Seawater, or salt water, is
water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a ...
from a
sea
The sea, connected as the world ocean or simply the ocean, is the body of salty water that covers approximately 71% of the Earth's surface. The word sea is also used to denote second-order sections of the sea, such as the Mediterranean Sea, ...
or
ocean
The ocean (also the sea or the world ocean) is the body of salt water that covers approximately 70.8% of the surface of Earth and contains 97% of Earth's water. An ocean can also refer to any of the large bodies of water into which the wo ...
. On average, seawater in the world's oceans has a
salinity
Salinity () is the saltiness or amount of salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensionless and equal ...
of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has approximately of
dissolved salts (predominantly
sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
() and
chloride
The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts ...
()
ions
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
). The average density at the surface is 1.025 kg/L. Seawater is
denser
Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek language, Greek letter Rho (letter), rho), although the Latin letter ''D'' ca ...
than both
fresh water
Fresh water or freshwater is any naturally occurring liquid or frozen water containing low concentrations of dissolved salts and other total dissolved solids. Although the term specifically excludes seawater and brackish water, it does include ...
and pure water (density 1.0 kg/L at ) because the dissolved salts increase the mass by a larger proportion than the volume. The freezing point of seawater decreases as salt concentration increases. At typical salinity, it
freezes
Freezing is a phase transition where a liquid turns into a solid when its temperature is lowered below its freezing point. In accordance with the internationally established definition, freezing means the solidification phase change of a liquid o ...
at about . The coldest seawater still in the liquid state ever recorded was found in 2010, in a stream under an
Antarctic
The Antarctic ( or , American English also or ; commonly ) is a polar region around Earth's South Pole, opposite the Arctic region around the North Pole. The Antarctic comprises the continent of Antarctica, the Kerguelen Plateau and other ...
glacier
A glacier (; ) is a persistent body of dense ice that is constantly moving under its own weight. A glacier forms where the accumulation of snow exceeds its Ablation#Glaciology, ablation over many years, often Century, centuries. It acquires dis ...
: the measured temperature was . Seawater
pH is typically limited to a range between 7.5 and 8.4.
However, there is no universally accepted reference pH-scale for seawater and the difference between measurements based on different reference scales may be up to 0.14 units.
Properties
Salinity
Although the vast majority of seawater has a salinity of between 31 and 38 g/kg, that is 3.1–3.8%, seawater is not uniformly saline throughout the world. Where mixing occurs with freshwater runoff from river mouths, near melting glaciers or vast amounts of precipitation (e.g.
Monsoon
A monsoon () is traditionally a seasonal reversing wind accompanied by corresponding changes in precipitation but is now used to describe seasonal changes in atmospheric circulation and precipitation associated with annual latitudinal oscil ...
), seawater can be substantially less saline. The most saline open sea is the
Red Sea
The Red Sea ( ar, البحر الأحمر - بحر القلزم, translit=Modern: al-Baḥr al-ʾAḥmar, Medieval: Baḥr al-Qulzum; or ; Coptic: ⲫⲓⲟⲙ ⲛ̀ϩⲁϩ ''Phiom Enhah'' or ⲫⲓⲟⲙ ⲛ̀ϣⲁⲣⲓ ''Phiom ǹšari''; T ...
, where high rates of
evaporation
Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidi ...
, low
precipitation
In meteorology, precipitation is any product of the condensation of atmospheric water vapor that falls under gravitational pull from clouds. The main forms of precipitation include drizzle, rain, sleet, snow, ice pellets, graupel and hail. ...
and low river run-off, and confined circulation result in unusually salty water. The salinity in isolated bodies of water can be considerably greater still about ten times higher in the case of the
Dead Sea
The Dead Sea ( he, יַם הַמֶּלַח, ''Yam hamMelaḥ''; ar, اَلْبَحْرُ الْمَيْتُ, ''Āl-Baḥrū l-Maytū''), also known by other names, is a salt lake bordered by Jordan to the east and Israel and the West Bank ...
. Historically, several salinity scales were used to approximate the absolute salinity of seawater. A popular scale was the "Practical Salinity Scale" where salinity was measured in "practical salinity units (PSU)". The current standard for salinity is the "Reference Salinity" scale with the salinity expressed in units of "g/kg".
Density
The
density
Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...
of surface seawater ranges from about 1020 to 1029 kg/m
3, depending on the temperature and salinity. At a temperature of 25 °C, the salinity of 35 g/kg and 1 atm pressure, the density of seawater is 1023.6 kg/m
3.
Deep in the ocean, under high pressure, seawater can reach a density of 1050 kg/m
3 or higher. The density of seawater also changes with salinity. Brines generated by seawater desalination plants can have salinities up to 120 g/kg. The density of typical seawater brine of 120 g/kg salinity at 25 °C and atmospheric pressure is 1088 kg/m
3.
