Vibronic Laser

Vibronic coupling (also called nonadiabatic coupling or derivative coupling) in a molecule involves the interaction between electronic and nuclear vibrational motion. The term "vibronic" originates from the combination of the terms "vibrational" and "electronic", denoting the idea that in a molecule, vibrational and electronic interactions are interrelated and influence each other. The magnitude of vibronic coupling reflects the degree of such interrelation.

In theoretical chemistry, the vibronic coupling is neglected within the Born–Oppenheimer approximation. Vibronic couplings are crucial to the understanding of nonadiabatic processes, especially near points of conical intersections. The direct calculation of vibronic couplings is not common due to difficulties associated with its evaluation.

Definition

Vibronic coupling describes the mixing of different electronic states as a result of small vibrations.
:$\mathbf_\equiv\langle\,\chi_(\mathbf;\mathbf)\,, \, \hat_\mathbf\chi_k(\mathbf;\mathbf)\rangle_$

Evaluation

The evaluation of vibronic coupling often involve complex mathematical treatment.

Numerical gradients

The form of vibronic coupling is essentially the derivative of the wave function. Each component of the vibronic coupling vector can be calculated with numerical differentiation methods using wave functions at displaced geometries. This is the procedure used in MOLPRO.

First order accuracy can be achieved with forward difference formula:

:
(\mathbf_)_l\approx\frac\left \mathbf+d\mathbf_l)-\gamma^(\mathbf, \mathbf)\right

Second order accuracy can be achieved with central difference formula:

:
(\mathbf_)_l\approx\frac\left \mathbf+d\mathbf_l)-\gamma^(\mathbf, \mathbf-d\mathbf_l)\right

Here, $\mathbf_l$ is a unit vector along direction $l$. $\gamma^$ is the transition density between the two electronic states.

:$\gamma^(\mathbf_1, \mathbf_2)=\langle\chi_(\mathbf;\mathbf_1)\,, \,\chi_k(\mathbf;\mathbf_2)\rangle_$

Evaluation of electronic wave functions for both electronic states are required at N displacement geometries for first order accuracy and 2*N displacements to achieve second order accuracy, where N is the number of nuclear degrees of freedom. This can be extremely computationally demanding for large molecules.

As with other numerical differentiation method, the evaluation of nonadiabatic coupling vector with this method is numerically unstable, limiting the accuracy of the result. Moreover, the calculation of the two transition densities in the numerator are not straightforward. The wave functions of both electronic states are expanded with Slater determinants or Configuration state functions (CSF). The contribution from the change of CSF basis is too demanding to evaluate using numerical method, and is usually ignored by employing an approximate diabatic CSF basis. This will also cause further inaccuracy of the calculated coupling vector, although this error is usually tolerable.

Analytic gradient methods

Evaluating derivative couplings with analytic gradient methods has the advantage of high accuracy and very low cost, usually much cheaper than one single point calculation. This means an acceleration factor of 2N. However, the process involves intense mathematical treatment and programming. As a result, few programs have currently implemented analytic evaluation of vibronic couplings. Details about this method can be found in ref. For the implementation for SA-MCSCF and MRCI in COLUMBUS, please see ref.

Crossings and avoided crossings of potential energy surfaces

Vibronic coupling is large in the case of two adiabatic potential energy surfaces coming close to each other (that is, when the energy gap between them is of the order of magnitude of one oscillation quantum). This happens in the neighbourhood of an avoided crossing of potential energy surfaces corresponding to distinct electronic states of the same spin symmetry. At the vicinity of conical intersections, where the potential energy surfaces of the same spin symmetry cross, the magnitude of vibronic coupling approaches infinity. In either case the adiabatic or Born–Oppenheimer approximation fails and vibronic couplings have to be taken into account.

The large magnitude of vibronic coupling near avoided crossings and conical intersections allows wave functions to propagate from one adiabatic potential energy surface to another, giving rise to nonadiabatic phenomena such as radiationless decay. The singularity of vibronic coupling at conical intersections is responsible for the existence of Geometric phase, which was discovered by Longuet-HigginsSee page 12 in this context. Geometric phase around the conical intersection involving the ground
electronic state of the C₆H₃F₃⁺
molecular ion is discussed on pages 385-386 of the textbook by
Bunker and Jensen.''Molecular Symmetry and Spectroscopy'',
2nd ed. Philip R. Bunker and Per Jensen, NRC Research Press,
Ottawa (1998

Difficulties and alternatives

Although crucial to the understanding of nonadiabatic processes, direct evaluation of vibronic couplings has been very limited.

Evaluation of vibronic couplings is often associated with severe difficulties in mathematical formulation and program implementations. As a result, the algorithms to evaluate vibronic couplings are not yet implemented in many quantum chemistry program suites.

The evaluation of vibronic couplings also requires correct description of at least two electronic states in regions where they are strongly coupled. This requires the use of multi-reference methods such as MCSCF and MRCI, which are computationally demanding and delicate quantum-chemical methods. This is further complicated by the fact that definition of vibronic couplings requires electronic wave functions. Unfortunately, wave function based methods are usually too expensive for larger systems and popular methods for larger systems such as density functional theory and molecular mechanics cannot generate wave function information.
As a result, direct evaluation of vibronic couplings are mostly limited to very small molecules. The magnitude of vibronic coupling is often introduced as an empirical parameter determined by reproducing experimental data.

Alternatively, one can avoid explicit use of derivative couplings by switch from the adiabatic to the diabatic representation of the potential energy surfaces. Although rigorous validation of a diabatic representation requires knowledge of vibronic coupling, it is often possible to construct such diabatic representations by referencing the continuity of physical quantities such as dipole moment, charge distribution or orbital occupations. However, such construction requires detailed knowledge of a molecular system and introduces significant arbitrariness. Diabatic representations constructed with different method can yield different results and the reliability of the result relies on the discretion of the researcher.

Theoretical development

The first discussion of the effect of vibronic coupling on molecular spectra is given in the paper by Herzberg and Teller.
Although the Herzberg-Teller effect appears to be the result of either vibronic coupling or the dependence of the electronic transition moment on the nuclear coordinates, it can be shown that these two apparently different causes of the Herzberg-Teller effect in a spectrum are two manifestations of the same phenomenon (see Section 14.1.9 of the book by Bunker and Jensen).
Calculations of the lower excited levels of benzene by Sklar in 1937 (with the valence bond method) and later in 1938 by Goeppert-Mayer and Sklar (with the molecular orbital method) demonstrated a correspondence between the theoretical predictions and experimental results of the benzene spectrum. The benzene spectrum was the first qualitative computation of the efficiencies of various vibrations at inducing intensity absorption.

See also

* Jahn-Teller effect
*Born–Huang approximation
* Born–Oppenheimer approximation
*Conical intersection

References

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Quantum chemistry
Molecular vibration
Dynamics (mechanics)