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In the field of
optics
Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultrav ...
, transparency (also called pellucidity or diaphaneity) is the
physical property of allowing
light
Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 te ...
to pass through the material without appreciable
scattering of light. On a
macroscopic scale
The macroscopic scale is the length scale on which objects or phenomena are large enough to be visible with the naked eye, without magnifying optical instruments. It is the opposite of microscopic.
Overview
When applied to physical phenomena a ...
(one in which the dimensions are much larger than the wavelengths of the
photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they a ...
s in question), the photons can be said to follow
Snell's law. Translucency (also called translucence or translucidity) allows light to pass through, but does not necessarily (again, on the macroscopic scale) follow Snell's law; the photons can be scattered at either of the two interfaces, or internally, where there is a change in index of
refraction
In physics, refraction is the redirection of a wave as it passes from one medium to another. The redirection can be caused by the wave's change in speed or by a change in the medium. Refraction of light is the most commonly observed phenome ...
. In other words, a translucent material is made up of components with different indices of refraction. A transparent material is made up of components with a uniform index of refraction. Transparent materials appear clear, with the overall appearance of one color, or any combination leading up to a brilliant
spectrum
A spectrum (plural ''spectra'' or ''spectrums'') is a condition that is not limited to a specific set of values but can vary, without gaps, across a continuum. The word was first used scientifically in optics to describe the rainbow of colors ...
of every color. The opposite property of translucency is
opacity.
When light encounters a material, it can interact with it in several different ways. These interactions depend on the
wavelength
In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats.
It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, t ...
of the light and the nature of the material. Photons interact with an object by some combination of reflection, absorption and transmission.
Some materials, such as
plate glass
Plate glass, flat glass or sheet glass is a type of glass, initially produced in plane form, commonly used for windows, glass doors, transparent walls, and windscreens. For modern architectural and automotive applications, the flat glass is ...
and clean
water
Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
, transmit much of the light that falls on them and reflect little of it; such materials are called optically transparent. Many liquids and aqueous solutions are highly transparent. Absence of structural defects (voids, cracks, etc.) and molecular structure of most liquids are mostly responsible for excellent optical transmission.
Materials which do not
transmit light are called
opaque
Opacity or opaque may refer to:
* Impediments to (especially, visible) light:
** Opacities, absorption coefficients
** Opacity (optics), property or degree of blocking the transmission of light
* Metaphors derived from literal optics:
** In lingu ...
. Many such substances have a
chemical composition which includes what are referred to as
absorption centers. Many substances are selective in their absorption of
white light frequencies. They absorb certain portions of the
visible spectrum
The visible spectrum is the portion of the electromagnetic spectrum that is visible to the human eye. Electromagnetic radiation in this range of wavelengths is called ''visible light'' or simply light. A typical human eye will respond to wa ...
while reflecting others. The frequencies of the spectrum which are not absorbed are either reflected or transmitted for our physical observation. This is what gives rise to
color
Color (American English) or colour (British English) is the visual perceptual property deriving from the spectrum of light interacting with the photoreceptor cells of the eyes. Color categories and physical specifications of color are assoc ...
. The attenuation of light of all frequencies and wavelengths is due to the combined mechanisms of absorption and
scattering.
Transparency can provide almost perfect
camouflage
Camouflage is the use of any combination of materials, coloration, or illumination for concealment, either by making animals or objects hard to see, or by disguising them as something else. Examples include the leopard's spotted coat, the b ...
for animals able to achieve it. This is easier in dimly-lit or turbid
sea
The sea, connected as the world ocean or simply the ocean, is the body of salty water that covers approximately 71% of the Earth's surface. The word sea is also used to denote second-order sections of the sea, such as the Mediterranean Sea, ...
water than in good illumination. Many
marine animals
Marine life, sea life, or ocean life is the plants, animals and other organisms that live in the salt water of seas or oceans, or the brackish water of coastal estuaries. At a fundamental level, marine life affects the nature of the planet. M ...
such as
jellyfish
Jellyfish and sea jellies are the informal common names given to the medusa-phase of certain gelatinous members of the subphylum Medusozoa, a major part of the phylum Cnidaria. Jellyfish are mainly free-swimming marine animals with umbrell ...
are highly transparent.
Etymology
*late Middle English: from Old French, from medieval Latin transparent- ‘shining through’, from Latin transparere, from trans- ‘through’ + parere ‘be visible’.
*late 16th century (in the Latin sense): from Latin translucent- ‘shining through’, from the verb translucere, from trans- ‘through’ + lucere ‘to shine’.
*late Middle English opake, from Latin opacus ‘darkened’. The current spelling (rare before the 19th century) has been influenced by the French form.
