Synthetic Resin
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Synthetic resins are industrially produced
resin In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on natu ...
s, typically
viscous The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the inter ...
substances that convert into rigid
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
s by the process of curing. In order to undergo curing, resins typically contain reactive end groups, such as acrylates or epoxides. Some synthetic resins have properties similar to natural plant
resin In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on natu ...
s, but many do not. Synthetic resins are of several classes. Some are manufactured by esterification of
organic compound In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The ...
s. Some are
thermosetting plastic In materials science, a thermosetting polymer, often called a thermoset, is a polymer that is obtained by irreversibly hardening (" curing") a soft solid or viscous liquid prepolymer (resin). Curing is induced by heat or suitable radiation and ...
s in which the term "resin" is loosely applied to the reactant(s), the product, or both. "Resin" may be applied to one of two monomers in a
copolymer In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are some ...
, the other being called a "hardener", as in
epoxy resin Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also coll ...
s. For thermosetting plastics that require only one monomer, the monomer compound is the "resin". For example, liquid
methyl methacrylate Methyl methacrylate (MMA) is an organic compound with the formula CH2=C(CH3)COOCH3. This colorless liquid, the methyl ester of methacrylic acid (MAA), is a monomer produced on a large scale for the production of poly(methyl methacrylate) (PMMA ...
is often called the "resin" or "casting resin" while in the liquid state, before it polymerizes and "sets". After setting, the resulting
poly(methyl methacrylate) Poly(methyl methacrylate) (PMMA) belongs to a group of materials called engineering plastics. It is a transparent thermoplastic. PMMA is also known as acrylic, acrylic glass, as well as by the trade names and brands Crylux, Plexiglas, Acrylite, ...
(PMMA) is often renamed "acrylic glass" or "acrylic". (This is the same material called Plexiglas and Lucite).


Types of synthetic resins

The classic variety is
epoxy resin Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also coll ...
, manufactured through
polymerization In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer, monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are ...
-polyaddition or polycondensation reactions, used as a thermoset polymer for adhesives and composites. Epoxy resin is two times stronger than concrete, seamless, and waterproof. Accordingly, it has been mainly in use for industrial flooring purposes since the 1960s. Since 2000, however, epoxy and polyurethane resins are used in interiors as well, mainly in Western Europe. Synthetic casting "resin" for embedding display objects in Plexiglas/Lucite (
PMMA PMMA may refer to: * para-Methoxymethamphetamine, a stimulant drug * Philippine Merchant Marine Academy The Philippine Merchant Marine Academy ( fil, Akademiya sa Bapor Pangkalakalan ng Pilipinas) also referred to by its acronym PMMA) is a ma ...
) is simply
methyl methacrylate Methyl methacrylate (MMA) is an organic compound with the formula CH2=C(CH3)COOCH3. This colorless liquid, the methyl ester of methacrylic acid (MAA), is a monomer produced on a large scale for the production of poly(methyl methacrylate) (PMMA ...
liquid, into which a polymerization catalyst is added and mixed, causing it to "set" (polymerize). The polymerization creates a block of PMMA plastic ("acrylic glass") which holds the display object inside a transparent block. Another synthetic polymer, sometimes called by the same general category, is
acetal resin Polyoxymethylene (POM), also known as acetal, polyacetal, and polyformaldehyde, is an engineering thermoplastic used in precision parts requiring high stiffness, low friction, and excellent dimensional stability. As with many other synthetic pol ...
. By contrast with the other synthetics, however, it has a simple chain structure with the repeat unit of form − H2O. Ion-exchange resins are used in water purification and
catalysis Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
of
organic reaction Organic reactions are chemical reactions involving organic compounds. The basic organic chemistry reaction types are addition reactions, elimination reactions, substitution reactions, pericyclic reactions, rearrangement reactions, Mechanistic Organ ...
s. (See also '' AT-10 resin'', ''
melamine resin Melamine resin or melamine formaldehyde (also shortened to melamine) is a resin with melamine rings terminated with multiple hydroxyl groups derived from formaldehyde. This thermosetting plastic material is made from melamine and formaldehyde. ...
''.) Certain ion-exchange resins are also used pharmaceutically as
bile acid sequestrant The bile acid sequestrants are a group of resins used to bind certain components of bile in the gastrointestinal tract. They disrupt the enterohepatic circulation of bile acids by combining with bile constituents and preventing their reabsorption fr ...
s, mainly as hypolipidemic agents, although they may be used for purposes other than lowering cholesterol. Solvent impregnated resins (SIRs) are porous resin particles which contain an additional liquid extractant inside the porous matrix. The contained extractant is supposed to enhance the capacity of the resin particles. A large category of resins, which constitutes 75% of resins used, is that of the unsaturated polyester resins. The production of PVC entails the production of "vinyl chloride resins", which differ in the degree of polymerization.


Silicone resisns

Silicone resin Silicone resins are a type of silicone material which is formed by branched, cage-like oligosiloxanes with the general formula of RnSiXmOy, where R is a non reactive substituent, usually Methyl (Me) or Phenyl (Ph), and X is a functional group Hydr ...
s are
silicone A silicone or polysiloxane is a polymer made up of siloxane (−R2Si−O−SiR2−, where R = organic group). They are typically colorless oils or rubber-like substances. Silicones are used in sealants, adhesives, lubricants, medicine, cooking ...
-based polymers that exhibit various useful properties like weatherability (durability), dielectricity, water repellency, thermal stability, and chemical inertness.


Health hazards

Health hazards potentially associated with synthetic resins are typically less of a concern than the hazards associated with the cured products, which are more commonly in contact with consumers. Issues of interest include the effects of unconsumed monomers, oligomers, and solvent carriers. Dental restorative materials based on bis-GMA-containing resins can break down into or be contaminated with the related compound
bisphenol A Bisphenol A (BPA) is a chemical compound primarily used in the manufacturing of various plastics. It is a colourless solid which is soluble in most common organic solvents, but has very poor solubility in water. BPA is produced on an industrial s ...
, a potential endocrine disrupter. However, no negative health effects of bis-GMA use in dental resins have been found.


See also

* Prepolymer * Resin casting *
Waterborne resins Waterborne resins are sometimes called water-based resins. They are resins or polymeric resins that use water as the carrying medium as opposed to solvent or solvent-less. Resins are used in the production of coatings, adhesives, sealants, elastom ...


References

{{Authority control Plastics * Polymers es:Resina#Resinas sintéticas ja:合成樹脂