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Zerodur (notation of the manufacturer: ZERODUR®),
registered trademark
of
Schott AG Schott AG is a German multinational glass company specializing in the manufacture of glass and glass-ceramics. Headquartered in Mainz, Germany, it is owned by the Carl Zeiss Foundation. The company's founder and namesake, Otto Schott, is credi ...
, is a lithium-
aluminosilicate Aluminosilicate minerals ( IMA symbol: Als) are minerals composed of aluminium, silicon, and oxygen, plus countercations. They are a major component of kaolin and other clay minerals. Andalusite, kyanite, and sillimanite are naturally occurr ...
glass-ceramic Glass-ceramics are polycrystalline materials produced through controlled crystallization of base glass, producing a fine uniform dispersion of crystals throughout the bulk material. Crystallization is accomplished by subjecting suitable glasses to ...
produced by
Schott AG Schott AG is a German multinational glass company specializing in the manufacture of glass and glass-ceramics. Headquartered in Mainz, Germany, it is owned by the Carl Zeiss Foundation. The company's founder and namesake, Otto Schott, is credi ...
since 1968. It has been used for a number of very large telescope mirrors including GTC,
Keck I The W. M. Keck Observatory is an astronomical observatory with two telescopes at an elevation of 4,145 meters (13,600 ft) near the summit of Mauna Kea in the U.S. state of Hawaii. Both telescopes have aperture primary mirrors, and when com ...
, Keck II, and
SOFIA Sofia ( ; bg, София, Sofiya, ) is the capital and largest city of Bulgaria. It is situated in the Sofia Valley at the foot of the Vitosha mountain in the western parts of the country. The city is built west of the Iskar river, and ha ...
, as well as some smaller telescopes (such as the
GREGOR Solar Telescope GREGOR is a solar telescope, equipped with a 1.5 m primary mirror, located at 2,390 m altitude at the Teide Observatory on Tenerife in the Canary Islands. It replaces the older Gregory Coudé Telescope and was inaugurated on May 21, 2012. First l ...
). With its very low
coefficient of thermal expansion Thermal expansion is the tendency of matter to change its shape A shape or figure is a graphics, graphical representation of an object or its external boundary, outline, or external Surface (mathematics), surface, as opposed to other pro ...
(CTE) it can be used to produce mirrors that retain acceptable
figures Figure may refer to: General *A shape, drawing, depiction, or geometric configuration *Figure (wood), wood appearance *Figure (music), distinguished from musical motif *Noise figure, in telecommunication *Dance figure, an elementary dance patter ...
in extremely
cold Cold is the presence of low temperature, especially in the atmosphere. In common usage, cold is often a subjective perception. A lower bound to temperature is absolute zero, defined as 0.00K on the Kelvin scale, an absolute thermodynamic ...
environments such as deep space. Although it has advantages for applications requiring a
coefficient of thermal expansion Thermal expansion is the tendency of matter to change its shape A shape or figure is a graphics, graphical representation of an object or its external boundary, outline, or external Surface (mathematics), surface, as opposed to other pro ...
less than that of
borosilicate glass Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion (≈3 × 10−6 K−1 at 20 °C), ma ...
, it remains very expensive as compared to borosilicate. The tight tolerance on CTE, ±0.007 K−1, allows for its use in high-precision applications.


Applications

# Optics #
Microlithography Microlithography is a general name for any manufacturing process that can create a minutely patterned thin film of protective materials over a substrate, such as a silicon wafer, in order to protect selected areas of it during subsequent etching ...
# Measurement technology