Introduction
With regard to the absorption of light, primary material considerations include:
*At the electronic level, absorption in the
ultraviolet
Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30 PHz) to 400 nm (750 THz), shorter than that of visible light, but longer than X-rays. UV radiation ...
and visible (UV-Vis) portions of the spectrum depends on whether the
electron orbitals An electron orbital may refer to:
* An atomic orbital, describing the behaviour of an electron in an atom
* A molecular orbital, describing the behaviour of an electron in a molecule
See also
* Electron configuration, the arrangement of electro ...
are spaced (or "quantized") such that they can absorb a
quantum of light (or
photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they a ...
) of a specific
frequency
Frequency is the number of occurrences of a repeating event per unit of time. It is also occasionally referred to as ''temporal frequency'' for clarity, and is distinct from ''angular frequency''. Frequency is measured in hertz (Hz) which is eq ...
, and does not violate
selection rules
In physics and chemistry, a selection rule, or transition rule, formally constrains the possible transitions of a system from one quantum state to another. Selection rules have been derived for electromagnetic transitions in molecules, in atoms, i ...
. For example, in most glasses, electrons have no available energy levels above them in range of that associated with visible light, or if they do, they violate selection rules, meaning there is no appreciable absorption in pure (undoped) glasses, making them ideal transparent materials for windows in buildings.
*At the atomic or molecular level, physical absorption in the infrared portion of the spectrum depends on the
frequencies of atomic or
molecular vibrations
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 1013 Hz to approximately 1014 ...
or
chemical bonds
A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules and crystals. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of ...
, and on
selection rule
In physics and chemistry, a selection rule, or transition rule, formally constrains the possible transitions of a system from one quantum state to another. Selection rules have been derived for electromagnetic transitions in molecules, in atoms, in ...
s. Nitrogen and oxygen are not greenhouse gases because there is no
molecular dipole moment
In physics, a dipole () is an electromagnetic phenomenon which occurs in two ways:
*An electric dipole deals with the separation of the positive and negative electric charges found in any electromagnetic system. A simple example of this system i ...
.
With regard to the
scattering of light, the most critical factor is the length scale of any or all of these structural features relative to the wavelength of the light being scattered. Primary material considerations include:
*Crystalline structure: whether the atoms or molecules exhibit the 'long-range order' evidenced in crystalline solids.
*Glassy structure: scattering centers include fluctuations in density or composition.
*
Microstructure
Microstructure is the very small scale structure of a material, defined as the structure of a prepared surface of material as revealed by an optical microscope above 25× magnification. The microstructure of a material (such as metals, polymers ...
: scattering centers include internal surfaces such as grain boundaries,
crystallographic defect
A crystallographic defect is an interruption of the regular patterns of arrangement of atoms or molecules in crystalline solids. The positions and orientations of particles, which are repeating at fixed distances determined by the unit cell para ...
s and microscopic pores.
*Organic materials: scattering centers include fiber and cell structures and boundaries.
Diffuse reflection
Diffuse reflection is the reflection of light or other waves or particles from a surface such that a ray incident on the surface is scattered at many angles rather than at just one angle as in the case of specular reflection. An ''ideal'' di ...
- Generally, when light strikes the surface of a (non-metallic and non-glassy) solid material, it bounces off in all directions due to multiple reflections by the microscopic irregularities ''inside'' the material (e.g., the
grain boundaries
In materials science, a grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are two-dimensional defects in the crystal structure, and tend to decrease the electrical and thermal ...
of a
polycrystalline
A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains.
Bacillite is a type of crystallite. It is rodlike with parallel longulites.
Stru ...
material, or the
cell
Cell most often refers to:
* Cell (biology), the functional basic unit of life
Cell may also refer to:
Locations
* Monastic cell, a small room, hut, or cave in which a religious recluse lives, alternatively the small precursor of a monastery ...
or
fiber
Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorpora ...
boundaries of an organic material), and by its surface, if it is rough. Diffuse reflection is typically characterized by omni-directional reflection angles. Most of the objects visible to the naked eye are identified via diffuse reflection. Another term commonly used for this type of reflection is "light scattering". Light scattering from the surfaces of objects is our primary mechanism of physical observation.
Light scattering in liquids and solids depends on the wavelength of the light being scattered. Limits to spatial scales of visibility (using white light) therefore arise, depending on the frequency of the light wave and the physical
dimension
In physics and mathematics, the dimension of a mathematical space (or object) is informally defined as the minimum number of coordinates needed to specify any point within it. Thus, a line has a dimension of one (1D) because only one coor ...
(or spatial scale) of the scattering center. Visible light has a wavelength scale on the order of a half a
micrometer Micrometer can mean:
* Micrometer (device), used for accurate measurements by means of a calibrated screw
* American spelling of micrometre
The micrometre ( international spelling as used by the International Bureau of Weights and Measures; ...