[ Seawater pH is limited to the range 7.5 to 8.4. The ]speed of sound
The speed of sound is the distance travelled per unit of time by a sound wave as it propagates through an elastic medium. At , the speed of sound in air is about , or one kilometre in or one mile in . It depends strongly on temperature as w ...
in seawater is about 1,500 m/s (whereas the speed of sound is usually around 330 m/s in air at roughly 101.3 kPa pressure, 1 atmosphere), and varies with water temperature, salinity, and pressure. The thermal conductivity
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa.
Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
of seawater is 0.6 W/mK at 25 °C and a salinity of 35 g/kg.
The thermal conductivity decreases with increasing salinity and increases with increasing temperature.
Chemical composition
Seawater contains more dissolved ion
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
s than all types of freshwater. However, the ratios of solutes differ dramatically. For instance, although seawater contains about 2.8 times more bicarbonate
In inorganic chemistry, bicarbonate (IUPAC-recommended nomenclature: hydrogencarbonate) is an intermediate form in the deprotonation of carbonic acid. It is a polyatomic anion with the chemical formula .
Bicarbonate serves a crucial biochemic ...
than river water, the percentage
In mathematics, a percentage (from la, per centum, "by a hundred") is a number or ratio expressed as a fraction of 100. It is often denoted using the percent sign, "%", although the abbreviations "pct.", "pct" and sometimes "pc" are also us ...
of bicarbonate in seawater as a ratio of ''all'' dissolved ion
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
s is far lower than in river water. Bicarbonate ions constitute 48% of river water solutes but only 0.14% for seawater. Differences like these are due to the varying residence time
The residence time of a fluid parcel is the total time that the parcel has spent inside a control volume (e.g.: a chemical reactor, a lake, a human body). The residence time of a set of parcels is quantified in terms of the frequency distribution ...
s of seawater solutes; sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
and chloride
The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts ...
have very long residence times, while calcium
Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...
(vital for carbonate
A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
formation) tends to precipitate much more quickly.[ The most abundant dissolved ions in seawater are sodium, chloride, ]magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
, sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ar ...
and calcium. Its osmolarity
Osmotic concentration, formerly known as osmolarity, is the measure of solute concentration, defined as the number of osmoles (Osm) of solute per litre (L) of solution (osmol/L or Osm/L). The osmolarity of a solution is usually expressed as Osm/L ...
is about 1000 mOsm/L.
Small amounts of other substances are found, including amino acids
Amino acids are organic compounds that contain both amino and carboxylic acid functional groups. Although hundreds of amino acids exist in nature, by far the most important are the alpha-amino acids, which comprise proteins. Only 22 alpha am ...
at concentrations of up to 2 micrograms of nitrogen atoms per liter, which are thought to have played a key role in the origin of life
In biology, abiogenesis (from a- 'not' + Greek bios 'life' + genesis 'origin') or the origin of life is the natural process by which life has arisen from non-living matter, such as simple organic compounds. The prevailing scientific hypothes ...
.
Microbial components
Research in 1957 by the Scripps Institution of Oceanography
The Scripps Institution of Oceanography (sometimes referred to as SIO, Scripps Oceanography, or Scripps) in San Diego, California, US founded in 1903, is one of the oldest and largest centers for oceanography, ocean and Earth science research ...
sampled water in both pelagic
The pelagic zone consists of the water column of the open ocean, and can be further divided into regions by depth (as illustrated on the right). The word ''pelagic'' is derived . The pelagic zone can be thought of as an imaginary cylinder or wa ...
and neritic
The neritic zone (or sublittoral zone) is the relatively shallow part of the ocean above the drop-off of the continental shelf, approximately in depth.
From the point of view of marine biology it forms a relatively stable and well-illuminated ...
locations in the Pacific Ocean. Direct microscopic counts and cultures were used, the direct counts in some cases showing up to 10 000 times that obtained from cultures. These differences were attributed to the occurrence of bacteria in aggregates, selective effects of the culture media, and the presence of inactive cells. A marked reduction in bacterial culture numbers was noted below the thermocline
A thermocline (also known as the thermal layer or the metalimnion in lakes) is a thin but distinct layer in a large body of fluid (e.g. water, as in an ocean or lake; or air, e.g. an atmosphere) in which temperature changes more drastically with ...
, but not by direct microscopic observation. Large numbers of spirilli
''Spirillum'' is a genus of Gram-negative bacteria in the family ''Spirillaceae'' of the ''Nitrosomonadales'' of the ''Betaproteobacteria''.Garrity, George M.; Brenner, Don J.; Krieg, Noel R.; Staley, James T. (eds.) (2005). Bergey's Manual of ...
