HOME

TheInfoList



OR:

A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a
polyatomic ion A polyatomic ion, also known as a molecular ion, is a covalent bonded set of two or more atoms, or of a metal complex, that can be considered to behave as a single unit and that has a net charge that is not zero. The term molecule may or may no ...
with the formula . The word ''carbonate'' may also refer to a
carbonate ester In organic chemistry, a carbonate ester (organic carbonate or organocarbonate) is an ester of carbonic acid. This functional group consists of a carbonyl group flanked by two alkoxy groups. The general structure of these carbonates is and the ...
, an organic compound containing the carbonate group C(=O)(O–)2. The term is also used as a verb, to describe carbonation: the process of raising the concentrations of carbonate and
bicarbonate In inorganic chemistry, bicarbonate (IUPAC-recommended nomenclature: hydrogencarbonate) is an intermediate form in the deprotonation of carbonic acid. It is a polyatomic anion with the chemical formula . Bicarbonate serves a crucial biochemi ...
ions in water to produce carbonated water and other carbonated beverageseither by the addition of
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is t ...
gas under pressure or by dissolving carbonate or bicarbonate salts into the water. In
geology Geology () is a branch of natural science concerned with Earth and other Astronomical object, astronomical objects, the features or rock (geology), rocks of which it is composed, and the processes by which they change over time. Modern geology ...
and mineralogy, the term "carbonate" can refer both to carbonate minerals and carbonate rock (which is made of chiefly carbonate minerals), and both are dominated by the carbonate ion, . Carbonate minerals are extremely varied and ubiquitous in chemically precipitated
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
. The most common are calcite or calcium carbonate, CaCO3, the chief constituent of
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms w ...
(as well as the main component of mollusc shells and
coral Corals are marine invertebrates within the class Anthozoa of the phylum Cnidaria. They typically form compact colonies of many identical individual polyps. Coral species include the important reef builders that inhabit tropical oceans and se ...
skeletons);
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
, a calcium-magnesium carbonate CaMg(CO3)2; and siderite, or
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
(II) carbonate, FeCO3, an important iron ore. Sodium carbonate ("soda" or "natron") and potassium carbonate ("potash") have been used since antiquity for cleaning and preservation, as well as for the manufacture of
glass Glass is a non- crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenchin ...
. Carbonates are widely used in industry, such as in iron smelting, as a raw material for
Portland cement Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19t ...
and lime manufacture, in the composition of ceramic glazes, and more.


Structure and bonding

The carbonate ion is the simplest oxocarbon anion. It consists of one
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon ma ...
atom surrounded by three
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
atoms, in a trigonal planar arrangement, with ''D''3h molecular symmetry. It has a molecular mass of 60.01  g/mol and carries a total formal charge of −2. It is the
conjugate base A conjugate acid, within the Brønsted–Lowry acid–base theory, is a chemical compound formed when an acid donates a proton () to a base—in other words, it is a base with a hydrogen ion added to it, as in the reverse reaction it loses a ...
of the hydrogencarbonate (bicarbonate) ion, , which is the conjugate base of , carbonic acid. The
Lewis structure Lewis structures, also known as Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDS), are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons ...
of the carbonate ion has two (long) single bonds to negative oxygen atoms, and one short double bond to a neutral oxygen atom. : This structure is incompatible with the observed symmetry of the ion, which implies that the three bonds are the same length and that the three oxygen atoms are equivalent. As in the case of the isoelectronic nitrate ion, the symmetry can be achieved by a
resonance Resonance describes the phenomenon of increased amplitude that occurs when the frequency of an applied periodic force (or a Fourier component of it) is equal or close to a natural frequency of the system on which it acts. When an oscil ...
among three structures: : This resonance can be summarized by a model with fractional bonds and delocalized charges: :