. Scattering centers (or particles) as small as one micrometer have been observed directly in the light
microscope
A microscope () is a laboratory instrument used to examine objects that are too small to be seen by the naked eye. Microscopy is the science of investigating small objects and structures using a microscope. Microscopic means being invisi ...
(e.g.,
Brownian motion
Brownian motion, or pedesis (from grc, πήδησις "leaping"), is the random motion of particles suspended in a medium (a liquid or a gas).
This pattern of motion typically consists of random fluctuations in a particle's position insi ...
).
Transparent ceramics
Optical transparency in polycrystalline materials is limited by the amount of light which is scattered by their microstructural features. Light scattering depends on the wavelength of the light. Limits to spatial scales of visibility (using white light) therefore arise, depending on the frequency of the light wave and the physical dimension of the scattering center. For example, since visible light has a wavelength scale on the order of a micrometer, scattering centers will have dimensions on a similar spatial scale. Primary scattering centers in polycrystalline materials include microstructural defects such as pores and grain boundaries. In addition to pores, most of the interfaces in a typical metal or ceramic object are in the form of
grain boundaries
In materials science, a grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are two-dimensional defects in the crystal structure, and tend to decrease the electrical and thermal ...
which separate tiny regions of crystalline order. When the size of the scattering center (or grain boundary) is reduced below the size of the wavelength of the light being scattered, the scattering no longer occurs to any significant extent.
In the formation of polycrystalline materials (metals and ceramics) the size of the crystalline grains is determined largely by the size of the crystalline particles present in the raw material during formation (or pressing) of the object. Moreover, the size of the grain boundaries scales directly with particle size. Thus a reduction of the original particle size well below the wavelength of visible light (about 1/15 of the light wavelength or roughly 600/15 = 40
nanometers) eliminates much of light scattering, resulting in a translucent or even transparent material.
Computer modeling of light transmission through translucent ceramic alumina has shown that microscopic pores trapped near grain boundaries act as primary scattering centers. The volume fraction of porosity had to be reduced below 1% for high-quality optical transmission (99.99 percent of theoretical density). This goal has been readily accomplished and amply demonstrated in laboratories and research facilities worldwide using the emerging chemical processing methods encompassed by the methods of
sol-gel chemistry and
nanotechnology.
Transparent ceramics have created interest in their applications for high energy lasers, transparent armor windows, nose cones for heat seeking missiles, radiation detectors for non-destructive testing, high energy physics, space exploration, security and medical imaging applications. Large
laser
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The fi ...
elements made from transparent ceramics can be produced at a relatively low cost. These components are free of internal
stress
Stress may refer to:
Science and medicine
* Stress (biology), an organism's response to a stressor such as an environmental condition
* Stress (linguistics), relative emphasis or prominence given to a syllable in a word, or to a word in a phrase ...
or intrinsic
birefringence, and allow relatively large doping levels or optimized custom-designed doping profiles. This makes ceramic laser elements particularly important for high-energy lasers.
The development of transparent panel products will have other potential advanced applications including high strength, impact-resistant materials that can be used for domestic windows and skylights. Perhaps more important is that walls and other applications will have improved overall strength, especially for high-shear conditions found in high seismic and wind exposures. If the expected improvements in mechanical properties bear out, the traditional limits seen on glazing areas in today's building codes could quickly become outdated if the window area actually contributes to the shear resistance of the wall.
Currently available infrared transparent materials typically exhibit a trade-off between optical performance, mechanical strength and price. For example,
sapphire
Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sa ...
(crystalline
alumina) is very strong, but it is expensive and lacks full transparency throughout the 3–5 micrometer mid-infrared range.
Yttria
Yttrium oxide, also known as yttria, is Y2 O3. It is an air-stable, white solid substance.
The thermal conductivity of yttrium oxide is 27 W/(m·K).
Uses Phosphors
Yttria is widely used to make Eu:YVO4 and Eu:Y2O3 phosphors that give the red ...
is fully transparent from 3–5 micrometers, but lacks sufficient strength, hardness, and thermal shock resistance for high-performance aerospace applications. Not surprisingly, a combination of these two materials in the form of the
yttrium aluminium garnet
Yttrium aluminium garnet (YAG, Y3 Al5 O12) is a synthetic crystalline material of the garnet group. It is a cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP) in a hexagonal or an orthorhombic, perovskite-like form, and ...
(YAG) is one of the top performers in the field.