-like forms were seen by microscope but not under cultivation. The disparity in numbers obtained by the two methods is well known in this and other fields. In the 1990s, improved techniques of detection and identification of microbes by probing just small snippets of DNA, enabled researchers taking part in the Census of Marine Life
The Census of Marine Life was a 10-year, US $650 million scientific initiative, involving a global network of researchers in more than 80 nations, engaged to assess and explain the diversity, distribution, and abundance of life in the oceans. Th ...
to identify thousands of previously unknown microbes usually present only in small numbers. This revealed a far greater diversity than previously suspected, so that a litre of seawater may hold more than 20,000 species. Mitchell Sogin Dr. Mitchell Sogin is a distinguished senior scientist at the Marine Biological Laboratory in Woods Hole, Massachusetts, whose research investigates the evolution and diversity of single-celled organisms.
Career
Dr. Sogin obtained a BS in Chemist ...
from the Marine Biological Laboratory
The Marine Biological Laboratory (MBL) is an international center for research and education in biological and environmental science. Founded in Woods Hole, Massachusetts, in 1888, the MBL is a private, nonprofit institution that was independent ...
feels that "the number of different kinds of bacteria in the oceans could eclipse five to 10 million."
Bacteria are found at all depths in the water column
A water column is a conceptual column of water from the surface of a sea, river or lake to the bottom sediment.Munson, B.H., Axler, R., Hagley C., Host G., Merrick G., Richards C. (2004).Glossary. ''Water on the Web''. University of Minnesota-D ...
, as well as in the sediments, some being aerobic, others anaerobic. Most are free-swimming, but some exist as symbionts
Symbiosis (from Greek , , "living together", from , , "together", and , bíōsis, "living") is any type of a close and long-term biological interaction between two different biological organisms, be it mutualistic, commensalistic, or parasit ...
within other organisms – examples of these being bioluminescent bacteria. Cyanobacteria
Cyanobacteria (), also known as Cyanophyta, are a phylum of gram-negative bacteria that obtain energy via photosynthesis. The name ''cyanobacteria'' refers to their color (), which similarly forms the basis of cyanobacteria's common name, blu ...
played an important role in the evolution of ocean processes, enabling the development of stromatolites
Stromatolites () or stromatoliths () are layered sedimentary formations (microbialite) that are created mainly by photosynthetic microorganisms such as cyanobacteria, sulfate-reducing bacteria, and Pseudomonadota (formerly proteobacteria). The ...
and oxygen in the atmosphere.
Some bacteria interact with diatoms
A diatom (New Latin, Neo-Latin ''diatoma''), "a cutting through, a severance", from el, διάτομος, diátomos, "cut in half, divided equally" from el, διατέμνω, diatémno, "to cut in twain". is any member of a large group com ...
, and form a critical link in the cycling of silicon in the ocean. One anaerobic species, ''Thiomargarita namibiensis
''Thiomargarita namibiensis'' is a Gram-negative coccoid bacterium, found in the ocean sediments of the continental shelf of Namibia. It is the second largest bacterium ever discovered, as a rule in diameter, but sometimes attaining . Cells of ...
'', plays an important part in the breakdown of hydrogen sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The unde ...
eruptions from diatomaceous sediments off the Namibian coast, and generated by high rates of phytoplankton
Phytoplankton () are the autotrophic (self-feeding) components of the plankton community and a key part of ocean and freshwater ecosystems. The name comes from the Greek words (), meaning 'plant', and (), meaning 'wanderer' or 'drifter'.
Ph ...
growth in the Benguela Current upwelling zone, eventually falling to the seafloor.
Bacteria-like Archaea
Archaea ( ; singular archaeon ) is a domain of single-celled organisms. These microorganisms lack cell nuclei and are therefore prokaryotes. Archaea were initially classified as bacteria, receiving the name archaebacteria (in the Archaebac ...
surprised marine microbiologists by their survival and thriving in extreme environments, such as the hydrothermal vents
A hydrothermal vent is a fissure on the seabed from which geothermally heated water discharges. They are commonly found near volcanically active places, areas where tectonic plates are moving apart at mid-ocean ridges, ocean basins, and hotspot ...
on the ocean floor. Alkalotolerant marine bacteria
Marine prokaryotes are marine bacteria and marine archaea. They are defined by their habitat as prokaryotes that live in marine environments, that is, in the saltwater of seas or oceans or the brackish water of coastal estuaries. All cellular ...
such as ''Pseudomonas
''Pseudomonas'' is a genus of Gram-negative, Gammaproteobacteria, belonging to the family Pseudomonadaceae and containing 191 described species. The members of the genus demonstrate a great deal of metabolic diversity and consequently are able ...
