anglesite
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Anglesite is a
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
sulfate mineral The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary mine ...
with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore,
galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It cryst ...
. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with
barite Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...
and celestine. It contains 74% of
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
by mass and therefore has a high
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...
of 6.3. Anglesite's color is white or gray with pale yellow streaks. It may be dark gray if impure. It was first recognized as a mineral species by
William Withering William Withering FRS (17 March 1741 – 6 October 1799) was an English botanist, geologist, chemist, physician and first systematic investigator of the bioactivity of digitalis. Withering was born in Wellington, Shropshire, the son of a surg ...
in 1783, who discovered it in the
Parys Parys (pronounced ) is a town situated on the banks of the Vaal River in the Free State province of South Africa. The name of the town is the Afrikaans translation of Paris. The name was given by a German surveyor named Schilbach who had partic ...
copper-mine in
Anglesey Anglesey (; cy, (Ynys) Môn ) is an island off the north-west coast of Wales. It forms a principal area known as the Isle of Anglesey, that includes Holy Island across the narrow Cymyran Strait and some islets and skerries. Anglesey island ...
; the name anglesite, from this locality, was given by F. S. Beudant in 1832. The crystals from Anglesey, which were formerly found abundantly on a matrix of dull
limonite Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxid ...
, are small in size and simple in form, being usually bounded by four faces of a prism and four faces of a dome; they are brownish-yellow in colour owing to a stain of limonite. Crystals from some other localities, notably from in
Sardinia Sardinia ( ; it, Sardegna, label=Italian, Corsican and Tabarchino ; sc, Sardigna , sdc, Sardhigna; french: Sardaigne; sdn, Saldigna; ca, Sardenya, label=Algherese and Catalan) is the second-largest island in the Mediterranean Sea, after ...
, are transparent and colourless, possessed of a brilliant adamantine lustre, and usually modified by numerous bright faces. The variety of combinations and habits presented by the crystals is very extensive, nearly two hundred distinct forms being figured by V. von Lang in his monograph of the species; without measurement of the angles the crystals are frequently difficult to decipher. There are distinct cleavages parallel to the faces of the prism (110) and the
basal plane In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns th ...
(001), but these are not so well developed as in the isomorphous minerals barite and celestite. Anglesite is a mineral of secondary origin, having been formed by the oxidation of galena in the upper parts of mineral lodes where these have been affected by weathering processes. At Monteponi the crystals encrust cavities in glistening granular galena; and from
Leadhills Leadhills, originally settled for the accommodation of miners, is a village in South Lanarkshire, Scotland, WSW of Elvanfoot. The population in 1901 was 835. It was originally known as Waterhead. It is the second highest village in Scotland, ...
, in
Scotland Scotland (, ) is a country that is part of the United Kingdom. Covering the northern third of the island of Great Britain, mainland Scotland has a border with England to the southeast and is otherwise surrounded by the Atlantic Ocean to the ...
,
pseudomorph In mineralogy, a pseudomorph is a mineral or mineral compound that appears in an atypical form (crystal system), resulting from a substitution process in which the appearance and dimensions remain constant, but the original mineral is replaced by ...
s of anglesite after galena are known. At most localities it is found as isolated crystals in the lead-bearing lodes, but at some places, in
Australia Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
and
Mexico Mexico (Spanish: México), officially the United Mexican States, is a country in the southern portion of North America. It is bordered to the north by the United States; to the south and west by the Pacific Ocean; to the southeast by Guatema ...
, it occurs as large masses, and is then mined as an
ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
of lead. Anglesite is sometimes used as a gemstone.


Gallery

File:Anglesite-113492.jpg, Anglesite crystal from Touissit District, Morocco (size: 2.8×1.6×0.5 cm) File:Anglésite-Sardaigne.jpg, Anglesite from Monteponi Mine, Iglesias, Carbonia-Iglesias Province (size:15.3x7cm) Image:Anglesite.svg, Anglesite diagram illustrating its orthorhombic crystalline form


See also

Lead(II) sulfate Lead(II) sulfate (PbSO4) is a white solid, which appears white in microcrystalline form. It is also known as ''fast white'', ''milk white'', ''sulfuric acid lead salt'' or ''anglesite''. It is often seen in the plates/electrodes of car batteries ...


References


Bibliography

*Palache, P.; Berman H.; Frondel, C. (1960). "''Dana's System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. (Seventh Edition)"'' John Wiley and Sons, Inc., New York, pp. 420–424.


External links

{{Authority control Lead minerals Sulfate minerals Orthorhombic minerals Minerals in space group 62 Luminescent minerals Gemstones Baryte group