Absorption of light in solids
When light strikes an object, it usually has not just a single frequency (or wavelength) but many. Objects have a tendency to selectively absorb, reflect or transmit light of certain frequencies. That is, one object might reflect green light while absorbing all other frequencies of visible light. Another object might selectively transmit blue light while absorbing all other frequencies of visible light. The manner in which visible light interacts with an object is dependent upon the frequency of the light, the nature of the atoms in the object, and often the nature of the
electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary particles because they have no ...
s in the
atom
Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons.
Every solid, liquid, gas, ...
s of the object.
Some materials allow much of the light that falls on them to be transmitted through the material without being reflected. Materials that allow the transmission of light waves through them are called optically transparent. Chemically pure (undoped) window glass and clean river or spring water are prime examples of this.
Materials which do not allow the transmission of any light wave frequencies are called
opaque
Opacity or opaque may refer to:
* Impediments to (especially, visible) light:
** Opacities, absorption coefficients
** Opacity (optics), property or degree of blocking the transmission of light
* Metaphors derived from literal optics:
** In lingu ...
. Such substances may have a chemical composition which includes what are referred to as absorption centers. Most materials are composed of materials which are selective in their absorption of light frequencies. Thus they absorb only certain portions of the visible spectrum. The frequencies of the spectrum which are not absorbed are either reflected back or transmitted for our physical observation. In the visible portion of the spectrum, this is what gives rise to color.
Absorption centers are largely responsible for the appearance of specific wavelengths of visible light all around us. Moving from longer (0.7 micrometer) to shorter (0.4 micrometer) wavelengths: red, orange, yellow, green and blue (ROYGB) can all be identified by our senses in the appearance of color by the selective absorption of specific light wave frequencies (or wavelengths). Mechanisms of selective light wave absorption include:
*Electronic: Transitions in electron
energy levels
A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The t ...
within the atom (e.g.,
pigments
A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compoun ...
). These transitions are typically in the ultraviolet (UV) and/or visible portions of the spectrum.
*Vibrational:
Resonance
Resonance describes the phenomenon of increased amplitude that occurs when the frequency of an applied Periodic function, periodic force (or a Fourier analysis, Fourier component of it) is equal or close to a natural frequency of the system ...
in atomic/molecular
vibrational modes
A normal mode of a dynamical system is a pattern of motion in which all parts of the system move sinusoidally with the same frequency and with a fixed phase relation. The free motion described by the normal modes takes place at fixed frequencies. ...
. These transitions are typically in the infrared portion of the spectrum.
UV-Vis: Electronic transitions
In electronic absorption, the frequency of the incoming light wave is at or near the energy levels of the electrons within the atoms which compose the substance. In this case, the electrons will absorb the energy of the light wave and increase their energy state, often moving outward from the
nucleus
Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to:
*Atomic nucleus, the very dense central region of an atom
* Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA
Nucl ...
of the atom into an outer shell or
orbital.
The atoms that bind together to make the molecules of any particular substance contain a number of electrons (given by the
atomic number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every ...
Z in the
periodic chart). Recall that all light waves are electromagnetic in origin. Thus they are affected strongly when coming into contact with
negatively charged electrons in matter. When
photons (individual packets of light energy) come in contact with the
valence electrons
In chemistry and physics, a valence electron is an electron in the outer shell associated with an atom, and that can participate in the formation of a chemical bond if the outer shell is not closed. In a single covalent bond, a shared pair forms ...
of atom, one of several things can and will occur:
*A molecule absorbs the photon, some of the energy may be lost via
luminescence
Luminescence is spontaneous emission of light by a substance not resulting from heat; or "cold light".
It is thus a form of cold-body radiation. It can be caused by chemical reactions, electrical energy, subatomic motions or stress on a crys ...
,
fluorescence
Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...
and
phosphorescence
Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluo ...
.
*A molecule absorbs the photon which results in reflection or scattering.
*A molecule cannot absorb the energy of the photon and the photon continues on its path. This results in transmission (provided no other absorption mechanisms are active).
Most of the time, it is a combination of the above that happens to the light that hits an object. The states in different materials vary in the range of energy that they can absorb. Most glasses, for example, block ultraviolet (UV) light. What happens is the electrons in the glass absorb the energy of the photons in the UV range while ignoring the weaker energy of photons in the visible light spectrum. But there are also existing special
glass
Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling ( quenching ...
types, like special types of
borosilicate glass
Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion (≈3 × 10−6 K−1 at 20 °C), m ...
or quartz that are UV-permeable and thus allow a high transmission of ultra violet light.
Thus, when a material is illuminated, individual photons of light can make the
valence electrons
In chemistry and physics, a valence electron is an electron in the outer shell associated with an atom, and that can participate in the formation of a chemical bond if the outer shell is not closed. In a single covalent bond, a shared pair forms ...
of an atom transition to a higher electronic
energy level
A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The t ...