'' and ''Vibrio
''Vibrio'' is a genus of Gram-negative bacteria, possessing a curved-rod (comma) shape, several species of which can cause foodborne infection, usually associated with eating undercooked seafood. Being highly salt tolerant and unable to survive ...
'' spp. survive in a pH range of 7.3 to 10.6, while some species will grow only at pH 10 to 10.6. Archaea also exist in pelagic waters and may constitute as much as half the ocean's biomass
Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms bi ...
, clearly playing an important part in oceanic processes. In 2000 sediments from the ocean floor revealed a species of Archaea that breaks down methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
, an important greenhouse
A greenhouse (also called a glasshouse, or, if with sufficient heating, a hothouse) is a structure with walls and roof made chiefly of Transparent ceramics, transparent material, such as glass, in which plants requiring regulated climatic condit ...
gas and a major contributor to atmospheric warming. Some bacteria break down the rocks of the sea floor, influencing seawater chemistry. Oil spills, and runoff containing human sewage and chemical pollutants have a marked effect on microbial life in the vicinity, as well as harbouring pathogens and toxins affecting all forms of marine life
Marine life, sea life, or ocean life is the plants, animals and other organisms that live in the salt water of seas or oceans, or the brackish water of coastal estuaries. At a fundamental level, marine life affects the nature of the planet. M ...
. The protist dinoflagellates
The dinoflagellates (Greek δῖνος ''dinos'' "whirling" and Latin ''flagellum'' "whip, scourge") are a monophyletic group of single-celled eukaryotes constituting the phylum Dinoflagellata and are usually considered algae. Dinoflagellates are ...
may at certain times undergo population explosions called blooms or red tide
A harmful algal bloom (HAB) (or excessive algae growth) is an algal bloom that causes negative impacts to other organisms by production of natural phycotoxin, algae-produced toxins, mechanical damage to other organisms, or by other means. HABs are ...
s, often after human-caused pollution. The process may produce metabolites
In biochemistry, a metabolite is an intermediate or end product of metabolism.
The term is usually used for small molecules. Metabolites have various functions, including fuel, structure, signaling, stimulatory and inhibitory effects on enzymes, c ...
known as biotoxins, which move along the ocean food chain, tainting higher-order animal consumers.
''Pandoravirus salinus
''Pandoravirus salinus'' is a large virus of genus ''Pandoravirus'', found in the marine sediment layer of the Tunquen River in Chile, and is one of the largest viruses identified, along with '' Pandoravirus dulcis''. It is 2.5 million nucleobas ...
'', a species of very large virus, with a genome much larger than that of any other virus species, was discovered in 2013. Like the other very large viruses ''Mimivirus
''Mimivirus'' is a genus of giant viruses, in the family ''Mimiviridae''. Amoeba serve as their natural hosts. This genus contains a single identified species named ''Acanthamoeba polyphaga mimivirus'' (APMV). It also refers to a group of phylo ...
'' and ''Megavirus
Megavirus is a viral genus containing a single identified species named ''Megavirus chilensis'', phylogenetically related to Acanthamoeba polyphaga Mimivirus (APMV). In colloquial speech, Megavirus chilensis is more commonly referred to as jus ...
'', ''Pandoravirus'' infects amoebas, but its genome, containing 1.9 to 2.5 megabases of DNA, is twice as large as that of ''Megavirus'', and it differs greatly from the other large viruses in appearance and in genome structure.
In 2013 researchers from Aberdeen University
, mottoeng = The fear of the Lord is the beginning of wisdom
, established =
, type = Public research universityAncient university
, endowment = £58.4 million (2021)
, budget ...
announced that they were starting a hunt for undiscovered chemicals in organisms that have evolved in deep sea trenches, hoping to find "the next generation" of antibiotics, anticipating an "antibiotic apocalypse" with a dearth of new infection-fighting drugs. The EU-funded research will start in the Atacama Trench
The Atacama Desert ( es, Desierto de Atacama) is a desert plateau in South America covering a 1,600 km (990 mi) strip of land on the Pacific coast, west of the Andes Mountains. The Atacama Desert is the driest nonpolar desert in the ...
and then move on to search trenches off New Zealand and Antarctica.
The ocean has a long history of human waste disposal on the assumption that its vast size makes it capable of absorbing and diluting all noxious material.
While this may be true on a small scale, the large amounts of sewage routinely dumped has damaged many coastal ecosystems, and rendered them life-threatening. Pathogenic viruses and bacteria occur in such waters, such as ''Escherichia coli
''Escherichia coli'' (),Wells, J. C. (2000) Longman Pronunciation Dictionary. Harlow ngland Pearson Education Ltd. also known as ''E. coli'' (), is a Gram-negative, facultative anaerobic, rod-shaped, coliform bacterium of the genus ''Escher ...
