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A vacuum is a space devoid of matter. The word is derived from the Latin adjective ''vacuus'' for "vacant" or " void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often discuss ideal test results that would occur in a ''perfect'' vacuum, which they sometimes simply call "vacuum" or free space, and use the term partial vacuum to refer to an actual imperfect vacuum as one might have in a laboratory or in space. In engineering and applied physics on the other hand, vacuum refers to any space in which the pressure is considerably lower than atmospheric pressure. The Latin term ''in vacuo'' is used to describe an object that is surrounded by a vacuum. The ''quality'' of a partial vacuum refers to how closely it approaches a perfect vacuum. Other things equal, lower gas pressure means higher-quality vacuum. For example, a typical vacuum cleaner produces enough
suction Suction is the colloquial term to describe the air pressure differential between areas. Removing air from a space results in a pressure differential. Suction pressure is therefore limited by external air pressure. Even a perfect vacuum cannot ...
to reduce air pressure by around 20%. But higher-quality vacuums are possible. Ultra-high vacuum chambers, common in chemistry, physics, and engineering, operate below one trillionth (10−12) of atmospheric pressure (100 nPa), and can reach around 100 particles/cm3. Outer space is an even higher-quality vacuum, with the equivalent of just a few hydrogen atoms per cubic meter on average in intergalactic space. This source estimates a density of for the Local Group. An atomic mass unit is , for roughly 40 atoms per cubic meter. Vacuum has been a frequent topic of philosophical debate since ancient Greek times, but was not studied empirically until the 17th century. Evangelista Torricelli produced the first laboratory vacuum in 1643, and other experimental techniques were developed as a result of his theories of atmospheric pressure. A Torricellian vacuum is created by filling with mercury a tall glass container closed at one end, and then inverting it in a bowl to contain the mercury (see below). Vacuum became a valuable industrial tool in the 20th century with the introduction of incandescent light bulbs and vacuum tubes, and a wide array of vacuum technologies has since become available. The development of
human spaceflight Human spaceflight (also referred to as manned spaceflight or crewed spaceflight) is spaceflight with a crew or passengers aboard a spacecraft, often with the spacecraft being operated directly by the onboard human crew. Spacecraft can also be ...
has raised interest in the impact of vacuum on human health, and on life forms in general.


Etymology

The word ''vacuum'' comes , noun use of neuter of ''vacuus'', meaning "empty", related to ''vacare'', meaning "to be empty". ''Vacuum'' is one of the few words in the English language that contains two consecutive vowels u.