. The photon is destroyed in the process and the absorbed radiant energy is transformed to electric potential energy. Several things can happen then to the absorbed energy: it may be re-emitted by the electron as
radiant energy
Radiant may refer to:
Computers, software, and video games
* Radiant (software), a content management system
* GtkRadiant, a level editor created by id Software for their games
* Radiant AI, a technology developed by Bethesda Softworks for '' ...
(in this case the overall effect is in fact a scattering of light), dissipated to the rest of the material (i.e. transformed into
heat
In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
), or the electron can be freed from the atom (as in the
photoelectric
The photoelectric effect is the emission of electrons when electromagnetic radiation, such as light, hits a material. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physics, and solid sta ...
and
Compton effects).
Infrared: Bond stretching
The primary physical mechanism for storing mechanical energy of motion in condensed matter is through
heat
In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
, or
thermal energy
The term "thermal energy" is used loosely in various contexts in physics and engineering. It can refer to several different well-defined physical concepts. These include the internal energy or enthalpy of a body of matter and radiation; heat, de ...
. Thermal energy manifests itself as energy of motion. Thus, heat is motion at the atomic and molecular levels. The primary mode of motion in
crystalline
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
substances is
vibration
Vibration is a mechanical phenomenon whereby oscillations occur about an equilibrium point. The word comes from Latin ''vibrationem'' ("shaking, brandishing"). The oscillations may be periodic, such as the motion of a pendulum—or random, su ...
. Any given atom will vibrate around some
mean
There are several kinds of mean in mathematics, especially in statistics. Each mean serves to summarize a given group of data, often to better understand the overall value (magnitude and sign) of a given data set.
For a data set, the '' ari ...
or average
position
Position often refers to:
* Position (geometry), the spatial location (rather than orientation) of an entity
* Position, a job or occupation
Position may also refer to:
Games and recreation
* Position (poker), location relative to the dealer
* ...
within a crystalline structure, surrounded by its nearest neighbors. This vibration in two dimensions is equivalent to the
oscillation
Oscillation is the repetitive or periodic variation, typically in time, of some measure about a central value (often a point of equilibrium) or between two or more different states. Familiar examples of oscillation include a swinging pendulum ...
of a clock's pendulum. It swings back and forth
symmetrical
Symmetry (from grc, συμμετρία "agreement in dimensions, due proportion, arrangement") in everyday language refers to a sense of harmonious and beautiful proportion and balance. In mathematics, "symmetry" has a more precise definiti ...
ly about some mean or average (vertical) position. Atomic and molecular vibrational frequencies may average on the order of 10
12 cycles per second
The cycle per second is a once-common English name for the unit of frequency now known as the hertz (Hz). The plural form was typically used, often written cycles per second, cycles/second, c.p.s., c/s, or, ambiguously, just cycles (Cy./Cyc.). T ...
(
Terahertz radiation
Terahertz radiation – also known as submillimeter radiation, terahertz waves, tremendously high frequency
(THF), T-rays, T-waves, T-light, T-lux or THz – consists of electromagnetic waves within the ITU-designated band of fre ...
).
When a light wave of a given frequency strikes a material with particles having the same or (resonant) vibrational frequencies, then those particles will absorb the energy of the light wave and transform it into thermal energy of vibrational motion. Since different atoms and molecules have different natural frequencies of vibration, they will selectively absorb different frequencies (or portions of the spectrum) of infrared light. Reflection and transmission of light waves occur because the frequencies of the light waves do not match the natural resonant frequencies of vibration of the objects. When infrared light of these frequencies strikes an object, the energy is reflected or transmitted.
If the object is transparent, then the light waves are passed on to neighboring atoms through the bulk of the material and re-emitted on the opposite side of the object. Such frequencies of light waves are said to be
transmitted.
Transparency in insulators
An object may be not transparent either because it reflects the incoming light or because it absorbs the incoming light. Almost all solids reflect a part and absorb a part of the incoming light.
When light falls onto a block of
metal
A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
, it encounters atoms that are tightly packed in a regular
lattice
Lattice may refer to:
Arts and design
* Latticework, an ornamental criss-crossed framework, an arrangement of crossing laths or other thin strips of material
* Lattice (music), an organized grid model of pitch ratios
* Lattice (pastry), an orna ...
and a "
sea of electrons
Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be descr ...
" moving randomly between the atoms.
In metals, most of these are non-bonding electrons (or free electrons) as opposed to the bonding electrons typically found in covalently bonded or ionically bonded non-metallic (insulating) solids. In a metallic bond, any potential bonding electrons can easily be lost by the atoms in a crystalline structure. The effect of this delocalization is simply to exaggerate the effect of the "sea of electrons". As a result of these electrons, most of the incoming light in metals is reflected back, which is why we see a
shiny metal surface.
