chemistry Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions ...

and

fluid mechanics Fluid mechanics is the branch of physics concerned with the mechanics of fluids ( liquids, gases, and plasmas) and the forces on them. It has applications in a wide range of disciplines, including mechanical, aerospace, civil, chemical and bio ...

, the volume fraction φ_''i'' is defined as the volume of a constituent ''V''_''i'' divided by the volume of all constituents of the mixture ''V'' prior to mixing: :

\phi_i = \frac

Being

dimensionless A dimensionless quantity (also known as a bare quantity, pure quantity, or scalar quantity as well as quantity of dimension one) is a quantity to which no physical dimension is assigned, with a corresponding SI unit of measurement of one (or 1) ...

, its unit is 1; it is expressed as a number, e.g., 0.18. It is the same concept as volume percent (vol%) except that the latter is expressed with a

denominator A fraction (from la, fractus, "broken") represents a part of a whole or, more generally, any number of equal parts. When spoken in everyday English, a fraction describes how many parts of a certain size there are, for example, one-half, eight ...

of 100, e.g., 18%. The volume fraction coincides with the volume concentration in

ideal solution In chemistry, an ideal solution or ideal mixture is a solution that exhibits thermodynamic properties analogous to those of a mixture of ideal gases. The enthalpy of mixing is zero as is the volume change on mixing by definition; the closer to zero ...

s where the volumes of the constituents are additive (the volume of the solution is equal to the sum of the volumes of its ingredients). The sum of all volume fractions of a mixture is equal to 1: :

\sum_^ V_i = V ; \qquad \sum_^ \phi_i = 1

The volume fraction (percentage by volume, vol%) is one way of expressing the composition of a mixture with a

dimensionless quantity A dimensionless quantity (also known as a bare quantity, pure quantity, or scalar quantity as well as quantity of dimension one) is a quantity to which no physical dimension is assigned, with a corresponding SI unit of measurement of one (or 1) ...

; mass fraction (percentage by weight, wt%) and

mole fraction In chemistry, the mole fraction or molar fraction (''xi'' or ) is defined as unit of the amount of a constituent (expressed in moles), ''ni'', divided by the total amount of all constituents in a mixture (also expressed in moles), ''n''tot. This ex ...

(percentage by

moles Moles can refer to: * Moles de Xert, a mountain range in the Baix Maestrat comarca, Valencian Community, Spain * The Moles (Australian band) *The Moles, alter ego of Scottish band Simon Dupree and the Big Sound People *Abraham Moles, French engin ...

, mol%) are others.

Volume concentration and volume percent

Volume percent is the

concentration In chemistry, concentration is the abundance of a constituent divided by the total volume of a mixture. Several types of mathematical description can be distinguished: '' mass concentration'', ''molar concentration'', ''number concentration'', an ...

of a certain

solute In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solvent ...

, measured by volume, in a

solution Solution may refer to: * Solution (chemistry), a mixture where one substance is dissolved in another * Solution (equation), in mathematics ** Numerical solution, in numerical analysis, approximate solutions within specified error bounds * Soluti ...

. It has as a denominator the volume of the mixture itself, as usual for expressions of concentration, rather than the total of all the individual component's volumes prior to mixing: :

\text = \frac\text\text \times 100% = \text \times 100%

\varphi_i = \phi_i (1 - \frac)

Volume Volume is a measure of occupied three-dimensional space. It is often quantified numerically using SI derived units (such as the cubic metre and litre) or by various imperial or US customary units (such as the gallon, quart, cubic inch). The de ...

percent is usually used when the solution is made by mixing two

fluid In physics, a fluid is a liquid, gas, or other material that continuously deforms (''flows'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are substances which cannot resist any shear ...

s, such as

liquids A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a (nearly) constant volume independent of pressure. As such, it is one of the four fundamental states of matter (the others being solid, gas, an ...

gases Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...

. However,

percentages In mathematics, a percentage (from la, per centum, "by a hundred") is a number or ratio expressed as a fraction of 100. It is often denoted using the percent sign, "%", although the abbreviations "pct.", "pct" and sometimes "pc" are also u ...

are only additive for

ideal gas An ideal gas is a theoretical gas composed of many randomly moving point particles that are not subject to interparticle interactions. The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is a ...

es.''Volume-volume percentage''Chembuddy

website A website (also written as a web site) is a collection of web pages and related content that is identified by a common domain name and published on at least one web server. Examples of notable websites are Google Search, Google, Facebook, Amaz ...

The percentage by volume (vol%) is one way of expressing the composition of a mixture with a

; mass fraction (percentage by weight, wt%) and

(percentage by

, mol%) are others. Excess Volume Mixture of Ethanol and Water

In the case of a mixture of ethanol and water, which are

miscible Miscibility () is the property of two substances to mix in all proportions (that is, to fully dissolve in each other at any concentration), forming a homogeneous mixture (a solution). The term is most often applied to liquids but also applies ...

in all proportions, the designation of solvent and solute is arbitrary. The volume of such a mixture is slightly less than the sum of the volumes of the components. Thus, by the above definition, the term "40% alcohol by volume" refers to a mixture of 40 volume units of ethanol with enough water to make a final volume of 100 units, rather than a mixture of 40 units of ethanol with 60 units of water. The "enough water" is actually slightly more than 60 volume units, since water-ethanol mixture loses volume due to intermolecular attraction.

Relation to mass fraction

Volume fraction is related to mass fraction,

Y_i \equiv\frac  = \frac

Y_i = \frac ,  \rho _\equiv ,  \rho_m\equiv\sum_j

where

\rho_i\

is the constituent density, and

\rho_m

is the mixture density.

References

{{Chemical solutions Dimensionless numbers of chemistry Physical chemistry Thermodynamics Analytical chemistry

Volume concentration and volume percent

Relation to mass fraction

See also

References