Historical understanding

Historically, there has been much dispute over whether such a thing as a vacuum can exist. Ancient Greek philosophers debated the existence of a vacuum, or void, in the context of atomism, which posited void and atom as the fundamental explanatory elements of physics. Following Plato, even the abstract concept of a featureless void faced considerable skepticism: it could not be apprehended by the senses, it could not, itself, provide additional explanatory power beyond the physical volume with which it was commensurate and, by definition, it was quite literally nothing at all, which cannot rightly be said to exist. Aristotle believed that no void could occur naturally, because the denser surrounding material continuum would immediately fill any incipient rarity that might give rise to a void. In his '' Physics'', book IV, Aristotle offered numerous arguments against the void: for example, that motion through a medium which offered no impediment could continue ''ad infinitum'', there being no reason that something would come to rest anywhere in particular. Lucretius argued for the existence of vacuum in the first century BC and Hero of Alexandria tried unsuccessfully to create an artificial vacuum in the first century AD. In the medieval Muslim world, the physicist and Islamic scholar Al-Farabi wrote a treatise rejecting the existence of the vacuum in the 10th century. He concluded that air's volume can expand to fill available space, and therefore the concept of a perfect vacuum was incoherent. According to Nader El-Bizri, the physicist Ibn al-Haytham and the
Mu'tazili Muʿtazila ( ar, المعتزلة ', English: "Those Who Withdraw, or Stand Apart", and who called themselves ''Ahl al-ʿAdl wa al-Tawḥīd'', English: "Party of ivineJustice and Oneness f God); was an Islamic group that appeared in early Islamic ...
theologians disagreed with Aristotle and Al-Farabi, and they supported the existence of a void. Using geometry, Ibn al-Haytham
mathematically Mathematics is an area of knowledge that includes the topics of numbers, formulas and related structures, shapes and the spaces in which they are contained, and quantities and their changes. These topics are represented in modern mathematics ...
demonstrated that place (''al-makan'') is the imagined three-dimensional void between the inner surfaces of a containing body. According to Ahmad Dallal, Abū Rayhān al-Bīrūnī also states that "there is no observable evidence that rules out the possibility of vacuum". The
suction Suction is the colloquial term to describe the air pressure differential between areas. Removing air from a space results in a pressure differential. Suction pressure is therefore limited by external air pressure. Even a perfect vacuum cannot ...
pump A pump is a device that moves fluids (liquids or gases), or sometimes slurries, by mechanical action, typically converted from electrical energy into hydraulic energy. Pumps can be classified into three major groups according to the method they u ...
was described by Arab engineer
Al-Jazari Badīʿ az-Zaman Abu l-ʿIzz ibn Ismāʿīl ibn ar-Razāz al-Jazarī (1136–1206, ar, بديع الزمان أَبُ اَلْعِزِ إبْنُ إسْماعِيلِ إبْنُ الرِّزاز الجزري, ) was a polymath: a scholar, ...
in the 13th century, and later appeared in Europe from the 15th century. Donald Routledge Hill, "Mechanical Engineering in the Medieval Near East", ''Scientific American'', May 1991, pp. 64–69 ( cf. Donald Routledge Hill
Mechanical Engineering
).
European
scholars A scholar is a person who pursues academic and intellectual activities, particularly academics who apply their intellectualism into expertise in an area of study. A scholar can also be an academic, who works as a professor, teacher, or researcher ...
such as
Roger Bacon Roger Bacon (; la, Rogerus or ', also '' Rogerus''; ), also known by the scholastic accolade ''Doctor Mirabilis'', was a medieval English philosopher and Franciscan friar who placed considerable emphasis on the study of nature through empiri ...
, Blasius of Parma and Walter Burley in the 13th and 14th century focused considerable attention on issues concerning the concept of a vacuum. Eventually following Stoic physics in this instance, scholars from the 14th century onward increasingly departed from the Aristotelian perspective in favor of a
supernatural Supernatural refers to phenomena or entities that are beyond the laws of nature. The term is derived from Medieval Latin , from Latin (above, beyond, or outside of) + (nature) Though the corollary term "nature", has had multiple meanings si ...
void beyond the confines of the cosmos itself, a conclusion widely acknowledged by the 17th century, which helped to segregate natural and theological concerns. Almost two thousand years after Plato, René Descartes also proposed a geometrically based alternative theory of atomism, without the problematic nothing–everything
dichotomy A dichotomy is a partition of a whole (or a set) into two parts (subsets). In other words, this couple of parts must be * jointly exhaustive: everything must belong to one part or the other, and * mutually exclusive: nothing can belong simulta ...
of void and atom. Although Descartes agreed with the contemporary position, that a vacuum does not occur in nature, the success of his namesake coordinate system and more implicitly, the spatial–corporeal component of his metaphysics would come to define the philosophically modern notion of empty space as a quantified extension of volume. By the ancient definition however, directional information and magnitude were conceptually distinct. Medieval thought experiments into the idea of a vacuum considered whether a vacuum was present, if only for an instant, between two flat plates when they were rapidly separated. There was much discussion of whether the air moved in quickly enough as the plates were separated, or, as Walter Burley postulated, whether a 'celestial agent' prevented the vacuum arising. The commonly held view that nature abhorred a vacuum was called ''
horror vacui Horror vacui can refer to: * Horror vacui (art), a concept in art approximately translated from Latin ''fear of empty spaces'' *Horror vacui (physics), a physical postulate * ''Horror Vacui'' (film), a 1984 German satirical film * ''Horror Vacui' ...
''. There was even speculation that even God could not create a vacuum if he wanted and the 1277 Paris condemnations of Bishop Etienne Tempier, which required there to be no restrictions on the powers of God, led to the conclusion that God could create a vacuum if he so wished. Jean Buridan reported in the 14th century that teams of ten horses could not pull open bellows when the port was sealed. The 17th century saw the first attempts to quantify measurements of partial vacuum. Evangelista Torricelli's
mercury Mercury commonly refers to: * Mercury (planet), the nearest planet to the Sun * Mercury (element), a metallic chemical element with the symbol Hg * Mercury (mythology), a Roman god Mercury or The Mercury may also refer to: Companies * Merc ...
barometer of 1643 and
Blaise Pascal Blaise Pascal ( , , ; ; 19 June 1623 – 19 August 1662) was a French mathematician, physicist, inventor, philosopher, and Catholic Church, Catholic writer. He was a child prodigy who was educated by his father, a tax collector in Rouen. Pa ...
's experiments both demonstrated a partial vacuum. In 1654,
Otto von Guericke Otto von Guericke ( , , ; spelled Gericke until 1666; November 20, 1602 – May 11, 1686 ; November 30, 1602 – May 21, 1686 ) was a German scientist, inventor, and politician. His pioneering scientific work, the development of experimental me ...
invented the first vacuum pump and conducted his famous Magdeburg hemispheres experiment, showing that, owing to atmospheric pressure outside the hemispheres, teams of horses could not separate two hemispheres from which the air had been partially evacuated. Robert Boyle improved Guericke's design and with the help of
Robert Hooke Robert Hooke FRS (; 18 July 16353 March 1703) was an English polymath active as a scientist, natural philosopher and architect, who is credited to be one of two scientists to discover microorganisms in 1665 using a compound microscope that ...
further developed vacuum pump technology. Thereafter, research into the partial vacuum lapsed until 1850 when
August Toepler August Joseph Ignaz Toepler (7 September 1836 – 6 March 1912) was a German chemist and physicist known for his experiments in electrostatics. Biography August Toepler was born on 7 September 1836. He studied chemistry at the Gewerbe-Insti ...
invented the Toepler pump and in 1855 when Heinrich Geissler invented the mercury displacement pump, achieving a partial vacuum of about 10 Pa (0.1  Torr). A number of electrical properties become observable at this vacuum level, which renewed interest in further research. While outer space provides the most rarefied example of a naturally occurring partial vacuum, the heavens were originally thought to be seamlessly filled by a rigid indestructible material called
aether Aether, æther or ether may refer to: Metaphysics and mythology * Aether (classical element), the material supposed to fill the region of the universe above the terrestrial sphere * Aether (mythology), the personification of the "upper sky", sp ...
. Borrowing somewhat from the pneuma of Stoic physics, aether came to be regarded as the rarefied air from which it took its name, (see
Aether (mythology) In Greek mythology, Aether, Æther, Aither, or Ether (; grc, Αἰθήρ (Brightness) ) is the personification of the bright upper sky. According to Hesiod, he was the son of Erebus (Darkness) and Nyx (Night), and the brother of Hemera (Day). ...
). Early theories of light posited a ubiquitous terrestrial and celestial medium through which light propagated. Additionally, the concept informed Isaac Newton's explanations of both refraction and of radiant heat. 19th century experiments into this luminiferous aether attempted to detect a minute drag on the Earth's orbit. While the Earth does, in fact, move through a relatively dense medium in comparison to that of interstellar space, the drag is so minuscule that it could not be detected. In 1912, astronomer Henry Pickering commented: "While the interstellar absorbing medium may be simply the ether, tis characteristic of a gas, and free gaseous molecules are certainly there". Later, in 1930, Paul Dirac proposed a model of the vacuum as an infinite sea of particles possessing negative energy, called the Dirac sea. This theory helped refine the predictions of his earlier formulated Dirac equation, and successfully predicted the existence of the
positron The positron or antielectron is the antiparticle or the antimatter counterpart of the electron. It has an electric charge of +1 '' e'', a spin of 1/2 (the same as the electron), and the same mass as an electron. When a positron collides ...
, confirmed two years later. Werner Heisenberg's uncertainty principle, formulated in 1927, predicted a fundamental limit within which instantaneous position and
momentum In Newtonian mechanics, momentum (more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. If is an object's mass an ...
, or energy and time can be measured. This has far reaching consequences on the "emptiness" of space between particles. In the late 20th century, so-called virtual particles that arise spontaneously from empty space were confirmed.