Most
insulators
Insulator may refer to:
* Insulator (electricity), a substance that resists electricity
** Pin insulator, a device that isolates a wire from a physical support such as a pin on a utility pole
** Strain insulator, a device that is designed to work ...
(or
dielectric
In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the mate ...
materials) are held together by
ionic bond
Ionic bonding is a type of chemical bonding that involves the electrostatic attraction between oppositely charged ions, or between two atoms with sharply different electronegativities, and is the primary interaction occurring in ionic compounds ...
s. Thus, these materials do not have free
conduction electrons, and the bonding electrons reflect only a small fraction of the incident wave. The remaining frequencies (or wavelengths) are free to propagate (or be transmitted). This class of materials includes all
ceramics
A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain ...
and
glass
Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling ( quenching ...
es.
If a dielectric material does not include light-absorbent additive molecules (pigments, dyes, colorants), it is usually transparent to the spectrum of visible light.
Color centers (or dye molecules, or "dopants") in a dielectric absorb a portion of the incoming light. The remaining frequencies (or wavelengths) are free to be reflected or transmitted. This is how colored glass is produced.
Most liquids and aqueous solutions are highly transparent. For example, water, cooking oil, rubbing alcohol, air, and natural gas are all clear. Absence of structural defects (voids, cracks, etc.) and molecular structure of most liquids are chiefly responsible for their excellent optical transmission. The ability of liquids to "heal" internal defects via viscous flow is one of the reasons why some fibrous materials (e.g., paper or fabric) increase their apparent transparency when wetted. The liquid fills up numerous voids making the material more structurally homogeneous.
Light scattering in an ideal defect-free
crystalline
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
(non-metallic) solid which provides ''no scattering centers'' for incoming light will be due primarily to any effects of anharmonicity within the ordered lattice. Light
transmission will be highly
directional due to the typical
anisotropy
Anisotropy () is the property of a material which allows it to change or assume different properties in different directions, as opposed to isotropy. It can be defined as a difference, when measured along different axes, in a material's physic ...
of crystalline substances, which includes their
symmetry group and
Bravais lattice
In geometry and crystallography, a Bravais lattice, named after , is an infinite array of discrete points generated by a set of discrete translation operations described in three dimensional space by
: \mathbf = n_1 \mathbf_1 + n_2 \mathbf_2 + n ...
. For example, the seven different
crystalline
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
forms of
quartz
Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
silica (
silicon dioxide
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
, SiO
2) are all clear,
transparent materials
In the field of optics, transparency (also called pellucidity or diaphaneity) is the physical property of allowing light to pass through the material without appreciable scattering of light. On a macroscopic scale (one in which the dimensions ...
.
Optical waveguides
Optically transparent materials focus on the response of a material to incoming light waves of a range of wavelengths. Guided light wave transmission via frequency selective waveguides involves the emerging field of
fiber optics and the ability of certain glassy compositions to act as a
transmission medium
A transmission medium is a system or substance that can mediate the propagation of signals for the purposes of telecommunication. Signals are typically imposed on a wave of some kind suitable for the chosen medium. For example, data can modulat ...
for a range of frequencies simultaneously (
multi-mode optical fiber
Multi-mode optical fiber is a type of optical fiber mostly used for communication over short distances, such as within a building or on a campus. Multi-mode links can be used for data rates up to 100 Gbit/s. Multi-mode fiber has a fairly large ...
) with little or no
interference
Interference is the act of interfering, invading, or poaching. Interference may also refer to:
Communications
* Interference (communication), anything which alters, modifies, or disrupts a message
* Adjacent-channel interference, caused by extr ...
between competing wavelengths or frequencies. This resonant mode of energy and data transmission via electromagnetic (light) wave propagation is relatively lossless.
An optical fiber is a
cylindrical dielectric waveguide that transmits light along its axis by the process of
total internal reflection
Total internal reflection (TIR) is the optical phenomenon in which waves arriving at the interface (boundary) from one medium to another (e.g., from water to air) are not refracted into the second ("external") medium, but completely reflect ...
. The fiber consists of a
core
Core or cores may refer to:
Science and technology
* Core (anatomy), everything except the appendages
* Core (manufacturing), used in casting and molding
* Core (optical fiber), the signal-carrying portion of an optical fiber
* Core, the centra ...
surrounded by a
cladding
Cladding is an outer layer of material covering another. It may refer to the following:
*Cladding (boiler), the layer of insulation and outer wrapping around a boiler shell
*Cladding (construction), materials applied to the exterior of buildings
...
layer. To confine the optical signal in the core, the
refractive index
In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium.
