5) s
, β
− (89.99%)
,
94Sr
, rowspan=2, 3(−)
, rowspan=2,
, rowspan=2,
, -
, β
−, n (10.01%)
,
93Sr
, -
, rowspan=2,
95Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 58
, rowspan=2, 94.929303(23)
, rowspan=2, 377.5(8) ms
, β
− (91.27%)
,
95Sr
, rowspan=2, 5/2−
, rowspan=2,
, rowspan=2,
, -
, β
−, n (8.73%)
,
94Sr
, -
, rowspan=2,
96Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 59
, rowspan=2, 95.93427(3)
, rowspan=2, 202.8(33) ms
, β
− (86.6%)
,
96Sr
, rowspan=2, 2+
, rowspan=2,
, rowspan=2,
, -
, β
−, n (13.4%)
,
95Sr
, -
, rowspan=3 style="text-indent:1em" ,
96mRb
, rowspan=3 colspan="3" style="text-indent:2em" , 0(200)# keV
, rowspan=3, 200# ms
1 ms, β
−
,
96Sr
, rowspan=3, 1(−#)
, rowspan=3,
, rowspan=3,
, -
, IT
,
96Rb
, -
, β
−, n
,
95Sr
, -
, rowspan=2,
97Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 60
, rowspan=2, 96.93735(3)
, rowspan=2, 169.9(7) ms
, β
− (74.3%)
,
97Sr
, rowspan=2, 3/2+
, rowspan=2,
, rowspan=2,
, -
, β
−, n (25.7%)
,
96Sr
, -
, rowspan=3,
98Rb
, rowspan=3 style="text-align:right" , 37
, rowspan=3 style="text-align:right" , 61
, rowspan=3, 97.94179(5)
, rowspan=3, 114(5) ms
, β
−(86.14%)
,
98Sr
, rowspan=3, (0,1)(−#)
, rowspan=3,
, rowspan=3,
, -
, β
−, n (13.8%)
,
97Sr
, -
, β
−, 2n (.051%)
,
96Sr
, -
, style="text-indent:1em" ,
98mRb
, colspan="3" style="text-indent:2em" , 290(130) keV
, 96(3) ms
, β
−
,
97Sr
, (3,4)(+#)
,
,
, -
, rowspan=2,
99Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 62
, rowspan=2, 98.94538(13)
, rowspan=2, 50.3(7) ms
, β
− (84.1%)
,
99Sr
, rowspan=2, (5/2+)
, rowspan=2,
, rowspan=2,
, -
, β
−, n (15.9%)
,
98Sr
, -
, rowspan=3,
100Rb
, rowspan=3 style="text-align:right" , 37
, rowspan=3 style="text-align:right" , 63
, rowspan=3, 99.94987(32)#
, rowspan=3, 51(8) ms
, β
− (94.25%)
,
100Sr
, rowspan=3, (3+)
, rowspan=3,
, rowspan=3,
, -
, β
−, n (5.6%)
,
99Sr
, -
, β
−, 2n (.15%)
,
98Sr
, -
, rowspan=2,
101Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 64
, rowspan=2, 100.95320(18)
, rowspan=2, 32(5) ms
, β
− (69%)
,
101Sr
, rowspan=2, (3/2+)#
, rowspan=2,
, rowspan=2,
, -
, β
−, n (31%)
,
100Sr
, -
, rowspan=2,
102Rb
, rowspan=2 style="text-align:right" , 37
, rowspan=2 style="text-align:right" , 65
, rowspan=2, 101.95887(54)#
, rowspan=2, 37(5) ms
, β
− (82%)
,
102Sr
, rowspan=2,
, rowspan=2,
, rowspan=2,
, -
, β
−, n (18%)
,
101Sr
, -
,
103Rb
, style="text-align:right" , 37
, style="text-align:right" , 66
,
, 26 ms
, β
−
,
103Sr
,
,
,
, -
,
104Rb
, style="text-align:right" , 37
, style="text-align:right" , 67
,
, 35# ms (>550 ns)
, β
−?
,
104Sr
,
,
,
, -
,
105Rb
, style="text-align:right" , 37
, style="text-align:right" , 68
,
,
,
,
,
,
,
, -
,
106Rb
, style="text-align:right" , 37
, style="text-align:right" , 69
,
,
,
,
,
,
,
Rubidium-87
Rubidium-87 is an
isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numb ...
of
rubidium. Rubidium-87 was the first and the most popular atom for making
Bose–Einstein condensate
In condensed matter physics, a Bose–Einstein condensate (BEC) is a state of matter that is typically formed when a gas of bosons at very low densities is cooled to temperatures very close to absolute zero (−273.15 °C or −459.6 ...
s in dilute
atomic gases. Even though
rubidium-85
Rubidium (37Rb) has 36 isotopes, with naturally occurring rubidium being composed of just two isotopes; 85Rb (72.2%) and the radioactive 87Rb (27.8%). Normal mixes of rubidium are radioactive enough to fog photographic film in approximately 30 ...
is more abundant, rubidium-87 has a positive scattering length, which means it is mutually repulsive, at low temperatures. This prevents a collapse of all but the smallest condensates. It is also easy to evaporatively cool, with a consistent strong mutual scattering. There is also a strong supply of cheap uncoated
diode laser
The laser diode chip removed and placed on the eye of a needle for scale
A laser diode (LD, also injection laser diode or ILD, or diode laser) is a semiconductor device similar to a light-emitting diode in which a diode pumped directly with e ...
s typically used in
CD writer
In computing, an optical disc drive is a disk drive, disc drive that uses laser light or electromagnetic waves within or near the visible light spectrum as part of the process of reading or writing data to or from optical discs. Some drives ...
s, which can operate at the correct wavelength.
Rubidium-87 has an atomic mass of 86.9091835 u, and a binding energy of 757,853 keV. Its atomic percent abundance is 27.835%, and has a half-life of .
References
* Isotope masses from:
**
* Isotopic compositions and standard atomic masses from:
**
**
* Half-life, spin, and isomer data selected from the following sources.
**
**
**
{{Navbox element isotopes
Rubidium
Rubidium