Classical field theories

The strictest criterion to define a vacuum is a region of space and time where all the components of the
stress–energy tensor The stress–energy tensor, sometimes called the stress–energy–momentum tensor or the energy–momentum tensor, is a tensor physical quantity that describes the density and flux of energy and momentum in spacetime, generalizing the stress ...
are zero. This means that this region is devoid of energy and momentum, and by consequence, it must be empty of particles and other physical fields (such as electromagnetism) that contain energy and momentum.


Gravity

In general relativity, a vanishing stress–energy tensor implies, through Einstein field equations, the vanishing of all the components of the Ricci tensor. Vacuum does not mean that the curvature of
space-time In physics, spacetime is a mathematical model that combines the three-dimensional space, three dimensions of space and one dimension of time into a single four-dimensional manifold. Minkowski diagram, Spacetime diagrams can be used to visualize S ...
is necessarily flat: the gravitational field can still produce curvature in a vacuum in the form of tidal forces and
gravitational wave Gravitational waves are waves of the intensity of gravity generated by the accelerated masses of an orbital binary system that propagate as waves outward from their source at the speed of light. They were first proposed by Oliver Heaviside in 1 ...
s (technically, these phenomena are the components of the
Weyl tensor In differential geometry, the Weyl curvature tensor, named after Hermann Weyl, is a measure of the curvature of spacetime or, more generally, a pseudo-Riemannian manifold. Like the Riemann curvature tensor, the Weyl tensor expresses the tidal forc ...
). The
black hole A black hole is a region of spacetime where gravitation, gravity is so strong that nothing, including light or other Electromagnetic radiation, electromagnetic waves, has enough energy to escape it. The theory of general relativity predicts t ...
(with zero electric charge) is an elegant example of a region completely "filled" with vacuum, but still showing a strong curvature.


Electromagnetism

In classical electromagnetism, the vacuum of free space, or sometimes just ''free space'' or ''perfect vacuum'', is a standard reference medium for electromagnetic effects. Some authors refer to this reference medium as ''classical vacuum'', a terminology intended to separate this concept from QED vacuum or QCD vacuum, where vacuum fluctuations can produce transient virtual particle densities and a relative permittivity and relative permeability that are not identically unity.For a qualitative description of vacuum fluctuations and virtual particles, see The relative permeability and permittivity of field-theoretic vacuums is described in and more recently in and also QCD vacuum is paramagnetic, while QED vacuum is diamagnetic. See In the theory of classical electromagnetism, free space has the following properties: * Electromagnetic radiation travels, when unobstructed, at the speed of light, the defined value 299,792,458 m/s in
SI units The International System of Units, known by the international abbreviation SI in all languages and sometimes Pleonasm#Acronyms and initialisms, pleonastically as the SI system, is the modern form of the metric system and the world's most wid ...
. * The
superposition principle The superposition principle, also known as superposition property, states that, for all linear systems, the net response caused by two or more stimuli is the sum of the responses that would have been caused by each stimulus individually. So tha ...
is always exactly true. For example, the electric potential generated by two charges is the simple addition of the potentials generated by each charge in isolation. The value of the
electric field An electric field (sometimes E-field) is the physical field that surrounds electrically charged particles and exerts force on all other charged particles in the field, either attracting or repelling them. It also refers to the physical field fo ...
at any point around these two charges is found by calculating the vector sum of the two electric fields from each of the charges acting alone. * The permittivity and permeability are exactly the electric constant and magnetic constant , respectively (in
SI units The International System of Units, known by the international abbreviation SI in all languages and sometimes Pleonasm#Acronyms and initialisms, pleonastically as the SI system, is the modern form of the metric system and the world's most wid ...
), or exactly 1 (in Gaussian units). * The
characteristic impedance The characteristic impedance or surge impedance (usually written Z0) of a uniform transmission line is the ratio of the amplitudes of voltage and current of a single wave propagating along the line; that is, a wave travelling in one direction in ...
() equals the impedance of free space ≈ 376.73 Ω. The vacuum of classical electromagnetism can be viewed as an idealized electromagnetic medium with the constitutive relations in SI units: :\boldsymbol D(\boldsymbol r,\ t) = \varepsilon_0 \boldsymbol E(\boldsymbol r,\ t)\, :\boldsymbol H(\boldsymbol r,\ t) = \frac \boldsymbol B(\boldsymbol r,\ t)\, relating the
electric displacement In physics, the electric displacement field (denoted by D) or electric induction is a vector field that appears in Maxwell's equations. It accounts for the effects of free and bound charge within materials. "D" stands for "displacement", as in ...
field to the
electric field An electric field (sometimes E-field) is the physical field that surrounds electrically charged particles and exerts force on all other charged particles in the field, either attracting or repelling them. It also refers to the physical field fo ...
and the
magnetic field A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
or ''H''-field to the magnetic induction or ''B''-field . Here is a spatial location and is time.