Chemical properties

Metal carbonates generally decompose on heating, liberating carbon dioxide from the long term
carbon cycle The carbon cycle is the biogeochemical cycle by which carbon is exchanged among the biosphere, pedosphere, geosphere, hydrosphere, and atmosphere of the Earth. Carbon is the main component of biological compounds as well as a major compon ...
to the short term carbon cycle and leaving behind an oxide of the metal. This process is called
calcination Calcination refers to thermal treatment of a solid chemical compound (e.g. mixed carbonate ores) whereby the compound is raised to high temperature without melting under restricted supply of ambient oxygen (i.e. gaseous O2 fraction of air), gen ...
, after ''calx'', the Latin name of quicklime or calcium oxide, CaO, which is obtained by roasting limestone in a
lime kiln A lime kiln is a kiln used for the calcination of limestone ( calcium carbonate) to produce the form of lime called quicklime (calcium oxide). The chemical equation for this reaction is : CaCO3 + heat → CaO + CO2 This reaction can take pla ...
. A carbonate salt forms when a positively charged ion, , , or , associates with the negatively charged oxygen atoms of the ion by forming electrostatic attractions with them, forming an ionic compound: : : : Most carbonate salts are
insoluble In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubi ...
in
water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
at standard temperature and pressure, with solubility constants of less than . Exceptions include
lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense soli ...
,
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
,
potassium Potassium is the chemical element with the symbol K (from Neo-Latin '' kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmos ...
, rubidium, caesium, and ammonium carbonates, as well as many
uranium carbonate Uranyl carbonate refers to the inorganic compound with the formula UO2CO3. Also known by its mineral name rutherfordine, this material consists of uranyl (UO22+) and carbonate (CO32-). Like most uranyl salts, the compound is a polymeric, each urani ...
s. In aqueous solution, carbonate, bicarbonate, carbon dioxide, and carbonic acid exist together in a dynamic equilibrium. In strongly basic conditions, the carbonate ion predominates, while in weakly basic conditions, the
bicarbonate In inorganic chemistry, bicarbonate (IUPAC-recommended nomenclature: hydrogencarbonate) is an intermediate form in the deprotonation of carbonic acid. It is a polyatomic anion with the chemical formula . Bicarbonate serves a crucial biochemi ...
ion is prevalent. In more acid conditions, aqueous
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is t ...
, CO2(aq), is the main form, which, with water, H2O, is in equilibrium with carbonic acidthe equilibrium lies strongly towards carbon dioxide. Thus sodium carbonate is basic, sodium bicarbonate is weakly basic, while carbon dioxide itself is a weak acid. Carbonated water is formed by dissolving CO2 in water under pressure. When the partial pressure of CO2 is reduced, for example when a can of soda is opened, the equilibrium for each of the forms of carbonate (carbonate, bicarbonate, carbon dioxide, and carbonic acid) shifts until the concentration of CO2 in the solution is equal to the solubility of CO2 at that temperature and pressure. In living systems an enzyme,
carbonic anhydrase The carbonic anhydrases (or carbonate dehydratases) () form a family of enzymes that catalyze the interconversion between carbon dioxide and water and the dissociated ions of carbonic acid (i.e. bicarbonate and hydrogen ions). The active sit ...
, speeds the interconversion of CO2 and carbonic acid. Although the carbonate salts of most metals are insoluble in water, the same is not true of the bicarbonate salts. In solution this equilibrium between carbonate, bicarbonate, carbon dioxide and carbonic acid changes constantly to the changing temperature and pressure conditions. In the case of metal ions with insoluble carbonates, such as CaCO3, formation of insoluble compounds results. This is an explanation for the buildup of scale inside pipes caused by hard water.


