Tianji Coal Chemistry Industry Group Chemical Spill
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The Tianji Coal Chemical Industry Group chemical spill was a severe chemical spill that occurred in
Shanxi Shanxi (; ; formerly romanised as Shansi) is a landlocked province of the People's Republic of China and is part of the North China region. The capital and largest city of the province is Taiyuan, while its next most populated prefecture-lev ...
Province,
China China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's most populous country, with a population exceeding 1.4 billion, slightly ahead of India. China spans the equivalent of five time zones and ...
during 2012–13. More than 39 tons of
aniline Aniline is an organic compound with the formula C6 H5 NH2. Consisting of a phenyl group attached to an amino group, aniline is the simplest aromatic amine In organic chemistry, an aromatic amine is an organic compound consisting of an aroma ...
s (toxic chemicals widely used as precursors in the manufacture of pigment, herbicides and other chemicals) leaked from a loose drainage valve at a plant owned by Tianji Coal Chemical Industry Group in the
Shanxi Shanxi (; ; formerly romanised as Shansi) is a landlocked province of the People's Republic of China and is part of the North China region. The capital and largest city of the province is Taiyuan, while its next most populated prefecture-lev ...
city of
Changzhi Changzhi () is a prefecture-level city in the southeast of Shanxi Province, China, bordering the provinces of Hebei and Henan to the northeast and east, respectively. Historically, the city was one of the 36 administrative areas (see Administrat ...
. This chemical spill contaminated the Zhuozhang River which is the source of drinking water for more than one million people, and so caused a water crisis in the downstream City of
Handan Handan is a prefecture-level city located in the southwest of Hebei province, China. The southernmost prefecture-level city of the province, it borders Xingtai on the north, and the provinces of Shanxi on the west, Henan on the south and Shando ...
,
Hebei Hebei or , (; alternately Hopeh) is a northern province of China. Hebei is China's sixth most populous province, with over 75 million people. Shijiazhuang is the capital city. The province is 96% Han Chinese, 3% Manchu, 0.8% Hui, an ...
Province.


Tianji Coal Chemical Industry Group

Tianji Coal Chemical Industry Group is one of the five largest state-owned coal companies in Shanxi. They use a water-intensive
gasification Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (). This is achieved by reacting ...
process to convert
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dea ...
to chemicals that are critical for a wide range of products. According to a Greenpeace report, the factory owned by Tianji Industry Group in Changzhi dumps more than six million tons of wastewater per year. In 2010 and 2011, Tianji was judged by Shanxi’s environmental protection bureau to be polluting above normal levels in four quarters and was fined each time.


Aniline leak

An aniline leak occurred on December 31, 2012 due to a poor-quality metal hose. About 39 tons of aniline, a potential
carcinogen A carcinogen is any substance, radionuclide, or radiation that promotes carcinogenesis (the formation of cancer). This may be due to the ability to damage the genome or to the disruption of cellular metabolic processes. Several radioactive substan ...
, went into the drainage from the
fertilizer A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...
factory. Thirty tons were contained by a reservoir, but nearly nine tons leaked into the Zhuozhang River. A large amount of dead fish was seen in the upper reaches of the Zhuozhang River. Leaked aniline traveled along the
Zhang River The Zhang River is a tributary of the Wei River in China. The river commences at the confluence of the rivers Qingzhang (or Clear Zhang, 清漳河) and Zhuozhang (or Turbid Zhang, 浊漳河), where between She county of Hebei and Linzhou of ...
and reached reservoirs in neighboring cities.