'', ''Vibrio cholerae
''Vibrio cholerae'' is a species of Gram-negative, facultative anaerobe and comma-shaped bacteria. The bacteria naturally live in brackish or saltwater where they attach themselves easily to the chitin-containing shells of crabs, shrimps, and oth ...
'' the cause of cholera
Cholera is an infection of the small intestine by some strains of the bacterium ''Vibrio cholerae''. Symptoms may range from none, to mild, to severe. The classic symptom is large amounts of watery diarrhea that lasts a few days. Vomiting and ...
, hepatitis A
Hepatitis A is an infectious disease of the liver caused by ''Hepatovirus A'' (HAV); it is a type of viral hepatitis. Many cases have few or no symptoms, especially in the young. The time between infection and symptoms, in those who develop them ...
, hepatitis E
Hepatitis E is inflammation of the liver caused by infection with the hepatitis E virus (HEV); it is a type of viral hepatitis. Hepatitis E has mainly a fecal-oral transmission route that is similar to hepatitis A, although the viruses are unrel ...
and polio
Poliomyelitis, commonly shortened to polio, is an infectious disease caused by the poliovirus. Approximately 70% of cases are asymptomatic; mild symptoms which can occur include sore throat and fever; in a proportion of cases more severe s ...
, along with protozoans causing giardiasis
Giardiasis is a parasitic disease caused by ''Giardia duodenalis'' (also known as ''G. lamblia'' and ''G. intestinalis''). Infected individuals who experience symptoms (about 10% have no symptoms) may have diarrhea, abdominal pain, and weight los ...
and cryptosporidiosis
Cryptosporidiosis, sometimes informally called crypto, is a parasitic disease caused by ''Cryptosporidium'', a genus of protozoan parasites in the phylum Apicomplexa. It affects the distal small intestine and can affect the respiratory tract in ...
. These pathogens are routinely present in the ballast water of large vessels, and are widely spread when the ballast is discharged.
Origin and history
The water in the sea was thought to come from the Earth's volcano
A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface.
On Earth, volcanoes are most often found where tectonic plates are ...
es, starting 4 billion years ago, released by degassing from molten rock. More recent work suggests much of the Earth's water may come from comet
A comet is an icy, small Solar System body that, when passing close to the Sun, warms and begins to release gases, a process that is called outgassing. This produces a visible atmosphere or coma, and sometimes also a tail. These phenomena ar ...
s.
Scientific theories
A scientific theory is an explanation of an aspect of the natural world and universe that has been repeatedly tested and corroborated in accordance with the scientific method, using accepted protocols of observation, measurement, and evaluation ...
behind the origins of sea salt started with Sir Edmond Halley
Edmond (or Edmund) Halley (; – ) was an English astronomer, mathematician and physicist. He was the second Astronomer Royal in Britain, succeeding John Flamsteed in 1720.
From an observatory he constructed on Saint Helena in 1676–77, H ...
in 1715, who proposed that salt and other minerals were carried into the sea by rivers after rainfall washed it out of the ground. Upon reaching the ocean, these salts concentrated as more salt arrived over time (see Hydrologic cycle
The water cycle, also known as the hydrologic cycle or the hydrological cycle, is a biogeochemical cycle that describes the continuous movement of water on, above and below the surface of the Earth. The mass of water on Earth remains fairly const ...
). Halley noted that most lakes that don't have ocean outlets (such as the Dead Sea
The Dead Sea ( he, יַם הַמֶּלַח, ''Yam hamMelaḥ''; ar, اَلْبَحْرُ الْمَيْتُ, ''Āl-Baḥrū l-Maytū''), also known by other names, is a salt lake bordered by Jordan to the east and Israel and the West Bank ...
and the Caspian Sea
The Caspian Sea is the world's largest inland body of water, often described as the world's largest lake or a full-fledged sea. An endorheic basin, it lies between Europe and Asia; east of the Caucasus, west of the broad steppe of Central Asia ...
, see endorheic basin
An endorheic basin (; also spelled endoreic basin or endorreic basin) is a drainage basin that normally retains water and allows no outflow to other external bodies of water, such as rivers or oceans, but drainage converges instead into lakes ...
), have high salt content. Halley termed this process "continental weathering".
Halley's theory was partly correct. In addition, sodium leached out of the ocean floor when the ocean formed. The presence of salt's other dominant ion, chloride, results from outgassing
Outgassing (sometimes called offgassing, particularly when in reference to indoor air quality) is the release of a gas that was dissolved, trapped, frozen, or absorbed in some material. Outgassing can include sublimation and evaporation (which a ...
of chloride (as hydrochloric acid
Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid
Acid strength is the tendency of an acid, symbol ...
) with other gases from Earth's interior via volcano
A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface.