Quantum mechanics

In quantum mechanics and
quantum field theory In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines classical field theory, special relativity, and quantum mechanics. QFT is used in particle physics to construct physical models of subatomic particles and ...
, the vacuum is defined as the state (that is, the solution to the equations of the theory) with the lowest possible energy (the
ground state The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. ...
of the
Hilbert space In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise natural ...
). In quantum electrodynamics this vacuum is referred to as ' QED vacuum' to distinguish it from the vacuum of
quantum chromodynamics In theoretical physics, quantum chromodynamics (QCD) is the theory of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a type ...
, denoted as QCD vacuum. QED vacuum is a state with no matter particles (hence the name), and no photons. As described above, this state is impossible to achieve experimentally. (Even if every matter particle could somehow be removed from a volume, it would be impossible to eliminate all the blackbody photons.) Nonetheless, it provides a good model for realizable vacuum, and agrees with a number of experimental observations as described next. QED vacuum has interesting and complex properties. In QED vacuum, the electric and magnetic fields have zero average values, but their variances are not zero.For example, see As a result, QED vacuum contains vacuum fluctuations ( virtual particles that hop into and out of existence), and a finite energy called vacuum energy. Vacuum fluctuations are an essential and ubiquitous part of quantum field theory. Some experimentally verified effects of vacuum fluctuations include
spontaneous emission Spontaneous emission is the process in which a quantum mechanical system (such as a molecule, an atom or a subatomic particle) transits from an excited energy state to a lower energy state (e.g., its ground state) and emits a quantized amount of ...
and the Lamb shift. Coulomb's law and the electric potential in vacuum near an electric charge are modified.In effect, the dielectric permittivity of the vacuum of classical electromagnetism is changed. For example, see Theoretically, in QCD multiple vacuum states can coexist. The starting and ending of cosmological inflation is thought to have arisen from transitions between different vacuum states. For theories obtained by quantization of a classical theory, each stationary point of the energy in the configuration space gives rise to a single vacuum.
String theory In physics, string theory is a theoretical framework in which the point-like particles of particle physics are replaced by one-dimensional objects called strings. String theory describes how these strings propagate through space and interac ...
is believed to have a huge number of vacua – the so-called string theory landscape.


Outer space

Outer space has very low density and pressure, and is the closest physical approximation of a perfect vacuum. But no vacuum is truly perfect, not even in interstellar space, where there are still a few hydrogen atoms per cubic meter. Stars, planets, and moons keep their
atmosphere An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A s ...
s by gravitational attraction, and as such, atmospheres have no clearly delineated boundary: the density of atmospheric gas simply decreases with distance from the object. The Earth's atmospheric pressure drops to about at of altitude, the
Kármán line The Kármán line (or von Kármán line ) is an attempt to define a boundary between Earth's atmosphere and outer space, and offers a specific definition set by the Fédération aéronautique internationale (FAI), an international record-keeping ...
, which is a common definition of the boundary with outer space. Beyond this line, isotropic gas pressure rapidly becomes insignificant when compared to radiation pressure from the Sun and the dynamic pressure of the solar winds, so the definition of pressure becomes difficult to interpret. The thermosphere in this range has large gradients of pressure, temperature and composition, and varies greatly due to space weather. Astrophysicists prefer to use
number density The number density (symbol: ''n'' or ''ρ''N) is an intensive quantity used to describe the degree of concentration of countable objects (particles, molecules, phonons, cells, galaxies, etc.) in physical space: three-dimensional volumetric number ...
to describe these environments, in units of particles per cubic centimetre. But although it meets the definition of outer space, the atmospheric density within the first few hundred kilometers above the Kármán line is still sufficient to produce significant
drag Drag or The Drag may refer to: Places * Drag, Norway, a village in Tysfjord municipality, Nordland, Norway * ''Drág'', the Hungarian name for Dragu Commune in Sălaj County, Romania * Drag (Austin, Texas), the portion of Guadalupe Street adj ...
on satellites. Most artificial satellites operate in this region called low Earth orbit and must fire their engines every couple of weeks or a few times a year (depending on solar activity). The drag here is low enough that it could theoretically be overcome by radiation pressure on
solar sail Solar sails (also known as light sails and photon sails) are a method of spacecraft propulsion using radiation pressure exerted by sunlight on large mirrors. A number of spaceflight missions to test solar propulsion and navigation have been p ...
s, a proposed propulsion system for interplanetary travel. Planets are too massive for their trajectories to be significantly affected by these forces, although their atmospheres are eroded by the solar winds. All of the observable universe is filled with large numbers of photons, the so-called cosmic background radiation, and quite likely a correspondingly large number of neutrinos. The current temperature of this radiation is about .


Measurement

The quality of a vacuum is indicated by the amount of matter remaining in the system, so that a high quality vacuum is one with very little matter left in it. Vacuum is primarily measured by its absolute pressure, but a complete characterization requires further parameters, such as temperature and chemical composition. One of the most important parameters is the mean free path (MFP) of residual gases, which indicates the average distance that molecules will travel between collisions with each other. As the gas density decreases, the MFP increases, and when the MFP is longer than the chamber, pump, spacecraft, or other objects present, the continuum assumptions of fluid mechanics do not apply. This vacuum state is called ''high vacuum'', and the study of fluid flows in this regime is called particle gas dynamics. The MFP of air at atmospheric pressure is very short, 70  nm, but at 100  mPa (≈) the MFP of room temperature air is roughly 100 mm, which is on the order of everyday objects such as vacuum tubes. The Crookes radiometer turns when the MFP is larger than the size of the vanes. Vacuum quality is subdivided into ranges according to the technology required to achieve it or measure it. These ranges were defined in ISO 3529-1:2019 as shown in the following table (100 Pa corresponds to 0.75 Torr; Torr is a non-SI unit): * Atmospheric pressure is variable but standardized at 101.325 kPa (760 Torr). * Deep space is generally much more empty than any artificial vacuum. It may or may not meet the definition of high vacuum above, depending on what region of space and astronomical bodies are being considered. For example, the MFP of interplanetary space is smaller than the size of the Solar System, but larger than small planets and moons. As a result, solar winds exhibit continuum flow on the scale of the Solar System, but must be considered a bombardment of particles with respect to the Earth and Moon. * Perfect vacuum is an ideal state of no particles at all. It cannot be achieved in a laboratory, although there may be small volumes which, for a brief moment, happen to have no particles of matter in them. Even if all particles of matter were removed, there would still be photons and gravitons, as well as dark energy, virtual particles, and other aspects of the quantum vacuum.


