Vauquelinite is a complex mineral with the formula
Cu Pb2(
Cr O4)(
PO
4)(O
H) making it a combined
chromate and
phosphate
In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid .
The phosphate or orthophosphate ion is derived from phospho ...
of
copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
and
lead
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
. It forms a series with the
arsenate mineral
Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or (v ...
fornacite
Fornacite is a rare lead, copper chromate arsenate hydroxide mineral with the formula: Pb2Cu(CrO4)(AsO4)(OH). It forms a series with the phosphate mineral vauquelinite. It forms variably green to yellow, translucent to transparent crystals in t ...
.
[
It was first described in 1818 in the ]Beryozovskoye deposit
Beryozovskoye deposit, Berezovskoe gold deposit, Berezovsky deposit, Berezovsk Mines, and some other names (russian: Берёзовское месторождение) is the first known primary deposit of gold in Russia. It is located 13 km nort ...
, Urals
The Ural Mountains ( ; rus, Ура́льские го́ры, r=Uralskiye gory, p=ʊˈralʲskʲɪjə ˈɡorɨ; ba, Урал тауҙары) or simply the Urals, are a mountain range that runs approximately from north to south through European ...
, Russia
Russia (, , ), or the Russian Federation, is a List of transcontinental countries, transcontinental country spanning Eastern Europe and North Asia, Northern Asia. It is the List of countries and dependencies by area, largest country in the ...
, and named for Louis Vauquelin
Prof. Louis Nicolas Vauquelin FRS(For) HFRSE (16 May 1763 – 14 November 1829) was a French pharmacist and chemist. He was the discoverer of both chromium and beryllium.
Early life
Vauquelin was born at Saint-André-d'Hébertot in Normandy, F ...
(1763–1829), a French chemist.[ It occurs in ]oxidized
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
ore deposits and is associated with crocoite
Crocoite is a mineral consisting of lead chromate, Pb Cr O4, and crystallizing in the monoclinic crystal system. It is identical in composition with the artificial product chrome yellow used as a paint pigment.
Description
Crocoite is commo ...
, pyromorphite
Pyromorphite is a mineral species composed of lead chlorophosphate: Pb5( P O4)3 Cl, sometimes occurring in sufficient abundance to be mined as an ore of lead. Crystals are common, and have the form of a hexagonal prism terminated by the basal pla ...
, mimetite
Mimetite is a lead arsenate chloride mineral (Pb5(AsO4)3Cl) which forms as a secondary mineral in lead deposits, usually by the oxidation of galena and arsenopyrite. The name derives from the Greek Μιμητής ''mimetes'', meaning "imitator" a ...
, cerussite
Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate (PbCO3), and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was mentioned by Conrad Gessner ...
, beudantite
Beudandite is a secondary mineral occurring in the oxidized zones of polymetallic deposits. It is a lead, iron, arsenate, sulfate with endmember formula: PbFe3(OH)6SO4AsO4.
Beudantite is in a subgroup of the alunite group. It is the arsenate an ...
and duftite
Duftite is a relatively common arsenate mineral with the formula CuPb(AsO4)(OH), related to conichalcite. It is green and often forms botryoidal aggregates. It is a member of the adelite- descloizite Group, Conichalcite-Duftite Series. Duftite ...
at the type locality in Russia.[
]
References
Copper(II) minerals
Lead minerals
Chromate minerals
Phosphate minerals
Monoclinic minerals
Minerals in space group 14
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