Water crisis

The contaminated Zhuozhang River feeds into the
Zhang River The Zhang River is a tributary of the Wei River in China. The river commences at the confluence of the rivers Qingzhang (or Clear Zhang, 清漳河) and Zhuozhang (or Turbid Zhang, 浊漳河), where between She county of Hebei and Linzhou of ...
, which is a source of drinking water for
Shanxi Shanxi (; ; formerly romanised as Shansi) is a landlocked province of the People's Republic of China and is part of the North China region. The capital and largest city of the province is Taiyuan, while its next most populated prefecture-lev ...
,
Hebei Hebei or , (; alternately Hopeh) is a northern province of China. Hebei is China's sixth most populous province, with over 75 million people. Shijiazhuang is the capital city. The province is 96% Han Chinese, 3% Manchu, 0.8% Hui, an ...
and
Henan Henan (; or ; ; alternatively Honan) is a landlocked province of China, in the central part of the country. Henan is often referred to as Zhongyuan or Zhongzhou (), which literally means "central plain" or "midland", although the name is al ...
provinces. Therefore, the spill affected at least 28 villages and a handful of cities of more than one million people, including Handan. After receiving confirmation of this chemical spill, officials in
Handan Handan is a prefecture-level city located in the southwest of Hebei province, China. The southernmost prefecture-level city of the province, it borders Xingtai on the north, and the provinces of Shanxi on the west, Henan on the south and Shando ...
shut down part of its municipal water supply system, which sent residents into a scramble for bottled water. In the countryside, officials also told farmers not to graze their livestock near the river. Fire engines were mobilized to bring water to the city's residents and 66,000 bottles of clean water were bought in from other cities. Underground reservoirs were also opened to support the city’s water use.


River cleanup

Nearly 5000 workers were called in for an immediate clean-up of the river. Because of the low temperature, a large part of contaminants was stopped by ice in the river. 670 tons of contaminated ice and more than 750 tons of wastewater have been cleared away.
Activated carbon Activated carbon, also called activated charcoal, is a form of carbon commonly used to filter contaminants from water and air, among many other uses. It is processed (activated) to have small, low-volume pores that increase the surface area avail ...
was also used to absorb the chemicals remaining in the unfrozen water below. After several days of cleanup, concentrations of aniline in the river decreased to 2.15 mg/L from the previous level of 72 mg/L, according to data from Wangjiazhuang monitoring station on Zhuozhang river near the eastern border of Shanxi province. However, based on national standards, the concentration should be less than 0.1 mg/L. Since the pollutants are not expected to decompose easily, it took weeks to solve the problems caused by this spill.


Delayed report

After the aniline leak occurred, officials in
Changzhi Changzhi () is a prefecture-level city in the southeast of Shanxi Province, China, bordering the provinces of Hebei and Henan to the northeast and east, respectively. Historically, the city was one of the 36 administrative areas (see Administrat ...
delayed reporting the spill for five days. The reason for delay is not clear, but it may be due to the large underestimations of the amount of leaked anilines in the first few days after spills. According to the regulation passed by the State Council in 2007, an institution responsible for an accident should report within an hour to the production safety department of a county-level government or higher. The report should reach a higher level of government within two hours. The mayor of Changzhi has apologized for the delay in reporting the spill affecting supplies of drinking water.


Punishment

After investigation into this spill, 24 managers in the company who were responsible for supervision were given administrative disciplinary sanctions. The mayor of Changzhi was removed from his position. Two heads of the plant's storage workshop were fired.


Challenges

The conflict over the Changzhi spill has drawn attention to the growing problems with water use and
pollution in China Pollution in China is one aspect of the broader topic of environmental issues in China. Various forms of pollution have increased as China has industrialised, which has caused widespread environmental health problems.Jared Diamond, '' Collapse: ...
. In 2011, inspections in 200 cities across China found that water in 55 percent of the tests was rated “fairly poor to extremely poor”. During the last ten years, China has witnessed major pollution incidents due to the pursuit of economic benefit and the neglect of pollution control by local governments and enterprises. Deficiencies in emergency mechanisms to handle environmental incidents at some local governments worsen the pollution problems.China org Report, Officials sacked over chemical leaks in N. China river, Jan 7th 2013
/ref>


See also

*
Environmental issues in China Environmental issues in China had risen in tandem with the country's rapid industrialisation, as well as lax environmental oversight especially during the early 2000s. China was ranked 120th out of the 180 countries on the 2020 Environmental ...


References

{{reflist Environmental disasters in China 2012 disasters in China 2012 in the environment 2012 industrial disasters 2013 disasters in China 2013 in the environment 2013 industrial disasters