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Belite
Belite is an industrial mineral important in Portland cement manufacture. Its main constituent is dicalcium silicate, Ca2SiO4, sometimes formulated as 2 CaO · SiO2 (C2S in cement chemist notation). Etymology The name was given by Törnebohm in 1897 to a crystal identified in microscopic investigation of Portland cement. Belite is a name in common use in the cement industry, but is not a recognised mineral name. It occurs naturally as the mineral larnite, the name being derived from Larne, Northern Ireland, the closest town to Scawt Hill where it was discovered. Composition and structure The belite found in Portland cement differs in composition from pure dicalcium silicate. It is a solid solution and contains minor amounts of other oxides besides CaO and SiO2. A typical composition:Taylor H.F.W. (1990), ''Cement Chemistry'', Academic Press, 1990, , pp. 10-11. Based on this, the formula can be expressed as Ca1.94Mg0.02Na0.01K0.03Fe0.02Al0.07Si0.90P0.01O3.93. In practic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cement Chemist Notation
Cement chemist notation (CCN) was developed to simplify the formulas cement chemists use on a daily basis. It is a shorthand way of writing the chemical formula of oxides of calcium, silicon, and various metals. Abbreviations of oxides The main oxides present in cement (or in glass and ceramics) are abbreviated in the following way: Conversion of hydroxides in oxide and free water For the sake of mass balance calculations, hydroxides present in hydrated phases found in hardened cement paste, such as in portlandite, Ca(OH)2, must first be converted into oxide and water. To better understand the conversion process of hydroxide anions in oxide and water, it is necessary to consider the autoprotolysis of the hydroxyl anions; it implies a proton exchange between two OH−, like in a classical acid–base reaction: : + → + or also, :2 OH− → O2− + H2O For portlandite this gives thus the following mass balance: :Ca(OH)2 → CaO + H2O Thus portlandite can be written as Ca ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Portland Cement
Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th century by Joseph Aspdin, and is usually made from limestone. It is a fine powder, produced by heating limestone and clay minerals in a kiln to form clinker, grinding the clinker, and adding 2 to 3 percent of gypsum. Several types of portland cement are available. The most common, called ordinary portland cement (OPC), is grey, but white Portland cement is also available. Its name is derived from its resemblance to Portland stone which was quarried on the Isle of Portland in Dorset, England. It was named by Joseph Aspdin who obtained a patent for it in 1824. His son William Aspdin is regarded as the inventor of "modern" portland cement due to his developments in the 1840s. The low cost and widespread availability of the limestone, shales ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alite
Alite is an impure form of tricalcium silicate, , sometimes formulated as ( in cement chemist notation), typically with 3-4% of substituent oxides. It is the major, and characteristic, phase in Portland cement. The name was given by Törnebohm in 1897 to a crystal identified in microscopic investigation of Portland cement. Hatrurite is the name of a mineral that is substituted . Composition and structure The alite found in Portland cement differs in composition from simple tricalcium silicate. It is a solid solution and contains minor amounts of other oxides besides CaO and . A typical composition is: Based on this, the formula can be expressed as . In practice, the composition varies with the bulk composition of the clinker, subject to certain limits. Substitution of calcium ions or orthosilicate ions requires that electric charges be kept in balance. For instance, a limited number of orthosilicate () ions can be replaced with sulfate () ions, provided that for each sul ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Clinker (cement)
200px, Typical clinker nodules 200px, Hot clinker Cement clinker is a solid material produced in the manufacture of Portland cement as an intermediary product. Clinker occurs as lumps or nodules, usually to in diameter. It is produced by sintering (fusing together without melting to the point of liquefaction) limestone and aluminosilicate materials such as clay during the cement kiln stage. Composition and preparation The Portland clinker essentially consists of four mineral phases: two calcium silicates, alite (Ca3Si) and belite (Ca2Si), along with tricalcium aluminate (Ca3Al) and calcium aluminoferrite (Ca4AlFe). These main mineral phases are produced by heating at high temperature clays and limestone. Portland cement clinker is made by heating a homogeneous mixture of raw materials in a rotary kiln at high temperature. The products of the chemical reaction aggregate together at their sintering temperature, about . Aluminium oxide and iron oxide are present only as a f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calcium Silicate
Calcium silicate is the chemical compound Ca2SiO4, also known as calcium orthosilicate and is sometimes formulated as 2CaO·SiO2. It is also referred to by the shortened trade name Cal-Sil or Calsil. It occurs naturally as the mineral larnite. Properties Calcium silicate is a white free-flowing powder. It can be derived from naturally occurring limestone and diatomaceous earth, a siliceous sedimentary rock. It is one of a group of compounds that can be produced by reacting calcium oxide and silica in various ratios e.g. 3CaO·SiO2, alite (Ca3SiO5); 2CaO·SiO2, (Ca2SiO4); 3CaO·2SiO2, (Ca3SiO7); and CaO·SiO2, wollastonite (CaSiO3). It has a low bulk density and high physical water absorption. Use Calcium silicate is used as an anticaking agent in food preparation, including table salt and as an |
Larnite