Relative versus absolute measurement

Vacuum is measured in units of pressure, typically as a subtraction relative to ambient atmospheric pressure on Earth. But the amount of relative measurable vacuum varies with local conditions. On the surface of Venus, where ground-level atmospheric pressure is much higher than on Earth, much higher relative vacuum readings would be possible. On the surface of the moon with almost no atmosphere, it would be extremely difficult to create a measurable vacuum relative to the local environment. Similarly, much higher than normal relative vacuum readings are possible deep in the Earth's ocean. A
submarine A submarine (or sub) is a watercraft capable of independent operation underwater. It differs from a submersible, which has more limited underwater capability. The term is also sometimes used historically or colloquially to refer to remotely op ...
maintaining an internal pressure of 1 atmosphere submerged to a depth of 10 atmospheres (98 metres; a 9.8-metre column of seawater has the equivalent weight of 1 atm) is effectively a vacuum chamber keeping out the crushing exterior water pressures, though the 1 atm inside the submarine would not normally be considered a vacuum. Therefore, to properly understand the following discussions of vacuum measurement, it is important that the reader assumes the relative measurements are being done on Earth at sea level, at exactly 1 atmosphere of ambient atmospheric pressure.


Measurements relative to 1 atm

The SI unit of pressure is the
pascal Pascal, Pascal's or PASCAL may refer to: People and fictional characters * Pascal (given name), including a list of people with the name * Pascal (surname), including a list of people and fictional characters with the name ** Blaise Pascal, Fren ...
(symbol Pa), but vacuum is often measured in torrs, named for an Italian physicist Torricelli (1608–1647). A torr is equal to the displacement of a millimeter of mercury (
mmHg A millimetre of mercury is a manometric unit of pressure, formerly defined as the extra pressure generated by a column of mercury one millimetre high, and currently defined as exactly pascals. It is denoted mmHg or mm Hg. Although not an SI ...
) in a manometer with 1 torr equaling 133.3223684 pascals above absolute zero pressure. Vacuum is often also measured on the barometric scale or as a percentage of atmospheric pressure in bars or
atmospheres The standard atmosphere (symbol: atm) is a unit of pressure defined as Pa. It is sometimes used as a ''reference pressure'' or ''standard pressure''. It is approximately equal to Earth's average atmospheric pressure at sea level. History The s ...
. Low vacuum is often measured in millimeters of mercury (mmHg) or pascals (Pa) below standard atmospheric pressure. "Below atmospheric" means that the absolute pressure is equal to the current atmospheric pressure. In other words, most low vacuum gauges that read, for example 50.79 Torr. Many inexpensive low vacuum gauges have a margin of error and may report a vacuum of 0 Torr but in practice this generally requires a two-stage rotary vane or other medium type of vacuum pump to go much beyond (lower than) 1 torr.


Measuring instruments

Many devices are used to measure the pressure in a vacuum, depending on what range of vacuum is needed. Hydrostatic gauges (such as the mercury column manometer) consist of a vertical column of liquid in a tube whose ends are exposed to different pressures. The column will rise or fall until its weight is in equilibrium with the pressure differential between the two ends of the tube. The simplest design is a closed-end U-shaped tube, one side of which is connected to the region of interest. Any fluid can be used, but
mercury Mercury commonly refers to: * Mercury (planet), the nearest planet to the Sun * Mercury (element), a metallic chemical element with the symbol Hg * Mercury (mythology), a Roman god Mercury or The Mercury may also refer to: Companies * Merc ...
is preferred for its high density and low vapour pressure. Simple hydrostatic gauges can measure pressures ranging from 1 torr (100 Pa) to above atmospheric. An important variation is the
McLeod gauge A McLeod gauge is a scientific instrument used to measure very low pressures, down to 10−6 Torr (1.33 m Pa). It was invented in 1874 by Herbert McLeod (1841–1923). McLeod gauges were once commonly found attached to equipment that operates unde ...
which isolates a known volume of vacuum and compresses it to multiply the height variation of the liquid column. The McLeod gauge can measure vacuums as high as 10−6 torr (0.1 mPa), which is the lowest direct measurement of pressure that is possible with current technology. Other vacuum gauges can measure lower pressures, but only indirectly by measurement of other pressure-controlled properties. These indirect measurements must be calibrated via a direct measurement, most commonly a McLeod gauge. The kenotometer is a particular type of hydrostatic gauge, typically used in power plants using steam turbines. The kenotometer measures the vacuum in the steam space of the condenser, that is, the exhaust of the last stage of the turbine. Mechanical or elastic gauges depend on a Bourdon tube, diaphragm, or capsule, usually made of metal, which will change shape in response to the pressure of the region in question. A variation on this idea is the capacitance manometer, in which the diaphragm makes up a part of a capacitor. A change in pressure leads to the flexure of the diaphragm, which results in a change in capacitance. These gauges are effective from 103 torr to 10−4 torr, and beyond. Thermal conductivity gauges rely on the fact that the ability of a gas to conduct heat decreases with pressure. In this type of gauge, a wire filament is heated by running current through it. A thermocouple or Resistance Temperature Detector (RTD) can then be used to measure the temperature of the filament. This temperature is dependent on the rate at which the filament loses heat to the surrounding gas, and therefore on the thermal conductivity. A common variant is the Pirani gauge which uses a single platinum filament as both the heated element and RTD. These gauges are accurate from 10 torr to 10−3 torr, but they are sensitive to the chemical composition of the gases being measured. Ionization gauges are used in ultrahigh vacuum. They come in two types: hot cathode and cold cathode. In the hot cathode version an electrically heated filament produces an electron beam. The electrons travel through the gauge and ionize gas molecules around them. The resulting ions are collected at a negative electrode. The current depends on the number of ions, which depends on the pressure in the gauge. Hot cathode gauges are accurate from 10−3 torr to 10−10 torr. The principle behind cold cathode version is the same, except that electrons are produced in a discharge created by a high voltage electrical discharge. Cold cathode gauges are accurate from 10−2 torr to 10−9 torr. Ionization gauge calibration is very sensitive to construction geometry, chemical composition of gases being measured, corrosion and surface deposits. Their calibration can be invalidated by activation at atmospheric pressure or low vacuum. The composition of gases at high vacuums will usually be unpredictable, so a mass spectrometer must be used in conjunction with the ionization gauge for accurate measurement.