Carbonate in the inorganic nomenclature

Systematic additive IUPAC name for carbonate anion is trioxidocarbonate(2−). Similarly,
cyanide Cyanide is a naturally occurring, rapidly acting, toxic chemical that can exist in many different forms. In chemistry, a cyanide () is a chemical compound that contains a functional group. This group, known as the cyano group, consists of ...
anion CN is named nitridocarbonate(1−). However, following the same logic for carbonate(4−) ( orthocarbonic acid), by similitude to silicate(4−) (
orthosilicic acid Orthosilicic acid () is an inorganic compound with the formula . Although rarely observed, it is the key compound of silica and silicates and the precursor to other silicic acids . Silicic acids play important roles in biomineralization and ...
), in the systematic additive nomenclature makes no sense as this species has never been identified under normal conditions of temperature and pressure. Orthocarbonic acid is energetically much less stable than orthosilicic acid and cannot exist under normal conditions because of the energetically unfavorable orbital configuration of a single central carbon atom bound to four oxygen atoms.


Organic carbonates

In
organic chemistry Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, J ...
a carbonate can also refer to a
functional group In organic chemistry, a functional group is a substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the r ...
within a larger molecule that contains a carbon atom bound to three oxygen atoms, one of which is double bonded. These compounds are also known as organocarbonates or carbonate esters, and have the general formula ROCOOR′, or RR′CO3. Important organocarbonates include dimethyl carbonate, the cyclic compounds ethylene carbonate and
propylene carbonate Propylene carbonate (often abbreviated PC) is an organic compound with the formula C4H6O3. It is a cyclic carbonate ester derived from propylene glycol. This colorless and odorless liquid is useful as a polar, aprotic solvent. Propylene carbonat ...
, and the phosgene replacement, triphosgene.


Buffer

Three reversible reactions control the pH balance of blood and act as a buffer to stabilise it in the range 7.37–7.43: # # # Exhaled CO2(g) depletes CO2(aq), which in turn consumes H2CO3, causing the equilibrium of the first reaction to try to restore the level of carbonic acid by reacting bicarbonate with a hydrogen ion, an example of Le Châtelier's principle. The result is to make the blood more alkaline (raise pH). By the same principle, when the pH is too high, the kidneys excrete bicarbonate () into urine as urea via the
urea cycle The urea cycle (also known as the ornithine cycle) is a cycle of biochemical reactions that produces urea (NH2)2CO from ammonia (NH3). Animals that use this cycle, mainly amphibians and mammals, are called ureotelic. The urea cycle converts h ...
(or Krebs–Henseleit ornithine cycle). By removing the bicarbonate, more H+ is generated from carbonic acid (H2CO3), which comes from CO2(g) produced by
cellular respiration Cellular respiration is the process by which biological fuels are oxidised in the presence of an inorganic electron acceptor such as oxygen to produce large amounts of energy, to drive the bulk production of ATP. Cellular respiration may be des ...
. Crucially, a similar buffer operates in the oceans. It is a major factor in climate change and the long-term carbon cycle, due to the large number of marine organisms (especially coral) which are made of calcium carbonate. Increased solubility of carbonate through increased temperatures results in lower production of marine calcite and increased concentration of atmospheric carbon dioxide. This, in turn, increases Earth temperature. The amount of available is on a geological scale and substantial quantities may eventually be redissolved into the sea and released to the atmosphere, increasing CO2 levels even more.


Carbonate salts

* Carbonate overview:


Presence outside Earth

It is generally thought that the presence of carbonates in rock is strong evidence for the presence of liquid water. Recent observations of the planetary nebula NGC 6302 show evidence for carbonates in space, where aqueous alteration similar to that on Earth is unlikely. Other minerals have been proposed which would fit the observations. Until recently carbonate deposits have not been found on Mars via remote sensing or in situ missions, even though Martian meteorites contain small amounts. Groundwater may have existed at Gusev and Meridiani Planum.


See also

* Cap carbonates * Orthocarbonic acid, , or , a hypothetic unstable molecule * Oxalate * Peroxocarbonate * Sodium percarbonate


References


External links


Carbonate/bicarbonate/carbonic acid equilibrium in water: pH of solutions, buffer capacity, titration and species distribution vs. pH computed with a free spreadsheet
* {{Authority control Oxyanions