Larnite is a calcium silicate mineral with formula: Ca2SiO4. It is the calcium member of the olivine group of minerals. It was first described from an occurrence at Scawt Hill, Larne, Northern Ireland in 1929 by Cecil Edgar Tilley and named for the location. At the type locality it occurs with wollastonite, spurrite, perovskite, merwinite, melilite and gehlenite. It occurs in contact metamorphosed limestones and chalks adjacent to basaltic intrusives. Dicalcium silicate is chemically, β–Ca2SiO4, sometimes represented by the formula 2CaO·SiO2. When used in the cement industry, the mineral is usually referred to as belite Belite is an industrial mineral important in Portland cement manufacture. Its main constituent is dicalcium silicate, Ca2SiO4, sometimes formulated as 2 CaO · SiO2 (C2S in cement chemist notation). Etymology The name was given by Törnebohm in .... References * Nesosilicates Monoclinic minerals Minerals in space group 14 {{silicate-mine ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Scawt Hill
Scawt Hill is a volcanic plug in County Antrim, Northern Ireland, in the borough of Larne, 5 km from the village of Ballygally. It gets its name from the Ulster Scots "" meaning scaly, scabby or rugged. Alternatively, '' 'scawt' '' meaning scruffy and contemptible, and when applied to rocks, covered in barnacles. Discovery of minerals Scawt Hill is notable for being the type locality for several hydrated calcium silicates, that is, the place where they were first identified. These minerals were formed when the existing chalk of the area was intensely altered by the intrusion of the feeder tube of an ancient volcano, now long since cooled and eroded to its roots.Wilson, H E et al (1986) Geological Survey of Northern Ireland, HMSO Minerals that were first discovered at Scawt Hill: * Larnite (''calcium orthosilicate'') a natural form of belite discovered in 1929 and named after Larne, the nearest town * Scawtite in 1929 * Portlandite in 1933 * Hydrocalumite in 1934 * Ran ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Portlandite
Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2). Occurrence Portlandite occurs in a variety of environments. At the type location in Northern Ireland it occurs as an alteration of calc–silicate rocks by contact metamorphism of larnite–spurrite. It occurs as fumarole deposits in the Vesuvius area. In Jebel Awq, Oman it occurs as precipitates from an alkaline spring emanating from ultramafic bedrock. In the Chelyabinsk coal basin of Russia it is produced by combustion of coal seams and similarly by spontaneous combustion of bitumen in the Hatrurim Formation of the Negev desert in Israel and the Maqarin area, Jordan. It also occurs in the manganese mining area of Kuruman, Cape Province, South Africa in the Kalahari Desert where it occurs as large crystals and masses. It occurs in association with afwillite, calcite, larnite, s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Forsterite
Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group ''Pbnm'') with cell parameters ''a'' 4.75 Å (0.475 nm), ''b'' 10.20 Å (1.020 nm) and ''c'' 5.98 Å (0.598 nm). Forsterite is associated with igneous and metamorphic rocks and has also been found in meteorites. In 2005 it was also found in cometary dust returned by the Stardust probe. In 2011 it was observed as tiny crystals in the dusty clouds of gas around a forming star. Two polymorphs of forsterite are known: wadsleyite (also orthorhombic) and ringwoodite ( isometric, Cubic crystal system). Both are mainly known from meteorites. Peridot is the gemstone variety of forsterite olivine. Composition Pure forsterite is composed of magnesium, oxygen and silicon. The chemical formula is Mg2SiO4. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Serpentinite
Serpentinite is a rock composed predominantly of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called ''serpentine'' or ''serpentine rock'', particularly in older geological texts and in wider cultural settings.California Government Code § 425.2; ''see'' Formation and mineralogy Serpentinite is formed by near to complete serpentinization of mafic to ultramafic rocks. Serpentinite can be formed wherever ultramafic rock is infiltrated by water poor in carbon dioxide. This occurs at mid-ocean ridges and in the forearc mantle of subduction zones. The final mineral composition of serpentinite is usually dominated by lizardite, chrysotile, and magnetite. Brucite and antigorite are less commonly present. Lizardite, chrysotile, and antigorite all have approximately the formula or , but differ in minor components and in form. Accessory minerals, present in smal ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Brucite
Brucite is the mineral form of magnesium hydroxide, with the chemical formula Mg( OH)2. It is a common alteration product of periclase in marble; a low-temperature hydrothermal vein mineral in metamorphosed limestones and chlorite schists; and formed during serpentinization of dunites. Brucite is often found in association with serpentine, calcite, aragonite, dolomite, magnesite, hydromagnesite, artinite, talc and chrysotile. It adopts a layered CdI2-like structure with hydrogen-bonds between the layers. Discovery Brucite was first described in 1824 by François Sulpice Beudant and named for the discoverer, American mineralogist, Archibald Bruce (1777–1818). A fibrous variety of brucite is called nemalite. It occurs in fibers or laths, usually elongated along 010 but sometimes 120 crystalline directions. Occurrence A notable location in the U.S. is Wood's Chrome Mine, Cedar Hill Quarry, Lancaster County, Pennsylvania. Yellow, white and blue Brucite with a botryoidal habit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Industrial Mineral
Industrial resources (minerals) are geological materials which are mined for their commercial value, which are not fuel (fuel minerals or mineral fuels) and are not sources of metals (metallic minerals) but are used in the industries based on their physical and/or chemical properties. They are used in their natural state or after beneficiation either as raw materials or as additives in a wide range of applications. Examples and applications Typical examples of industrial rocks and minerals are limestone, clays, sand, gravel, diatomite, kaolin, bentonite, silica, barite, gypsum, and talc. Some examples of applications for industrial minerals are construction, ceramics, paints, electronics, filtration, plastics, glass, detergents and paper. In some cases, even organic materials (peat) and industrial products or by-products (cement, slag, silica fume) are categorized under industrial minerals, as well as metallic compounds mainly utilized in non-metallic form (as an example most ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