Uses

Vacuum is useful in a variety of processes and devices. Its first widespread use was in the incandescent light bulb to protect the filament from chemical degradation. The chemical inertness produced by a vacuum is also useful for electron beam welding, cold welding, vacuum packing and vacuum frying. Ultra-high vacuum is used in the study of atomically clean substrates, as only a very good vacuum preserves atomic-scale clean surfaces for a reasonably long time (on the order of minutes to days). High to ultra-high vacuum removes the obstruction of air, allowing particle beams to deposit or remove materials without contamination. This is the principle behind
chemical vapor deposition Chemical vapor deposition (CVD) is a vacuum deposition method used to produce high quality, and high-performance, solid materials. The process is often used in the semiconductor industry to produce thin films. In typical CVD, the wafer (substra ...
, physical vapor deposition, and dry etching which are essential to the fabrication of
semiconductors A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glas ...
and
optical coating An optical coating is one or more thin layers of material deposited on an optical component such as a lens, prism or mirror, which alters the way in which the optic reflects and transmits light. These coatings have become a key technology in th ...
s, and to
surface science Surface science is the study of physical and chemical phenomena that occur at the interface of two phases, including solid–liquid interfaces, solid–gas interfaces, solid–vacuum interfaces, and liquid–gas interfaces. It includes the fiel ...
. The reduction of convection provides the thermal insulation of thermos bottles. Deep vacuum lowers the
boiling point The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding envir ...
of liquids and promotes low temperature outgassing which is used in freeze drying,
adhesive Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advant ...
preparation, distillation,
metallurgy Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the sc ...
, and process purging. The electrical properties of vacuum make electron microscopes and vacuum tubes possible, including
cathode ray tube A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms ( oscilloscope), pictu ...
s. Vacuum interrupters are used in electrical switchgear.
Vacuum arc A vacuum arc can arise when the surfaces of metal electrodes in contact with a good vacuum begin to emit electrons either through heating (thermionic emission) or in an electric field that is sufficient to cause field electron emission. Once initia ...
processes are industrially important for production of certain grades of steel or high purity materials. The elimination of air friction is useful for flywheel energy storage and ultracentrifuges.


Vacuum-driven machines

Vacuums are commonly used to produce
suction Suction is the colloquial term to describe the air pressure differential between areas. Removing air from a space results in a pressure differential. Suction pressure is therefore limited by external air pressure. Even a perfect vacuum cannot ...
, which has an even wider variety of applications. The Newcomen steam engine used vacuum instead of pressure to drive a piston. In the 19th century, vacuum was used for traction on Isambard Kingdom Brunel's experimental atmospheric railway. Vacuum brakes were once widely used on trains in the UK but, except on
heritage railway A heritage railway or heritage railroad (US usage) is a railway operated as living history to re-create or preserve railway scenes of the past. Heritage railways are often old railway lines preserved in a state depicting a period (or periods) i ...
s, they have been replaced by air brakes. Manifold vacuum can be used to drive accessories on automobiles. The best known application is the vacuum servo, used to provide power assistance for the
brake A brake is a mechanical device that inhibits motion by absorbing energy from a moving system. It is used for slowing or stopping a moving vehicle, wheel, axle, or to prevent its motion, most often accomplished by means of friction. Background ...
s. Obsolete applications include vacuum-driven
windscreen wipers A windscreen wiper, windshield wiper, wiper blade (American English), or simply wiper, is a device used to remove rain, snow, ice, washer fluid, water, or debris from a vehicle's front window. Almost all motor vehicles, including cars, truck ...
and Autovac fuel pumps. Some aircraft instruments ( Attitude Indicator (AI) and the Heading Indicator (HI)) are typically vacuum-powered, as protection against loss of all (electrically powered) instruments, since early aircraft often did not have electrical systems, and since there are two readily available sources of vacuum on a moving aircraft, the engine and an external venturi. Vacuum induction melting uses electromagnetic induction within a vacuum. Maintaining a vacuum in the condenser is an important aspect of the efficient operation of
steam turbine A steam turbine is a machine that extracts thermal energy from pressurized steam and uses it to do mechanical work on a rotating output shaft. Its modern manifestation was invented by Charles Parsons in 1884. Fabrication of a modern steam turbin ...
s. A steam jet
ejector An injector is a system of ducting and nozzles used to direct the flow of a high-pressure fluid in such a way that a lower pressure fluid is Entrainment (hydrodynamics), entrained in the jet and carried through a duct to a region of higher pre ...
or liquid ring vacuum pump is used for this purpose. The typical vacuum maintained in the condenser steam space at the exhaust of the turbine (also called condenser backpressure) is in the range 5 to 15 kPa (absolute), depending on the type of condenser and the ambient conditions.


