ground granulated blast furnace slag
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Ground-granulated blast-furnace
slag Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-prod ...
(GGBS or GGBFS) is obtained by quenching molten iron
slag Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-prod ...
(a by-product of iron and
steel-making Steelmaking is the process of producing steel from iron ore and carbon/or scrap. In steelmaking, impurities such as nitrogen, silicon, phosphorus, sulfur and excess carbon (the most important impurity) are removed from the sourced iron, and alloy ...
) from a
blast furnace A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being "forced" or supplied above atmospheric ...
in water or steam, to produce a glassy, granular product that is then dried and ground into a fine powder. Ground-granulated blast furnace slag is a latent hydraulic binder forming calcium silicate hydrates (C-S-H) after contact with water. It is a strength-enhancing compound improving the durability of concrete. It is a component of metallurgic cement ( in the European norm ). Its main advantage is its slow release of hydration heat allowing to limit the temperature increase in massive concrete components and structures during cement setting and concrete curing, or to cast concrete during hot summer.


Production and composition

The chemical composition of a slag varies considerably depending on the composition of the raw materials in the
iron production Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundance ...
process. Silicate and aluminate impurities from the ore and coke are combined in the
blast furnace A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being "forced" or supplied above atmospheric ...
with a
flux Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications to physics. For transport ph ...
which lowers the viscosity of the slag. In the case of pig iron production the flux consists mostly of a mixture of limestone and
forsterite Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthor ...
or in some cases
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
. In the blast furnace the slag floats on top of the iron and is decanted for separation. Slow cooling of slag melts results in an unreactive crystalline material consisting of an assemblage of Ca-Al-Mg silicates. To obtain a good slag reactivity or hydraulicity, the slag melt needs to be rapidly cooled or quenched below 800 °C in order to prevent the crystallization of merwinite and melilite. To cool and fragment the slag a granulation process can be applied in which molten slag is subjected to jet streams of water or air under pressure. Alternatively, in the pelletization process the liquid slag is partially cooled with water and subsequently projected into the air by a rotating drum. In order to obtain a suitable reactivity, the obtained fragments are ground to reach the same fineness as Portland cement. The main components of blast furnace slag are CaO (30-50%), SiO2 (28-38%), Al2O3 (8-24%), and MgO (1-18%). In general increasing the CaO content of the slag results in raised slag
basicity In chemistry, there are three definitions in common use of the word base, known as Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed by G.-F. Rou ...
and an increase in
compressive strength In mechanics, compressive strength or compression strength is the capacity of a material or structure to withstand loads tending to reduce size (as opposed to tensile strength which withstands loads tending to elongate). In other words, compre ...
. The MgO and Al2O3 content show the same trend up to respectively 10-12% and 14%, beyond which no further improvement can be obtained. Several compositional ratios or so-called hydraulic indices have been used to correlate slag composition with hydraulic activity; the latter being mostly expressed as the binder compressive strength. The glass content of slags suitable for blending with Portland cement typically varies between 90-100% and depends on the cooling method and the temperature at which cooling is initiated. The glass structure of the quenched glass largely depends on the proportions of network-forming elements such as Si and Al over network-modifiers such as Ca, Mg and to a lesser extent Al. Increased amounts of network-modifiers lead to higher degrees of network depolymerization and reactivity. Common crystalline constituents of blast-furnace slags are merwinite and melilite. Other minor components which can form during progressive crystallization are
belite Belite is an industrial mineral important in Portland cement manufacture. Its main constituent is dicalcium silicate, Ca2SiO4, sometimes formulated as 2 CaO · SiO2 (C2S in cement chemist notation). Etymology The name was given by Törnebohm in ...
, monticellite, rankinite, wollastonite and
forsterite Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthor ...
. Minor amounts of reduced sulphur are commonly encountered as oldhamite.


Applications

GGBS is used to make durable concrete structures in combination with ordinary Portland cement and/or other pozzolanic materials. GGBS has been widely used in Europe, and increasingly in the United States and in Asia (particularly in Japan and Singapore) for its superiority in concrete durability, extending the lifespan of buildings from fifty years to a hundred years. Two major uses of GGBS are in the production of quality-improved slag cement, namely Portland Blastfurnace cement (PBFC) and high-slag blast-furnace cement (HSBFC), with GGBS content ranging typically from 30 to 70%; and in the production of
ready-mixed Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wi ...
or site-batched durable concrete. Concrete made with GGBS cement sets more slowly than concrete made with ordinary Portland cement, depending on the amount of GGBS in the cementitious material, but also continues to gain strength over a longer period in production conditions. This results in lower heat of
hydration Hydration may refer to: * Hydrate, a substance that contains water * Hydration enthalpy, energy released through hydrating a substance * Hydration reaction, a chemical addition reaction where a hydroxyl group and proton are added to a compound * ...
and lower temperature rises, and makes avoiding
cold joint Soldering (; ) is a process in which two or more items are joined by melting and putting a filler metal (solder) into the joint, the filler metal having a lower melting point than the adjoining metal. Unlike welding, soldering does not involv ...
s easier, but may also affect construction schedules where quick setting is required. Use of GGBS significantly reduces the risk of damages caused by alkali–silica reaction (ASR), provides higher resistance to chloride ingress — reducing the risk of reinforcement corrosion — and provides higher resistance to attacks by sulfate and other chemicals.


