silicate mineral
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.
In mineralogy, silica (silicon dioxide, ) is usually consid ...
with formula (Fe2+)8Ti3Zr2 Si3O24. It is mostly composed of
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
,
oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
,
silicon
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic tab ...
,
zirconium
Zirconium is a chemical element with the symbol Zr and atomic number 40. The name ''zirconium'' is taken from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian '' zargun'' (zircon; ''zar-gun'', ...
and
titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
with smaller fractions of
yttrium
Yttrium is a chemical element with the symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost always found in com ...
and
calcium
Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...
. It is named after the
Mare Tranquillitatis
Mare Tranquillitatis (Latin ''tranquillitātis'', the Sea of Tranquillity or Sea of Tranquility; see spelling differences) is a lunar mare that sits within the Tranquillitatis basin on the Moon. It is the first location on another world to be ...
(Sea of Tranquility), the place on the Moon from which the rock samples in which it was found were brought during the
Apollo 11
Apollo 11 (July 16–24, 1969) was the American spaceflight that first landed humans on the Moon. Commander Neil Armstrong and lunar module pilot Buzz Aldrin landed the Apollo Lunar Module ''Eagle'' on July 20, 1969, at 20:17 UTC, an ...
mission in 1969. It was the last mineral brought from the Moon which was thought to be unique, with no counterpart on Earth, until it was discovered in Australia in 2011.
Discovery
In 1970, material scientists found a new unnamed Fe, Ti, Zr- silicate mineral containing rare-earths and Y in lunar rock sample 10047. The first detailed analysis of the mineral was published in 1971 and the name "tranquillityite" was proposed and later accepted by the
International Mineralogical Association
Founded in 1958, the International Mineralogical Association (IMA) is an international group of 40 national societies. The goal is to promote the science of mineralogy and to standardize the nomenclature of the 5000 plus known mineral species. Th ...
. It was later found in lunar rock samples from all Apollo missions. Samples were dated by Pb/Pb ion probe techniques.
Together with armalcolite and pyroxferroite, it is one of the three minerals which were first discovered on the Moon, before terrestrial occurrences were found. Fragments of tranquillityite were later found in Northwest Africa, in the NWA 856
Martian meteorite
A Martian meteorite is a rock that formed on Mars, was ejected from the planet by an impact event, and traversed interplanetary space before landing on Earth as a meteorite. , 277 meteorites had been classified as Martian, less than half a percen ...
.
Terrestrial occurrences of tranquillityite have been found in six localities in the
Pilbara
The Pilbara () is a large, dry, thinly populated region in the north of Western Australia. It is known for its Aboriginal peoples; its ancient landscapes; the red earth; and its vast mineral deposits, in particular iron ore. It is also a glo ...
region of
Western Australia
Western Australia (commonly abbreviated as WA) is a state of Australia occupying the western percent of the land area of Australia excluding external territories. It is bounded by the Indian Ocean to the north and west, the Southern Ocean to th ...
, in 2011. The Australian occurrences include a number of
Proterozoic
The Proterozoic () is a geological eon spanning the time interval from 2500 to 538.8million years ago. It is the most recent part of the Precambrian "supereon". It is also the longest eon of the Earth's geologic time scale, and it is subdivided ...
to
Cambrian
The Cambrian Period ( ; sometimes symbolized C with bar, Ꞓ) was the first geological period of the Paleozoic Era, and of the Phanerozoic Eon. The Cambrian lasted 53.4 million years from the end of the preceding Ediacaran Period 538.8 million ...
age
diabase
Diabase (), also called dolerite () or microgabbro,
is a mafic, holocrystalline, subvolcanic rock equivalent to volcanic basalt or plutonic gabbro. Diabase dikes and sills are typically shallow intrusive bodies and often exhibit fine-graine ...
and
gabbro
Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is che ...
dikes
Dyke (UK) or dike (US) may refer to:
General uses
* Dyke (slang), a slang word meaning "lesbian"
* Dike (geology), a subvertical sheet-like intrusion of magma or sediment
* Dike (mythology), ''Dikē'', the Greek goddess of moral justice
* Dikes ...
baddeleyite
Baddeleyite is a rare zirconium oxide mineral (ZrO2 or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dar ...
, and
apatite
Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common e ...
associated with late stage intergrowths of
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
and
feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldsp ...
.
Properties
Tranquillityite forms thin stripes up to 15 by 65 micrometres in size in basaltic rocks, where it was produced at a late crystallization stage. It is associated with
troilite
Troilite is a rare iron sulfide mineral with the simple formula of FeS. It is the iron-rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1-x)S (x = 0 to 0.2) which is iron deficient. As troilite lacks the iron deficiency whic ...
cristobalite
Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the ...
and
alkali feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspa ...
. The mineral is nearly opaque and appears dark red-brown in thin crystals. The analyzed samples contain less than 10% impurities (Y, Al, Mn, Cr, Nb and other
rare-earth element
The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silve ...
uranium
Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
. Presence of a significant amount of uranium allowed scientists to estimate the age of tranquillityite and some associated minerals in Apollo 11 samples as 3710 million years using the
uranium–lead dating
Uranium–lead dating, abbreviated U–Pb dating, is one of the oldest and most refined of the radiometric dating schemes. It can be used to date rocks that formed and crystallised from about 1 million years to over 4.5 billion years ago with routi ...
technique.
Irradiation by
alpha particle
Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be produce ...
s generated by uranium decay is believed to be the origin of the predominantly amorphous
metamict
Metamictisation (sometimes called metamictization or metamiction) is a natural process resulting in the gradual and ultimately complete destruction of a mineral's crystal structure, leaving the mineral amorphous. The affected material is therefore ...
structure of tranquillityite. Its crystals were obtained by annealing the samples at for 30 minutes. Longer annealing did not improve the crystalline quality, and annealing at higher temperatures resulted in spontaneous fracture of samples.
The crystals were initially found to have a
hexagonal
In geometry, a hexagon (from Greek , , meaning "six", and , , meaning "corner, angle") is a six-sided polygon. The total of the internal angles of any simple (non-self-intersecting) hexagon is 720°.
Regular hexagon
A '' regular hexagon'' has ...
crystal structure with the lattice parameters, ''a'' = 1.169 nm, ''c'' = 2.225 nm and three formula units per unit cell, but later reassigned a
face-centered cubic
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
There are three main varieties of ...
structure (
fluorite
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.
The Mohs sca ...
-like). A tranquillityite-like crystalline phase has been synthesized by mixing oxide powders in an appropriate ratio, determined from the chemical analysis of the lunar samples, and annealing the mixture at . This phase was not pure, but intergrown with various intermetallic compounds.