Properties

Zerodur has both an
amorphous In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal. Etymology The term comes from the Greek ''a'' ("wi ...
(vitreous) component and a
crystalline A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...
component. Its most important properties are: * Particularly low
thermal expansion Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions. Temperature is a monotonic function of the average molecular kinetic ...
: in the range 0 to 50 °C it has a mean of 0 ± 0.007 K−1, which is two orders of magnitude better than that of fused quartz.
/ref> * High 3D Homogeneity (physics), homogeneity with few inclusions, bubbles and internal stria (as contrasted to
Cer-Vit Cer-vit is a family of glass-ceramic materials that were invented by Owens Illinois in the mid-1960s. Its principle ingredients are the oxides of lithium, aluminum and silicon. It is melted to form a glass which is then heat treated to nucleate and ...
). * Hardness similar to that of
borosilicate glass Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion (≈3 × 10−6 K−1 at 20 °C), ma ...
, so that it can be ground and polished more easily than
fused quartz Fused quartz, fused silica or quartz glass is a glass consisting of almost pure silica (silicon dioxide, SiO2) in amorphous (non-crystalline) form. This differs from all other commercial glasses in which other ingredients are added which change ...
. * High affinity for
coatings A coating is a covering that is applied to the surface of an object, usually referred to as the substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquids, gases or solids e.g. Powder ...
. * Low helium permeability. * Non-porous (as contrasted to
sintered Clinker nodules produced by sintering Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing ...
ceramics). * Good chemical stability similar to that of
fused quartz Fused quartz, fused silica or quartz glass is a glass consisting of almost pure silica (silicon dioxide, SiO2) in amorphous (non-crystalline) form. This differs from all other commercial glasses in which other ingredients are added which change ...
. *
Fracture toughness In materials science, fracture toughness is the critical stress intensity factor of a sharp crack where propagation of the crack suddenly becomes rapid and unlimited. A component's thickness affects the constraint conditions at the tip of a c ...
approximately 0.9 MPa·m1/2.


Physical properties

*
Dispersion Dispersion may refer to: Economics and finance *Dispersion (finance), a measure for the statistical distribution of portfolio returns *Price dispersion, a variation in prices across sellers of the same item *Wage dispersion, the amount of variatio ...
: (''n''F − ''n''C) = 0.00967 *
Density Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...
: 2.53 g/cm3 at 25 °C *
Young's modulus Young's modulus E, the Young modulus, or the modulus of elasticity in tension or compression (i.e., negative tension), is a mechanical property that measures the tensile or compressive stiffness of a solid material when the force is applied leng ...
: 9.1  Pa *
Poisson ratio In materials science and solid mechanics, Poisson's ratio \nu ( nu) is a measure of the Poisson effect, the deformation (expansion or contraction) of a material in directions perpendicular to the specific direction of loading. The value of Poi ...
: 0.24 *
Specific heat capacity In thermodynamics, the specific heat capacity (symbol ) of a substance is the heat capacity of a sample of the substance divided by the mass of the sample, also sometimes referred to as massic heat capacity. Informally, it is the amount of heat t ...
at 25 °C: 0.196 cal/(g·K) = 0.82 J/(g·K) *
Coefficient of thermal expansion Thermal expansion is the tendency of matter to change its shape A shape or figure is a graphics, graphical representation of an object or its external boundary, outline, or external Surface (mathematics), surface, as opposed to other pro ...
(20 °C to 300 °C) : 0.05 ± 0.10/K *
Thermal conductivity The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
: at 20 °C: 1.46 W/(m·K) * Maximum application temperature: 600 °C *
Impact resistance In materials science and metallurgy, toughness is the ability of a material to absorb energy and plastically deform without fracturing.glass Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenching) of ...


See also

*
CorningWare Corning Ware, also written CorningWare, was originally a brand name for a unique glass-ceramic (Pyroceram) cookware resistant to thermal shock. It was first introduced in 1958 by Corning Glass Works (later Corning Inc.) in the United States. The ...
*
Macor Macor is the trademark for a machinable glass-ceramic developed and sold by Corning Inc. It is a white material that looks somewhat like porcelain. Macor is a good thermal insulator and is stable up to temperatures of 1000 °C, with very li ...
*
Ring laser gyroscope A ring laser gyroscope (RLG) consists of a ring laser having two independent counter-propagating resonant modes over the same path; the difference in phase is used to detect rotation. It operates on the principle of the Sagnac effect which shifts ...
*
Sitall Sitall (also known as Sitall CO-115M or Astrositall) is a crystalline glass-ceramic with ultra-low coefficient of thermal expansion (CTE). It was originally manufactured in the former Soviet Union and was used in the making of primary mirrors for t ...


References


External links

{{Glass makers and brands Glass types Low-expansion glass Low thermal expansion materials Glass-ceramics Glass trademarks and brands Transparent materials German brands