The refractive index determines how much the path of light is bent, or ...
of the core must be greater than that of the cladding. The refractive index is the parameter reflecting the
speed of light
The speed of light in vacuum, commonly denoted , is a universal physical constant that is important in many areas of physics. The speed of light is exactly equal to ). According to the special theory of relativity, is the upper limit ...
in a material. (Refractive index is the ratio of the speed of light in vacuum to the speed of light in a given medium. The refractive index of vacuum is therefore 1.) The larger the refractive index, the more slowly light travels in that medium. Typical values for core and cladding of an optical fiber are 1.48 and 1.46, respectively.
When light traveling in a dense medium hits a boundary at a steep angle, the light will be completely reflected. This effect, called
total internal reflection
Total internal reflection (TIR) is the optical phenomenon in which waves arriving at the interface (boundary) from one medium to another (e.g., from water to air) are not refracted into the second ("external") medium, but completely reflect ...
, is used in optical fibers to confine light in the core. Light travels along the fiber bouncing back and forth off of the boundary. Because the light must strike the boundary with an angle greater than the
critical angle
Critical angle may refer to:
*Critical angle (optics), the angle of incidence above which total internal reflection occurs
*Critical angle of attack
In fluid dynamics, angle of attack (AOA, α, or \alpha) is the angle between a reference lin ...
, only light that enters the fiber within a certain range of angles will be propagated. This range of angles is called the
acceptance cone A guided ray (also bound ray or trapped ray) is a ray of light in a multi-mode optical fiber, which is confined by the core.
For step index fiber, light entering the fiber will be guided if it falls within the acceptance cone of the fiber, that i ...
of the fiber. The size of this acceptance cone is a function of the refractive index difference between the fiber's core and cladding.
Optical
Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultravio ...
waveguides
A waveguide is a structure that guides waves, such as electromagnetic waves or sound, with minimal loss of energy by restricting the transmission of energy to one direction. Without the physical constraint of a waveguide, wave intensities de ...
are used as components in integrated optical circuits (e.g. combined with lasers or
light-emitting diodes
A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (cor ...
, LEDs) or as the transmission medium in local and long haul
optical communication systems.
Mechanisms of attenuation
Attenuation
In physics, attenuation (in some contexts, extinction) is the gradual loss of flux intensity through a medium. For instance, dark glasses attenuate sunlight, lead attenuates X-rays, and water and air attenuate both light and sound at variabl ...
in
fiber optics, also known as transmission loss, is the reduction in intensity of the light beam (or signal) with respect to distance traveled through a transmission medium. Attenuation coefficients in fiber optics usually use units of dB/km through the medium due to the very high quality of transparency of modern optical transmission media. The medium is usually a fiber of silica glass that confines the incident light beam to the inside. Attenuation is an important factor limiting the transmission of a signal across large distances. In optical fibers the main attenuation source is scattering from molecular level irregularities (
Rayleigh scattering
Rayleigh scattering ( ), named after the 19th-century British physicist Lord Rayleigh (John William Strutt), is the predominantly elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of th ...
) due to structural disorder and compositional fluctuations of the
glass structure. This same phenomenon is seen as one of the limiting factors in the transparency of infrared missile domes. Further attenuation is caused by light absorbed by residual materials, such as metals or water ions, within the fiber core and inner cladding. Light leakage due to bending, splices, connectors, or other outside forces are other factors resulting in attenuation.
As camouflage
![Expl0469 - Flickr - NOAA Photo Library](https://upload.wikimedia.org/wikipedia/commons/0/0a/Expl0469_-_Flickr_-_NOAA_Photo_Library.jpg)
Many
marine animals that float near the surface are highly transparent, giving them almost perfect
camouflage
Camouflage is the use of any combination of materials, coloration, or illumination for concealment, either by making animals or objects hard to see, or by disguising them as something else. Examples include the leopard's spotted coat, the b ...
.
[Herring, Peter (2002). ''The Biology of the Deep Ocean''. Oxford University Press. . pp. 190–191.] However, transparency is difficult for bodies made of materials that have different
refractive indices
In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium.
The refractive index determines how much the path of light is bent, or ...
from seawater. Some marine animals such as
jellyfish
Jellyfish and sea jellies are the informal common names given to the medusa-phase of certain gelatinous members of the subphylum Medusozoa, a major part of the phylum Cnidaria. Jellyfish are mainly free-swimming marine animals with umbrell ...
have gelatinous bodies, composed mainly of water; their thick
mesogloea
Mesoglea refers to the extracellular matrix found in cnidarians like coral or jellyfish that functions as a hydrostatic skeleton. It is related to but distinct from mesohyl, which generally refers to extracellular material found in sponges.
Descr ...
is acellular and highly transparent. This conveniently makes them
buoyant
Buoyancy (), or upthrust, is an upward force exerted by a fluid that opposes the weight of a partially or fully immersed object. In a column of fluid, pressure increases with depth as a result of the weight of the overlying fluid. Thus the pr ...
