Spertiniite is a rare copper hydroxide mineral. Chemically it is
copper(II) hydroxide
Copper(II) hydroxide is the hydroxide of copper with the chemical formula of Cu(OH)2. It is a pale greenish blue or bluish green solid. Some forms of copper(II) hydroxide are sold as "stabilized" copper(II) hydroxide, although they likely consist ...
with formula Cu(OH)
2. It occurs as blue to blue green tabular
orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a r ...
crystal aggregates in a secondary alkaline environment altering
chalcocite
Chalcocite (), copper(I) sulfide (Cu2S), is an important copper ore mineral. It is opaque and dark gray to black, with a metallic luster. It has a hardness of 2.5–3 on the Mohs scale. It is a sulfide with a monoclinic crystal system.
The ...
. Associated minerals include chalcocite,
atacamite
Atacamite is a copper halide mineral: a copper(II) chloride hydroxide with formula Cu2Cl(OH)3. It was first described for deposits in the Atacama Desert of Chile in 1801 by D. de Fallizen. The Atacama Desert is also the namesake of the mineral.
...
,
native copper
Native copper is an uncombined form of copper that occurs as a natural mineral. Copper is one of the few metallic elements to occur in native form, although it most commonly occurs in oxidized states and mixed with other elements. Native coppe ...
,
diopside
Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
,
grossular
Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from t ...
and
vesuvianite
Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. It was first discovered within ...
.
[
]
Discovery and occurrence
It was first described in 1981 for an occurrence in the Jeffrey quarry of the Johns-Manville mine, Asbestos
Asbestos () is a naturally occurring fibrous silicate mineral. There are six types, all of which are composed of long and thin fibrous crystals, each fibre being composed of many microscopic "fibrils" that can be released into the atmosphere b ...
, Estrie
Estrie () is an administrative region of Quebec that comprises the Eastern Townships. ''Estrie'', a French neologism, was coined as a derivative of ''est'', "east". Originally settled by anglophones, today it is about 90 per cent francophone. Angl ...
, Québec
Quebec ( ; )According to the Government of Canada, Canadian government, ''Québec'' (with the acute accent) is the official name in Canadian French and ''Quebec'' (without the accent) is the province's official name in Canadian English is ...
. It was named for mine geologist Francesco Spertini (born 1937).[ In addition to the type locality, it has also been reported from ]Mont Saint-Hilaire
Mont Saint-Hilaire (English: Mount Saint-Hilaire; abe, Wigwômadenizibo; see for other names) is an isolated hill, high, in the Montérégie region of southern Quebec. It is about thirty kilometres east of Montreal, and immediately east of the ...
, Quebec; Ely, White Pine County, Nevada
White Pine County is a largely rural, mountain county along the central eastern boundary of the U.S. state of Nevada. As of the 2010 census, the population was 10,030. Its county seat is Ely. The name "(Rocky Mountain) white pine" is an old ...
; and Bisbee, Cochise County, Arizona
Cochise County () is a county in the southeastern corner of the U.S. state of Arizona. It is named after the Native American chief Cochise.
The population was 125,447 at the 2020 census. The county seat is Bisbee and the most populous city is ...
. It has been reported from Dzhezkazgan, Kazakhstan
Kazakhstan, officially the Republic of Kazakhstan, is a transcontinental country located mainly in Central Asia and partly in Eastern Europe. It borders Russia to the north and west, China to the east, Kyrgyzstan to the southeast, Uzbeki ...
; from slag
Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-prod ...
at Juliushutte, Astfeld, Harz Mountains
The Harz () is a highland area in northern Germany. It has the highest elevations for that region, and its rugged terrain extends across parts of Lower Saxony, Saxony-Anhalt, and Thuringia. The name ''Harz'' derives from the Middle High German ...
, Germany
Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...
; and from Tsumeb
, nickname =
, settlement_type = City
, motto = ''Glück Auf'' (German language, German for ''Good luck'')
, image_skyline = Welcome to tsumeb.jpg
, imagesize =
, image_caption ...
, Namibia
Namibia (, ), officially the Republic of Namibia, is a country in Southern Africa. Its western border is the Atlantic Ocean. It shares land borders with Zambia and Angola to the north, Botswana to the east and South Africa to the south and ea ...
.[
A 2006 study has produced evidence the blue mineral ]chrysocolla
Chrysocolla ( ) is a hydrated copper phyllosilicate mineral and mineraloid with formula (x<1)[ or .][
The structure of the mineral has been questioned, as a 2006 spectrographic study suggest material identified as ...]
may be a microscopic mixture of spertiniite, amorphous
In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal.
Etymology
The term comes from the Greek ''a'' ("wi ...
silica and water.Chrysocolla on Mindat
/ref>
![Kristallstruktur Kupfer(II)-hydroxid](https://upload.wikimedia.org/wikipedia/commons/7/79/Kristallstruktur_Kupfer%28II%29-hydroxid.png)
References
{{Reflist
Copper(II) minerals
Hydroxide minerals
Orthorhombic minerals
Minerals in space group 36