How GGBS cement is used

GGBS cement can be added to concrete in the concrete manufacturer's batching plant, along with Portland cement, aggregates and water. The normal ratios of aggregates and water to cementitious material in the mix remain unchanged. GGBS is used as a direct replacement for Portland cement, on a one-to-one basis by weight. Replacement levels for GGBS vary from 30% to up to 85%. Typically 40 to 50% is used in most instances. The use of GGBS in addition to Portland cement in concrete in Europe is covered in the concrete standard EN 206:2013. This standard establishes two categories of additions to concrete along with ordinary Portland cement: nearly inert additions (Type I) and pozzolanic or latent hydraulic additions (Type II). GGBS cement falls in the latter category. As GGBS cement is slightly less expensive than Portland cement, concrete made with GGBS cement will be similarly priced to that made with ordinary Portland cement. It is used partially as per mix ratio.


Architectural and engineering benefits


Durability

GGBS cement is routinely specified in concrete to provide protection against both sulfate attack and chloride attack. GGBS has now effectively replaced sulfate-resisting Portland cement (SRPC) on the market for sulfate resistance because of its superior performance and greatly reduced cost compared to SRPC. Most projects in Dublin's Docklands, including Spencer Dock, are using GGBS in subsurface concrete for sulfate resistance. Bulk Electrical Resistivity is a test method that can measure the resistivity of concrete samples. (ASTM 1876-19) The higher electrical resistivity can be an indication of higher ion transfer resistivity and thus higher durability. By replacing up to 50% GGBS in concrete, researchers have shown that durability can be significantly improved. To protect against chloride attack, GGBS is used at a replacement level of 50% in concrete. Instances of chloride attack occur in reinforced concrete in marine environments and in road bridges where the concrete is exposed to splashing from road de-icing salts. In most
NRA The National Rifle Association of America (NRA) is a gun rights advocacy group based in the United States. Founded in 1871 to advance rifle marksmanship, the modern NRA has become a prominent gun rights lobbying organization while conti ...
projects in Ireland GGBS is now specified in structural concrete for bridge piers and abutments for protection against chloride attack. The use of GGBS in such instances will increase the life of the structure by up to 50% had only Portland cement been used, and precludes the need for more expensive
stainless steel Stainless steel is an alloy of iron that is resistant to rusting and corrosion. It contains at least 11% chromium and may contain elements such as carbon, other nonmetals and metals to obtain other desired properties. Stainless steel's corros ...
reinforcing. GGBS is also routinely used to limit the temperature rise in large concrete pours. The more gradual hydration of GGBS cement generates both lower peak and less total overall heat than Portland cement. This reduces thermal gradients in the concrete, which prevents the occurrence of microcracking which can weaken the concrete and reduce its durability, and was used for this purpose in the construction of the
Jack Lynch Tunnel The Jack Lynch Tunnel (Irish: ''Tollán Sheáin Uí Loingsigh'') is an immersed tube tunnel and an integral part of the N40 road network in Cork, Ireland. It is named after former Taoiseach, Jack Lynch, a native of Cork. It takes the road ...
in
Cork Cork or CORK may refer to: Materials * Cork (material), an impermeable buoyant plant product ** Cork (plug), a cylindrical or conical object used to seal a container ***Wine cork Places Ireland * Cork (city) ** Metropolitan Cork, also known as G ...
.


Appearance

In contrast to the stony grey of concrete made with Portland cement, the near-white color of GGBS cement permits architects to achieve a lighter color for exposed fair-faced concrete finishes, at no extra cost. To achieve a lighter color finish, GGBS is usually specified at between 50% to 70% replacement levels, although levels as high as 85% can be used. GGBS cement also produces a smoother, more defect-free surface, due to the fineness of the GGBS particles. Dirt does not adhere to GGBS concrete as easily as concrete made with Portland cement, reducing maintenance costs. GGBS cement prevents the occurrence of
efflorescence In chemistry, efflorescence (which means "to flower out" in French) is the migration of a salt to the surface of a porous material, where it forms a coating. The essential process involves the dissolving of an internally held salt in water, or ...
, the staining of concrete surfaces by calcium carbonate deposits. Due to its much lower lime content and lower permeability, GGBS is effective in preventing efflorescence when used at replacement levels of 50% to 60%.


Strength

Concrete containing GGBS cement has a higher ultimate strength than concrete made with Portland cement. It has a higher proportion of the strength-enhancing calcium silicate hydrates (CSH) than concrete made with Portland cement only, and a reduced content of free lime, which does not contribute to concrete strength. Concrete made with GGBS continues to gain strength over time, and has been shown to double its 28-day strength over periods of 10 to 12 years. The optimum dosage of Ground granulated blast-furnace slag (GGBS) for replacement in concrete was reported to be 20-30% by mass to provide higher compressive strength compared to the concrete made with only cement.


Sustainability

Since GGBS is a by-product of steel manufacturing process, its use in concrete is recognized by
LEED Leadership in Energy and Environmental Design (LEED) is a green building certification program used worldwide. Developed by the non-profit U.S. Green Building Council (USGBC), it includes a set of rating systems for the design, construction ...
, as well a
Building Environmental Assessment Method (BEAM) Plus
in Hong Kong, etc. as improving the sustainability of the project and will therefore add points towards LEED and BEAM Plus certifications. In this respect, GGBS can also be used for superstructure in addition to the cases where the concrete is in contact with chlorides and sulfates. This is provided that the slower setting time for casting of the superstructure is justified.


Notes


External links

* The Concrete Society, ''Cementitious Materials: The effect of GGBS,
fly ash Fly ash, flue ash, coal ash, or pulverised fuel ash (in the UK) plurale tantum: coal combustion residuals (CCRs)is a coal combustion product that is composed of the particulates (fine particles of burned fuel) that are driven out of coal-fired ...
, silica fume and limestone fines on the properties of concrete'
Cementitious materials


References

* * * * * {{Concrete navbox Amorphous solids Glass compositions Cement Concrete Materials