Sodium aluminate is an

inorganic In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...

chemical that is used as an effective source of

aluminium hydroxide Aluminium hydroxide, Al(OH)3, is found in nature as the mineral gibbsite (also known as hydrargillite) and its three much rarer polymorphs: bayerite, doyleite, and nordstrandite. Aluminium hydroxide is amphoteric, i.e., it has both basic and ...

for many industrial and technical applications. Pure

sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...

aluminate In chemistry, an aluminate is a compound containing an oxyanion of aluminium, such as sodium aluminate. In the naming of inorganic compounds, it is a suffix that indicates a polyatomic ion, polyatomic anion with a central aluminum atom. Aluminate ...

(

anhydrous A substance is anhydrous if it contains no water. Many processes in chemistry can be impeded by the presence of water; therefore, it is important that water-free reagents and techniques are used. In practice, however, it is very difficult to achie ...

) is a white

crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...

line solid having a formula variously given as NaAlO₂, NaAl(OH)₄ (

hydrated Drinking is the act of ingesting water or other liquids into the body through the mouth, proboscis, or elsewhere. Humans drink by swallowing, completed by peristalsis in the esophagus. The physiological processes of drinking vary widely among o ...

), Na₂O·Al₂O₃, or Na₂Al₂O₄. Commercial sodium aluminate is available as a solution or a solid.
Other related compounds, sometimes called sodium aluminate, prepared by reaction of Na₂O and Al₂O₃ are Na₅AlO₄ which contains discrete AlO₄⁵⁻ anions, Na₇Al₃O₈ and Na₁₇Al₅O₁₆ which contain complex polymeric anions, and NaAl₁₁O₁₇, once mistakenly believed to be β-alumina, a phase of aluminium oxide.Egon Wiberg, Arnold Frederick Holleman (2001) ''Inorganic Chemistry'', Elsevier

Structure

Anhydrous sodium aluminate, NaAlO₂, contains a three-dimensional framework of corner linked AlO₄ tetrahedra. The hydrated form NaAlO₂·5/4H₂O has layers of AlO₄ tetrahedra joined into rings and the layers are held together by sodium ions and water molecules that hydrogen bond to O atoms in the AlO₄ tetrahedra.

Manufacturing

Sodium aluminate is manufactured by the dissolution of

(Al(OH)₃) in a

caustic soda Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations and hydroxide anions . Sodium hydroxide is a highly caustic base and alka ...

(NaOH) solution. Aluminium hydroxide (

gibbsite Gibbsite, Al(OH)3, is one of the mineral forms of aluminium hydroxide. It is often designated as γ-Al(OH)3 (but sometimes as α-Al(OH)3.). It is also sometimes called hydrargillite (or hydrargyllite). Gibbsite is an important ore of aluminiu ...

) can be dissolved in 20–25% aqueous NaOH solution at a temperature near the boiling point. The use of more concentrated NaOH solutions leads to a semi-solid product. The process must be carried out in steam-heated vessels of

nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to ...

steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...

, and the aluminium hydroxide should be boiled with approximately 50% aqueous caustic soda until a pulp forms. The final mixture has to be poured into a tank and cooled; a solid mass containing about 70% NaAlO₂ then forms. After being crushed, this product is dehydrated in a rotary oven. The resulting product contains 90% NaAlO₂ and 1% water, together with 1% free NaOH.

Reaction of aluminium metal and alkali

Sodium aluminate is also formed by the action of sodium hydroxide on elemental aluminium which is an

amphoteric In chemistry, an amphoteric compound () is a molecule or ion that can react both as an acid and as a base. What exactly this can mean depends on which definitions of acids and bases are being used. One type of amphoteric species are amphiproti ...

metal. The reaction is highly exothermic once established and is accompanied by the rapid evolution of hydrogen gas. The reaction is sometimes written as: : 2Al + 2NaOH + 2H₂O → 2NaAlO₂ + 3H₂ However, the species produced in solution is likely to contain the l(OH)₄sup>− ion or perhaps the l(H₂O)₂(OH)₄sup>− ion.

Uses

In water treatment it is used as an adjunct to water softening systems, as a coagulant aid to improve

flocculation Flocculation, in the field of chemistry, is a process by which colloidal particles come out of suspension to sediment under the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from pr ...

, and for removing dissolved

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...

and

phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phospho ...

s. In construction technology, sodium aluminate is employed to accelerate the solidification of

concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wi ...

, mainly when working during frost. Sodium aluminate is also used in the

paper industry The pulp and paper industry comprises companies that use wood as raw material and produce pulp, paper, paperboard and other cellulose-based products. Manufacturing process The pulp is fed to a paper machine where it is formed as a paper web an ...

, for

fire brick A fire brick, firebrick, or refractory is a block of ceramic material used in lining furnaces, kilns, fireboxes, and fireplaces. A refractory brick is built primarily to withstand high temperature, but will also usually have a low thermal con ...

production, alumina production and so forth. Sodium aluminate solutions are intermediates in the production of

zeolites Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ･y where is either a metal ion or H+. These pos ...

.Alan Dyer, (1994), ''Encyclopedia of Inorganic Chemistry'', R. Bruce King (ed.), John Wiley & Sons,

Structure

Manufacturing

Reaction of aluminium metal and alkali

Uses

References

See also