On Earth, volcanoes are most often found where tectonic plates are ...
s and hydrothermal vent
A hydrothermal vent is a fissure on the seabed from which geothermally heated water discharges. They are commonly found near volcanically active places, areas where tectonic plates are moving apart at mid-ocean ridges, ocean basins, and hotspot ...
s. The sodium and chloride ions subsequently became the most abundant constituents of sea salt.
Ocean salinity has been stable for billions of years, most likely as a consequence of a chemical/tectonic
Tectonics (; ) are the processes that control the structure and properties of the Earth's crust and its evolution through time. These include the processes of mountain building, the growth and behavior of the strong, old cores of continents k ...
system which removes as much salt as is deposited; for instance, sodium and chloride sinks include evaporite
An evaporite () is a water-soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocea ...
deposits, pore-water burial, and reactions with seafloor basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
s.[
]
Human impacts
Climate change
In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
, rising levels of carbon dioxide in Earth's atmosphere
Carbon dioxide in Earth's atmosphere is a trace gas that plays an integral part in the greenhouse effect, carbon cycle, photosynthesis and oceanic carbon cycle. It is one of several greenhouse gases in Earth's atmosphere that are contributing t ...
, excess nutrients, and pollution in many forms are altering global oceanic geochemistry
Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...
. Rates of change for some aspects greatly exceed those in the historical and recent geological record. Major trends include an increasing acidity
In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a sequ ...
, reduced subsurface oxygen in both near-shore and pelagic waters, rising coastal nitrogen levels, and widespread increases in mercury
Mercury commonly refers to:
* Mercury (planet), the nearest planet to the Sun
* Mercury (element), a metallic chemical element with the symbol Hg
* Mercury (mythology), a Roman god
Mercury or The Mercury may also refer to:
Companies
* Merc ...
and persistent organic pollutants. Most of these perturbations are tied either directly or indirectly to human fossil fuel combustion, fertilizer, and industrial activity. Concentrations are projected to grow in coming decades, with negative impacts on ocean biota and other marine resources.
One of the most striking features of this is ocean acidification
Ocean acidification is the reduction in the pH value of the Earth’s ocean. Between 1751 and 2021, the average pH value of the ocean surface has decreased from approximately 8.25 to 8.14. The root cause of ocean acidification is carbon dioxid ...
, resulting from increased CO2 uptake of the oceans related to higher atmospheric concentration of CO2 and higher temperatures, because it severely affects coral reef
A coral reef is an underwater ecosystem characterized by reef-building corals. Reefs are formed of colonies of coral polyps held together by calcium carbonate. Most coral reefs are built from stony corals, whose polyps cluster in groups.
Co ...
s, mollusk
Mollusca is the second-largest phylum of invertebrate animals after the Arthropoda, the members of which are known as molluscs or mollusks (). Around 85,000 extant species of molluscs are recognized. The number of fossil species is e ...
s, echinoderm
An echinoderm () is any member of the phylum Echinodermata (). The adults are recognisable by their (usually five-point) radial symmetry, and include starfish, brittle stars, sea urchins, sand dollars, and sea cucumbers, as well as the sea ...
s and crustacean
Crustaceans (Crustacea, ) form a large, diverse arthropod taxon which includes such animals as decapods, seed shrimp, branchiopods, fish lice, krill, remipedes, isopods, barnacles, copepods, amphipods and mantis shrimp. The crustacean group ...
s (see coral bleaching
Coral bleaching is the process when corals become white due to various stressors, such as changes in temperature, light, or nutrients. Bleaching occurs when coral polyps expel the zooxanthellae (dinoflagellates that are commonly referred to as alg ...
).
Human consumption
Accidentally consuming small quantities of clean seawater is not harmful, especially if the seawater is taken along with a larger quantity of fresh water. However, drinking seawater to maintain hydration is counterproductive; more water must be excreted to eliminate the salt (via urine
Urine is a liquid by-product of metabolism in humans and in many other animals. Urine flows from the kidneys through the ureters to the urinary bladder. Urination results in urine being excretion, excreted from the body through the urethra.
Cel ...
) than the amount of water obtained from the seawater itself. In normal circumstances, it would be considered ill-advised to consume large amounts of unfiltered seawater.
The renal system
The urinary system, also known as the urinary tract or renal system, consists of the kidneys, ureters, bladder, and the urethra. The purpose of the urinary system is to eliminate waste from the body, regulate blood volume and blood pressure, con ...
actively regulates the levels of sodium and chloride in the blood within a very narrow range around 9 g/L (0.9% by mass).