Outgassing

Evaporation Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidi ...
and
sublimation Sublimation or sublimate may refer to: * ''Sublimation'' (album), by Canvas Solaris, 2004 * Sublimation (phase transition), directly from the solid to the gas phase * Sublimation (psychology), a mature type of defense mechanism * Sublimate of mer ...
into a vacuum is called outgassing. All materials, solid or liquid, have a small vapour pressure, and their outgassing becomes important when the vacuum pressure falls below this vapour pressure. Outgassing has the same effect as a leak and will limit the achievable vacuum. Outgassing products may condense on nearby colder surfaces, which can be troublesome if they obscure optical instruments or react with other materials. This is of great concern to space missions, where an obscured telescope or solar cell can ruin an expensive mission. The most prevalent outgassing product in vacuum systems is water absorbed by chamber materials. It can be reduced by desiccating or baking the chamber, and removing absorbent materials. Outgassed water can condense in the oil of
rotary vane pump A rotary vane pump is a positive-displacement pump that consists of vanes mounted to a rotor that rotates inside a cavity. In some cases these vanes can have variable length and/or be tensioned to maintain contact with the walls as the pump rotates ...
s and reduce their net speed drastically if gas ballasting is not used. High vacuum systems must be clean and free of organic matter to minimize outgassing. Ultra-high vacuum systems are usually baked, preferably under vacuum, to temporarily raise the vapour pressure of all outgassing materials and boil them off. Once the bulk of the outgassing materials are boiled off and evacuated, the system may be cooled to lower vapour pressures and minimize residual outgassing during actual operation. Some systems are cooled well below room temperature by
liquid nitrogen Liquid nitrogen—LN2—is nitrogen in a liquid state at low temperature. Liquid nitrogen has a boiling point of about . It is produced industrially by fractional distillation of liquid air. It is a colorless, low viscosity liquid that is wide ...
to shut down residual outgassing and simultaneously cryopump the system.


Pumping and ambient air pressure

Fluids cannot generally be pulled, so a vacuum cannot be created by
suction Suction is the colloquial term to describe the air pressure differential between areas. Removing air from a space results in a pressure differential. Suction pressure is therefore limited by external air pressure. Even a perfect vacuum cannot ...
. Suction can spread and dilute a vacuum by letting a higher pressure push fluids into it, but the vacuum has to be created first before suction can occur. The easiest way to create an artificial vacuum is to expand the volume of a container. For example, the diaphragm muscle expands the chest cavity, which causes the volume of the lungs to increase. This expansion reduces the pressure and creates a partial vacuum, which is soon filled by air pushed in by atmospheric pressure. To continue evacuating a chamber indefinitely without requiring infinite growth, a compartment of the vacuum can be repeatedly closed off, exhausted, and expanded again. This is the principle behind positive displacement pumps, like the manual water pump for example. Inside the pump, a mechanism expands a small sealed cavity to create a vacuum. Because of the pressure differential, some fluid from the chamber (or the well, in our example) is pushed into the pump's small cavity. The pump's cavity is then sealed from the chamber, opened to the atmosphere, and squeezed back to a minute size. The above explanation is merely a simple introduction to vacuum pumping, and is not representative of the entire range of pumps in use. Many variations of the positive displacement pump have been developed, and many other pump designs rely on fundamentally different principles. Momentum transfer pumps, which bear some similarities to dynamic pumps used at higher pressures, can achieve much higher quality vacuums than positive displacement pumps. Entrapment pumps can capture gases in a solid or absorbed state, often with no moving parts, no seals and no vibration. None of these pumps are universal; each type has important performance limitations. They all share a difficulty in pumping low molecular weight gases, especially hydrogen, helium, and
neon Neon is a chemical element with the symbol Ne and atomic number 10. It is a noble gas. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with about two-thirds the density of air. It was discovered (along with krypton ...
. The lowest pressure that can be attained in a system is also dependent on many things other than the nature of the pumps. Multiple pumps may be connected in series, called stages, to achieve higher vacuums. The choice of seals, chamber geometry, materials, and pump-down procedures will all have an impact. Collectively, these are called ''vacuum technique''. And sometimes, the final pressure is not the only relevant characteristic. Pumping systems differ in oil contamination, vibration, preferential pumping of certain gases, pump-down speeds, intermittent duty cycle, reliability, or tolerance to high leakage rates. In ultra high vacuum systems, some very "odd" leakage paths and outgassing sources must be considered. The water absorption of aluminium and palladium becomes an unacceptable source of outgassing, and even the adsorptivity of hard metals such as stainless steel or titanium must be considered. Some oils and greases will boil off in extreme vacuums. The permeability of the metallic chamber walls may have to be considered, and the grain direction of the metallic flanges should be parallel to the flange face. The lowest pressures currently achievable in laboratory are about . However, pressures as low as have been indirectly measured in a cryogenic vacuum system. This corresponds to ≈100 particles/cm3.


