Vitrolite
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Pigmented structural glass, also known generically as structural glass and as vitreous marble, and marketed under the names Carrara glass, Sani Onyx, and Vitrolite, among others, is a high-strength, colored
glass Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenching) of ...
. Developed in the United States in 1900, it was widely used around the world in the first half of the 20th century in
Art Deco Art Deco, short for the French ''Arts Décoratifs'', and sometimes just called Deco, is a style of visual arts, architecture, and product design, that first appeared in France in the 1910s (just before World War I), and flourished in the Unite ...
and
Streamline Moderne Streamline Moderne is an international style of Art Deco architecture and design that emerged in the 1930s. Inspired by aerodynamic design, it emphasized curving forms, long horizontal lines, and sometimes nautical elements. In industrial design ...
buildings. It also found use as a material for signs, tables, and areas requiring a hygienic surface. Over time, the trademarked name "vitrolite" became a generic term for the glass.


Overview

Pigmented structural glass was developed in 1900 in the United States by the Marrietta Manufacturing Company of
Indianapolis Indianapolis (), colloquially known as Indy, is the state capital and most populous city of the U.S. state of Indiana and the seat of Marion County. According to the U.S. Census Bureau, the consolidated population of Indianapolis and Marion ...
,
Indiana Indiana () is a U.S. state in the Midwestern United States. It is the 38th-largest by area and the 17th-most populous of the 50 States. Its capital and largest city is Indianapolis. Indiana was admitted to the United States as the 19th s ...
. The product was made by combining
borax Borax is a salt (ionic compound), a hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a basic solution. It is commonly available in powder or granular form, ...
,
cryolite Cryolite ( Na3 Al F6, sodium hexafluoroaluminate) is an uncommon mineral identified with the once-large deposit at Ivittuut on the west coast of Greenland, mined commercially until 1987. History Cryolite was first described in 1798 by Danish vete ...
,
kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral ...
,
manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
,
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
,
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldsp ...
, and
fluorspar Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...
. The
fluoride Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts typ ...
s made the glass opaque. These materials were fused into glass at a temperature of and then annealed. The annealing process took much longer than it did for
plate glass Plate glass, flat glass or sheet glass is a type of glass, initially produced in plane form, commonly used for windows, glass doors, transparent walls, and windscreens. For modern architectural and automotive applications, the flat glass is s ...
, often lasting three to five days. This left the glass very strong, with a
compressive strength In mechanics, compressive strength or compression strength is the capacity of a material or structure to withstand loads tending to reduce size (as opposed to tensile strength which withstands loads tending to elongate). In other words, compre ...
about 40 percent greater than
marble Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or Dolomite (mineral), dolomite. Marble is typically not Foliation (geology), foliated (layered), although there are exceptions. In geology, the ...
. If the product was to be affixed to another surface (such as the exterior of a building), one side of the slab was grooved before the glass hardened. The exposed side(s) of the material was flame polished, which left the product highly reflective and brilliant. Later manufacturing techniques used fine sand to polish the surface, followed by
felt Felt is a textile material that is produced by matting, condensing and pressing fibers together. Felt can be made of natural fibers such as wool or animal fur, or from synthetic fibers such as petroleum-based acrylic or acrylonitrile or wood ...
blocks and
iron(III) oxide Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturally ...
powder. Originally, only beige, black, and white colors were available. But by the 1930s, new manufacturing methods could make pigmented structure glass
translucent In the field of optics, transparency (also called pellucidity or diaphaneity) is the physical property of allowing light to pass through the material without appreciable scattering of light. On a macroscopic scale (one in which the dimensions a ...
, and more than 30 colors were available. In time, even
agate Agate () is a common rock formation, consisting of chalcedony and quartz as its primary components, with a wide variety of colors. Agates are primarily formed within volcanic and metamorphic rocks. The ornamental use of agate was common in Ancie ...
- and marble-like color patterns were available. Black structural glass was sometimes
silvered Silvering is the chemical process of coating a non-conductive substrate such as glass with a reflective substance, to produce a mirror. While the metal is often silver, the term is used for the application of any reflective metal. Process Mos ...
, to give it a reflective finish. Pigmented structural glass could be manufactured in flat panels or curves, and in a wide range of sizes and thicknesses. Small mosaic tiles, affixed to flexible fabric, were another option for fitting the product to curved surfaces. In time, manufacturers learned that pigmented structural glass could be carved, cut, inlaid, laminated, sandblasted, and sculpted to create a wide range of finishes and textures. When translucent, it could be illuminated from within.