, but it also makes them large for their muscle mass, so they cannot swim fast, making this form of camouflage a costly trade-off with mobility.
[ Gelatinous ]plankton
Plankton are the diverse collection of organisms found in water (or air) that are unable to propel themselves against a current (or wind). The individual organisms constituting plankton are called plankters. In the ocean, they provide a crucia ...
ic animals are between 50 and 90 percent transparent. A transparency of 50 percent is enough to make an animal invisible to a predator such as cod
Cod is the common name for the demersal fish genus '' Gadus'', belonging to the family Gadidae. Cod is also used as part of the common name for a number of other fish species, and one species that belongs to genus ''Gadus'' is commonly not call ...
at a depth of ; better transparency is required for invisibility
Invisibility is the state of an object that cannot be seen. An object in this state is said to be ''invisible'' (literally, "not visible"). The phenomenon is studied by physics and perceptual psychology.
Since objects can be seen by light i ...
in shallower water, where the light is brighter and predators can see better. For example, a cod can see prey that are 98 percent transparent in optimal lighting in shallow water. Therefore, sufficient transparency for camouflage is more easily achieved in deeper waters.[ For the same reason, transparency in air is even harder to achieve, but a partial example is found in the
]glass frog
The glass frogs belong to the amphibian family Centrolenidae ( order Anura). While the general background coloration of most glass frogs is primarily lime green, the abdominal skin of some members of this family is transparent and translucent ...
s of the South American rain forest, which have translucent skin and pale greenish limbs. Several Central American species of clearwing ( ithomiine) butterflies and many dragonflies
A dragonfly is a flying insect belonging to the infraorder Anisoptera below the order Odonata. About 3,000 extant species of true dragonfly are known. Most are tropical, with fewer species in temperate regions. Loss of wetland habitat threa ...
and allied insect
Insects (from Latin ') are pancrustacean hexapod invertebrates of the class Insecta. They are the largest group within the arthropod phylum. Insects have a chitinous exoskeleton, a three-part body ( head, thorax and abdomen), three ...
s also have wings which are mostly transparent, a form of crypsis that provides some protection from predators.
See also
*Brillouin scattering Brillouin scattering (also known as Brillouin light scattering or BLS), named after Léon Brillouin, refers to the interaction of light with the material waves in a medium (e.g. electrostriction and magnetostriction). It is mediated by the refractiv ...
*Clarity meter
A transparency meter, also called a clarity meter, is an instrument used to measure the transparency of an object. Transparency refers to the optical distinctness with which an object can be seen when viewed through plastic film/sheet, glass, etc ...
*Colloidal crystal A colloidal crystal is an ordered array of colloid particles and fine grained materials analogous to a standard crystal whose repeating subunits are atoms or molecules. A natural example of this phenomenon can be found in the gem opal, where sphere ...
* Haze (optics)
*Light scattering
Scattering is a term used in physics to describe a wide range of physical processes where moving particles or radiation of some form, such as light or sound, are forced to deviate from a straight trajectory by localized non-uniformities (including ...
*Pellicle mirror
A pellicle mirror is an ultra-thin, ultra-lightweight semi-transparent mirror employed in the light path of an optical instrument, splitting the light beam into two separate beams, both of reduced light intensity. Splitting the beam allows its use ...
*Photonic crystal
A photonic crystal is an optical nanostructure in which the refractive index changes periodically. This affects the propagation of light in the same way that the structure of natural crystals gives rise to X-ray diffraction and that the atomic ...
* Transparent metals
*Turbidity
Turbidity is the cloudiness or haziness of a fluid caused by large numbers of individual particles that are generally invisible to the naked eye, similar to smoke in air. The measurement of turbidity is a key test of water quality.
Fluids ...
References
Further reading
*''Electrodynamics of continuous media'', Landau, L. D., Lifshits. E.M. and Pitaevskii, L.P., (Pergamon Press, Oxford, 1984)
*''Laser Light Scattering: Basic Principles and Practice'' Chu, B., 2nd Edn. (Academic Press, New York 1992)
*''Solid State Laser Engineering'', W. Koechner (Springer-Verlag, New York, 1999)
*''Introduction to Chemical Physics'', J.C. Slater (McGraw-Hill, New York, 1939)
*''Modern Theory of Solids'', F. Seitz, (McGraw-Hill, New York, 1940)
*''Modern Aspects of the Vitreous State'', J.D.MacKenzie, Ed. (Butterworths, London, 1960)
External links
UV stability
Properties of Optical Materials
{{DEFAULTSORT:Transparent Materials
Glass engineering and science
Dimensionless numbers