Effects on humans and animals

Humans and animals exposed to vacuum will lose consciousness after a few seconds and die of
hypoxia Hypoxia means a lower than normal level of oxygen, and may refer to: Reduced or insufficient oxygen * Hypoxia (environmental), abnormally low oxygen content of the specific environment * Hypoxia (medical), abnormally low level of oxygen in the tis ...
within minutes, but the symptoms are not nearly as graphic as commonly depicted in media and popular culture. The reduction in pressure lowers the temperature at which blood and other body fluids boil, but the elastic pressure of blood vessels ensures that this boiling point remains above the internal body temperature of Although the blood will not boil, the formation of gas bubbles in bodily fluids at reduced pressures, known as ebullism, is still a concern. The gas may bloat the body to twice its normal size and slow circulation, but tissues are elastic and porous enough to prevent rupture. Swelling and ebullism can be restrained by containment in a flight suit.
Shuttle The original meaning of the word shuttle is the device used in weaving to carry the weft. By reference to the continual to-and-fro motion associated with that, the term was then applied in transportation and then in other spheres. Thus the word ma ...
astronauts wore a fitted elastic garment called the Crew Altitude Protection Suit (CAPS) which prevents ebullism at pressures as low as 2 kPa (15 Torr). Rapid boiling will cool the skin and create frost, particularly in the mouth, but this is not a significant hazard. Animal experiments show that rapid and complete recovery is normal for exposures shorter than 90 seconds, while longer full-body exposures are fatal and resuscitation has never been successful. A study by NASA on eight chimpanzees found all of them survived two and a half minute exposures to vacuum. There is only a limited amount of data available from human accidents, but it is consistent with animal data. Limbs may be exposed for much longer if breathing is not impaired.. Robert Boyle was the first to show in 1660 that vacuum is lethal to small animals. An experiment indicates that plants are able to survive in a low pressure environment (1.5 kPa) for about 30 minutes. Cold or oxygen-rich atmospheres can sustain life at pressures much lower than atmospheric, as long as the density of oxygen is similar to that of standard sea-level atmosphere. The colder air temperatures found at altitudes of up to 3 km generally compensate for the lower pressures there. Above this altitude, oxygen enrichment is necessary to prevent altitude sickness in humans that did not undergo prior acclimatization, and
spacesuit A space suit or spacesuit is a garment worn to keep a human alive in the harsh environment of outer space, vacuum and temperature extremes. Space suits are often worn inside spacecraft as a safety precaution in case of loss of cabin pressure, ...
s are necessary to prevent ebullism above 19 km. Most spacesuits use only 20 kPa (150 Torr) of pure oxygen. This pressure is high enough to prevent ebullism, but decompression sickness and gas embolisms can still occur if decompression rates are not managed. Rapid decompression can be much more dangerous than vacuum exposure itself. Even if the victim does not hold his or her breath, venting through the windpipe may be too slow to prevent the fatal rupture of the delicate alveoli of the
lung The lungs are the primary organs of the respiratory system in humans and most other animals, including some snails and a small number of fish. In mammals and most other vertebrates, two lungs are located near the backbone on either side of t ...
s.
Eardrum In the anatomy of humans and various other tetrapods, the eardrum, also called the tympanic membrane or myringa, is a thin, cone-shaped membrane that separates the external ear The outer ear, external ear, or auris externa is the extern ...
s and sinuses may be ruptured by rapid decompression, soft tissues may bruise and seep blood, and the stress of shock will accelerate oxygen consumption leading to hypoxia. Injuries caused by rapid decompression are called barotrauma. A pressure drop of 13 kPa (100 Torr), which produces no symptoms if it is gradual, may be fatal if it occurs suddenly. Some extremophile
microorganisms A microorganism, or microbe,, ''mikros'', "small") and ''organism'' from the el, ὀργανισμός, ''organismós'', "organism"). It is usually written as a single word but is sometimes hyphenated (''micro-organism''), especially in olde ...
, such as tardigrades, can survive vacuum conditions for periods of days or weeks.


Examples


See also

* Decay of the vacuum ( Pair production) *
Engine vacuum Manifold vacuum, or engine vacuum in an internal combustion engine is the difference in air pressure between the engine's intake manifold and Earth's atmosphere. Manifold vacuum is an effect of a piston's movement on the induction stroke and the c ...
* False vacuum * Helium mass spectrometer – technical instrumentation to detect a vacuum leak * Joining materials * Pneumatic tube – transport system using vacuum or pressure to move containers in tubes *
Rarefaction Rarefaction is the reduction of an item's density, the opposite of compression. Like compression, which can travel in waves (sound waves, for instance), rarefaction waves also exist in nature. A common rarefaction wave is the area of low relativ ...
– reduction of a medium's density *
Suction Suction is the colloquial term to describe the air pressure differential between areas. Removing air from a space results in a pressure differential. Suction pressure is therefore limited by external air pressure. Even a perfect vacuum cannot ...
– creation of a partial vacuum * Theta vacuum – vacuum state of semi-classical pure-Yang Mills theories *
Vacuum cementing Vacuum cementing or vacuum welding is the natural process of solidifying small objects in a hard vacuum. The most notable example is dust on the surface of the Moon. This effect was reported to be a problem with the first American and Soviet sa ...
– natural process of solidifying homogeneous "dust" in vacuum * Vacuum column – controlling loose magnetic tape in early computer data recording tape drives *
Vacuum deposition Vacuum deposition is a group of processes used to deposit layers of material atom-by-atom or molecule-by-molecule on a solid surface. These processes operate at pressures well below atmospheric pressure (i.e., vacuum). The deposited layers can ...
– process of depositing atoms and molecules in a sub-atmospheric pressure environment * Vacuum engineering * Vacuum flange – joining of vacuum systems


References

* *


External links


Leybold – Fundamentals of Vacuum Technology (PDF)

VIDEO on the nature of vacuum
by Canadian astrophysicist Doctor P


American Vacuum Society

Journal of Vacuum Science and Technology A

Journal of Vacuum Science and Technology B




*
Vacuum, Production of Space

"Much Ado About Nothing" by Professor John D. Barrow, Gresham College
* Free pdf copy o
The Structured Vacuum – thinking about nothing
by Johann Rafelski and Berndt Muller (1985) . {{Authority control Physical phenomena Industrial processes Gases Articles containing video clips Latin words and phrases