In most open waters concentrations vary somewhat around typical values of about 3.5%, far higher than the body can tolerate and most beyond what the kidney can process. A point frequently overlooked in claims that the kidney can excrete NaCl in Baltic
Baltic may refer to:
Peoples and languages
* Baltic languages, a subfamily of Indo-European languages, including Lithuanian, Latvian and extinct Old Prussian
*Balts (or Baltic peoples), ethnic groups speaking the Baltic languages and/or originati ...
concentrations of 2% (in arguments to the contrary) is that the gut cannot absorb water at such concentrations, so that there is no benefit in drinking such water. The salinity of Baltic surface water, however, is never 2%. It is 0,9% or less, and thus never higher than that of bodily fluids. Drinking seawater temporarily increases blood's NaCl concentration. This signals the kidney
The kidneys are two reddish-brown bean-shaped organs found in vertebrates. They are located on the left and right in the retroperitoneal space, and in adult humans are about in length. They receive blood from the paired renal arteries; blood ...
to excrete sodium, but seawater's sodium concentration is above the kidney's maximum concentrating ability. Eventually the blood's sodium concentration rises to toxic levels, removing water from cells and interfering with nerve
A nerve is an enclosed, cable-like bundle of nerve fibers (called axons) in the peripheral nervous system.
A nerve transmits electrical impulses. It is the basic unit of the peripheral nervous system. A nerve provides a common pathway for the e ...
conduction, ultimately producing fatal seizure
An epileptic seizure, informally known as a seizure, is a period of symptoms due to abnormally excessive or synchronous neuronal activity in the brain. Outward effects vary from uncontrolled shaking movements involving much of the body with los ...
and cardiac arrhythmia
Arrhythmias, also known as cardiac arrhythmias, heart arrhythmias, or dysrhythmias, are irregularities in the heartbeat, including when it is too fast or too slow. A resting heart rate that is too fast – above 100 beats per minute in adults ...
.
Survival manuals consistently advise against drinking seawater. A summary of 163 life raft
A lifeboat or liferaft is a small, rigid or inflatable boat carried for emergency evacuation in the event of a disaster aboard a ship. Lifeboat drills are required by law on larger commercial ships. Rafts (raft, liferafts) are also used. In t ...
voyages estimated the risk of death at 39% for those who drank seawater, compared to 3% for those who did not. The effect of seawater intake on rats confirmed the negative effects of drinking seawater when dehydrated.
The temptation to drink seawater was greatest for sailors who had expended their supply of fresh water and were unable to capture enough rainwater for drinking. This frustration was described famously by a line from Samuel Taylor Coleridge
Samuel Taylor Coleridge (; 21 October 177225 July 1834) was an English poet, literary critic, philosopher, and theologian who, with his friend William Wordsworth, was a founder of the Romantic Movement in England and a member of the Lake Poe ...
's ''The Rime of the Ancient Mariner
''The Rime of the Ancient Mariner'' (originally ''The Rime of the Ancyent Marinere'') is the longest major poem by the English poet Samuel Taylor Coleridge, written in 1797–1798 and published in 1798 in the first edition of ''Lyrical Ballad ...
'':
Although humans cannot survive on seawater, some people claim that up to two cups a day, mixed with fresh water in a 2:3 ratio, produces no ill effect. The French physician Alain Bombard
Alain Bombard (; Paris, 27 October 1924 – Paris, 19 July 2005) was a French biologist, physician and politician famous for sailing in a small boat across the Atlantic Ocean without provision. He theorized that a human being could very well su ...
survived an ocean crossing in a small Zodiak rubber boat using mainly raw fish meat, which contains about 40% water (like most living tissues), as well as small amounts of seawater and other provisions harvested from the ocean. His findings were challenged, but an alternative explanation was not given. In his 1948 book ''The Kon-Tiki Expedition
''The Kon-Tiki Expedition: By Raft Across the South Seas'' ( no, Kon-Tiki ekspedisjonen) is a 1948 book by the Norwegian writer Thor Heyerdahl. It recounts Heyerdahl's experiences with the ''Kon-Tiki'' expedition, where he travelled across the P ...
'', Thor Heyerdahl
Thor Heyerdahl KStJ (; 6 October 1914 – 18 April 2002) was a Norwegian adventurer and ethnographer with a background in zoology, botany and geography.
Heyerdahl is notable for his ''Kon-Tiki'' expedition in 1947, in which he sailed 8,000&nb ...
reported drinking seawater mixed with fresh in a 2:3 ratio during the 1947 expedition. A few years later, another adventurer, William Willis, claimed to have drunk two cups of seawater and one cup of fresh per day for 70 days without ill effect when he lost part of his water supply.
During the 18th century, Richard Russell advocated the medical use of this practice in the UK, and René Quinton
René Joseph Quinton (1866–1925) was a French biologist, aviation pioneer and decorated World War I soldier.
In his biology career, he developed a treatment based on seawater injections that he called ''sérum de Quinton'', which has been aban ...
expanded the advocation of this practice to other countries, notably France, in the 20th century. Currently, it is widely practiced in Nicaragua and other countries, supposedly taking advantage of the latest medical discoveries.