Manufacturing history

Pigmented structural glass was originally marketed under the name "Sani Onyx" by Marrietta Manufacturing. The company also used the name "Sani Rox", while the term "vitreous marble" was coined by the firm as a general descriptive. By 1906, the
Pittsburgh Plate Glass Company PPG Industries, Inc. is an American Fortune 500 company and global supplier of paints, coatings, and specialty materials. With headquarters in Pittsburgh, Pittsburgh, Pennsylvania, PPG operates in more than 70 countries around the globe. By re ...
had developed its own pigmented structural glass, which it called "Carrara glass". The same year, the Penn-American Plate Company began making a pigmented structural glass which it called "Novus Sanitary Structural Glass". In 1916, The Vitrolite Company began manufacturing the product under the name "Vitrolite", which eventually became a generic name for pigmented structural glass. In time, about eight American firms made pigmented structural glass, although Carrara glass and Vitrolite dominated the market. Names used by these and other companies to market the product included "Argentine", "Glastone", "Marbrunite", "Nuralite", and "Opalite". Pigmented structural glass was also manufactured by
Pilkington Brothers Pilkington is a Japanese-owned glass-manufacturing company which is based in Lathom, Lancashire, United Kingdom. In the UK it includes several legal entities and is a subsidiary of Japanese company Nippon Sheet Glass, NSG Group. Prior to its a ...
in the
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the continental mainland. It comprises England, Scotland, Wales and North ...
. Marrietta Manufacturing originally marketed pigmented structural glass as a lining for refrigerators. Industrial consumers quickly found new uses for the product as countertops, dados, bathroom partitions, storefront signs, and tabletops. By the early 1920s, it was advertised as an inexpensive alternative to marble or ceramic tile. The Art Deco and Steamline Moderne architectural movements vastly increased the market for pigmented structural glass. Its first important architectural use came in 1912, when it was used for bathroom stall partitions and dados in the
Woolworth Building The Woolworth Building is an early skyscraper, early American skyscraper designed by architect Cass Gilbert located at 233 Broadway (Manhattan), Broadway in the Tribeca neighborhood of Manhattan in New York City. It was the tallest building in ...
in
New York City New York, often called New York City or NYC, is the List of United States cities by population, most populous city in the United States. With a 2020 population of 8,804,190 distributed over , New York City is also the L ...
. By 1929, of pigmented structural glass was being manufactured in the United States. Throughout the 1930s, the product also found a use as
cladding Cladding is an outer layer of material covering another. It may refer to the following: *Cladding (boiler), the layer of insulation and outer wrapping around a boiler shell *Cladding (construction), materials applied to the exterior of buildings ...
for storefronts, entryways, lobbies, and even as ceiling material. It was seen as an inexpensive means of making a dated building look modern. The Great Depression significantly reduced the demand for pigmented structural glass. American production reached only in 1933. By the 1950s, changing architectural tastes had vastly reduced the demand for the product. The last two American manufacturers ceased production about 1960: Libbey-Owens-Ford shut down its pigmented structural glass plant in 1958, followed by Pittsburgh Plate Glass in the early 1960s. Production continued in the United Kingdom until 1968, and in
Bavaria Bavaria ( ; ), officially the Free State of Bavaria (german: Freistaat Bayern, link=no ), is a state in the south-east of Germany. With an area of , Bavaria is the largest German state by land area, comprising roughly a fifth of the total lan ...
,
Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
, until the end of the 20th century.


Characteristics

Unlike
masonry Masonry is the building of structures from individual units, which are often laid in and bound together by mortar; the term ''masonry'' can also refer to the units themselves. The common materials of masonry construction are bricks, building ...
, pigmented structural glass does not craze, swell, or warp. It is highly burn and stain resistant, and is
colorfast Colour fastness is a term—used in the dyeing of textile materials—that characterizes a material's colour's resistance to fading or running. Colour fastness is the property of dyes and it is directly proportional to the binding force between pho ...
. Since it is a glass, it is impervious to moisture. It cannot absorb
pathogenic bacteria Pathogenic bacteria are bacteria that can cause disease. This article focuses on the bacteria that are pathogenic to humans. Most species of bacteria are harmless and are often Probiotic, beneficial but others can cause infectious diseases. The n ...
,
virus A virus is a submicroscopic infectious agent that replicates only inside the living cells of an organism. Viruses infect all life forms, from animals and plants to microorganisms, including bacteria and archaea. Since Dmitri Ivanovsky's 1 ...
es,
pathogenic fungi Pathogenic fungi are fungi that cause disease in humans or other organisms. Approximately 300 fungi are known to be pathogenic to humans. Markedly more fungi are known to be pathogenic to plant life than those of the animal kingdom. The study of fu ...
, or
parasites Parasitism is a Symbiosis, close relationship between species, where one organism, the parasite, lives on or inside another organism, the Host (biology), host, causing it some harm, and is Adaptation, adapted structurally to this way of lif ...
, and is easy to render
aseptic Asepsis is the state of being free from disease-causing micro-organisms (such as pathogenic bacteria, viruses, pathogenic fungi, and parasites). There are two categories of asepsis: medical and surgical. The modern day notion of asepsis is deriv ...
.


References

;Notes ;Citations


Bibliography

* * * * * * * * * *{{cite book, ref={{sfnRef, ''The Modern Hospital Yearbook'', 1919, author=, chapter=The Vitrolite Co., title=The Modern Hospital Yearbook, location=Chicago, publisher=The Modern Hospital Publishing Company, date=1919, chapter-url=https://books.google.com/books?id=NcoyAQAAMAAJ&q=vitrolite&pg=PA692 Glass trademarks and brands Building materials