Vitriol is the general

chemical A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., wi ...

name encompassing a class of

chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...

comprising

sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ar ...

s of certain metalsoriginally,

iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...

copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...

. Those mineral substances were distinguished by their color, such as green vitriol for hydrated

iron(II) sulfate Iron(II) sulfate (British English: iron(II) sulphate) or ferrous sulfate denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the heptahydrate (''x'' = 7) but several values for x are know ...

and blue vitriol for hydrated

copper(II) sulfate Copper(II) sulfate, also known as copper sulphate, is an inorganic compound with the chemical formula . It forms hydrates , where ''n'' can range from 1 to 7. The pentahydrate (''n'' = 5), a bright blue crystal, is the most commonly encountered h ...

.Vitriol
entry in the online Encyclopaedia Britannica. Accessed on 2020-08-28. These materials were originally found as crystals formed by evaporation of groundwater that percolated through

sulfide Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...

minerals and collected in pools on the floor of old

mine Mine, mines, miners or mining may refer to: Extraction or digging * Miner, a person engaged in mining or digging *Mining, extraction of mineral resources from the ground through a mine Grammar *Mine, a first-person English possessive pronoun ...

s. The word ''vitriol'' comes from the Latin word ''vitriolus'', meaning "small glass", as those crystals resembled pieces of colored glass. Oil of vitriol was an old name for concentrated

sulfuric acid Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formu ...

, which was historically obtained through the dry distillation (

pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...

) of vitriols. The name, shortened to vitriol, continued to be used for this viscous liquid long after the minerals came to be called "sulfates". The term ''vitriolic'' in the sense of "harshly condemnatory" is derived from the corrosive nature of this substance.

History

The study of vitriol began in

ancient times Ancient history is a time period from the beginning of writing and recorded human history to as far as late antiquity. The span of recorded history is roughly 5,000 years, beginning with the Sumerian cuneiform script. Ancient history cov ...

Sumer Sumer () is the earliest known civilization in the historical region of southern Mesopotamia (south-central Iraq), emerging during the Chalcolithic and early Bronze Ages between the sixth and fifth millennium BC. It is one of the cradles of c ...

ians had a list of types of vitriol that they classified according to the substances' color. Some of the earliest discussions on the origin and properties of vitriol is in the works of the Greek physician

Dioscorides Pedanius Dioscorides ( grc-gre, Πεδάνιος Διοσκουρίδης, ; 40–90 AD), “the father of pharmacognosy”, was a Greek physician, pharmacologist, botanist, and author of ''De materia medica'' (, On Medical Material) —a 5-vol ...

(first century AD) and the Roman naturalist

Pliny the Elder Gaius Plinius Secundus (AD 23/2479), called Pliny the Elder (), was a Roman author, naturalist and natural philosopher, and naval and army commander of the early Roman Empire, and a friend of the emperor Vespasian. He wrote the encyclopedic '' ...

(23–79 AD).

Galen Aelius Galenus or Claudius Galenus ( el, Κλαύδιος Γαληνός; September 129 – c. AD 216), often Anglicized as Galen () or Galen of Pergamon, was a Greek physician, surgeon and philosopher in the Roman Empire. Considered to be one of ...

also discussed its medical use. Metallurgical uses for vitriolic substances were recorded in the Hellenistic alchemical works of

Zosimos of Panopolis Zosimos of Panopolis ( el, Ζώσιμος ὁ Πανοπολίτης; also known by the Latin name Zosimus Alchemista, i.e. "Zosimus the Alchemist") was a Greco-Egyptian alchemist and Gnostic mystic who lived at the end of the 3rd and beginning ...

, in the treatise ''Phisica et Mystica'', and the

Leyden papyrus X The Leyden papyrus X (P. Leyden X) is a papyrus codex written in Greek at about the end of the 3rd century A.D.E.R.Caley, ''The Leyden Paprus X: An English Translation with Brief Notes''p.1149 "These two papyri have, however, upon the basis of unqu ...

. Medieval Islamic chemists like Jābir ibn Ḥayyān (died c. 806–816 AD, known in Latin as Geber), Abū Bakr al-Rāzī (865–925 AD, known in Latin as Rhazes),

Ibn Sina Ibn Sina ( fa, ابن سینا; 980 – June 1037 CE), commonly known in the West as Avicenna (), was a Persian polymath who is regarded as one of the most significant physicians, astronomers, philosophers, and writers of the Islamic G ...

(980–1037 AD, known in Latin as Avicenna), and Muḥammad ibn Ibrāhīm al-Watwat (1234–1318 AD) included vitriol in their mineral classification lists. Sulfuric acid was called "oil of vitriol" by medieval European alchemists because it was prepared by roasting "green vitriol" (

) in an iron

retort In a chemistry laboratory, a retort is a device used for distillation or dry distillation of substances. It consists of a spherical vessel with a long downward-pointing neck. The liquid to be distilled is placed in the vessel and heated. The ...

. The first vague allusions to it appear in the works of

Vincent of Beauvais Vincent of Beauvais ( la, Vincentius Bellovacensis or ''Vincentius Burgundus''; c. 1264) was a Dominican friar at the Cistercian monastery of Royaumont Abbey, France. He is known mostly for his ''Speculum Maius'' (''Great mirror''), a major work ...

, in the ''Compositum de Compositis'' ascribed to Saint

Albertus Magnus Albertus Magnus (c. 1200 – 15 November 1280), also known as Saint Albert the Great or Albert of Cologne, was a German Dominican friar, philosopher, scientist, and bishop. Later canonised as a Catholic saint, he was known during his life ...

, and in

pseudo-Geber Pseudo-Geber (or "Latin pseudo-Geber") is the presumed author or group of authors responsible for a corpus of pseudepigraphic alchemical writings dating to the late 13th and early 14th centuries. These writings were falsely attributed to Jabir ...

's ''Summa perfectionis'' (all thirteenth century AD)..

References

{{Authority control Sulfuric acid