Most oceangoing vessels desalinate potable
Drinking water is water that is used in drink or food preparation; potable water is water that is safe to be used as drinking water. The amount of drinking water required to maintain good health varies, and depends on physical activity level, a ...
water from seawater using processes such as vacuum distillation
Vacuum distillation is distillation performed under reduced pressure, which allows the purification of compounds not readily distilled at ambient pressures or simply to save time or energy. This technique separates compounds based on differences i ...
or multi-stage flash distillation
Multi-stage flash distillation (MSF) is a water desalination process that distills sea water by flashing a portion of the water into steam in multiple stages of what are essentially countercurrent heat exchangers. Current MSF facilities may hav ...
in an evaporator
An evaporator is a device used to turn the liquid form of a chemical substance, such as water, into a vapor.
Uses
Air conditioning and refrigeration
Some air conditioners and refrigerators use a compressed liquid with a low boiling point, ...
, or, more recently, reverse osmosis
Reverse osmosis (RO) is a water purification process that uses a partially permeable membrane to separate ions, unwanted molecules and larger particles from drinking water. In reverse osmosis, an applied pressure is used to overcome osmotic pre ...
. These energy-intensive processes were not usually available during the Age of Sail
The Age of Sail is a period that lasted at the latest from the mid-16th (or mid- 15th) to the mid- 19th centuries, in which the dominance of sailing ships in global trade and warfare culminated, particularly marked by the introduction of naval ...
. Larger sailing warships with large crews, such as Nelson
Nelson may refer to:
Arts and entertainment
* ''Nelson'' (1918 film), a historical film directed by Maurice Elvey
* ''Nelson'' (1926 film), a historical film directed by Walter Summers
* ''Nelson'' (opera), an opera by Lennox Berkeley to a lib ...
's , were fitted with distilling apparatus in their galleys
A galley is a type of ship that is propelled mainly by oars. The galley is characterized by its long, slender hull, shallow draft, and low freeboard (clearance between sea and gunwale). Virtually all types of galleys had sails that could be used ...
.
Animals such as fish, whales, sea turtle
Sea turtles (superfamily Chelonioidea), sometimes called marine turtles, are reptiles of the order Testudines and of the suborder Cryptodira. The seven existing species of sea turtles are the flatback, green, hawksbill, leatherback, loggerhead, ...
s, and seabird
Seabirds (also known as marine birds) are birds that are adapted to life within the marine environment. While seabirds vary greatly in lifestyle, behaviour and physiology, they often exhibit striking convergent evolution, as the same enviro ...
s, such as penguins and albatross
Albatrosses, of the biological family Diomedeidae, are large seabirds related to the procellariids, storm petrels, and diving petrels in the order Procellariiformes (the tubenoses). They range widely in the Southern Ocean and the North Pacifi ...
es, have adapted to living in a high-saline habitat. For example, sea turtles and saltwater crocodiles remove excess salt from their bodies through their tear ducts
The nasolacrimal duct (also called the tear duct) carries tears from the lacrimal sac of the Human eye, eye into the nasal cavity. The duct begins in the eye socket between the maxillary and lacrimal bones, from where it passes downwards and backw ...
.
Mineral extraction
Minerals have been extracted from seawater since ancient times. Currently the four most concentrated metals – Na, Mg, Ca and K – are commercially extracted from seawater. During 2015 in the US 63% of magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
production came from seawater and brines. Bromine
Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table (halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a simila ...
is also produced from seawater in China
China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's most populous country, with a population exceeding 1.4 billion, slightly ahead of India. China spans the equivalent of five time zones and ...
and Japan. Lithium
Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid el ...
extraction from seawater was tried in the 1970s, but the tests were soon abandoned. The idea of extracting uranium
Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
from seawater has been considered at least from the 1960s, but only a few grams of uranium were extracted in Japan
Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the north ...
in the late 1990s. The main issue is not one of technological feasibility but that current prices on the uranium market
The uranium market, like all commodity markets, has a history of volatility, moving with the standard forces of supply and demand as well as geopolitical pressures. It has also evolved particularities of its own in response to the unique nature and ...
for uranium from other sources are about three to five times lower than the lowest price achieved by seawater extraction. Similar issues hamper the use of reprocessed uranium
Reprocessed uranium (RepU) is the uranium recovered from nuclear reprocessing, as done commercially in France, the UK and Japan and by nuclear weapons states' military plutonium production programs. This uranium makes up the bulk of the material s ...
and are often brought forth against nuclear reprocessing
Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the ...
and the manufacturing of MOX fuel
Mixed oxide fuel, commonly referred to as MOX fuel, is nuclear fuel that contains more than one oxide of fissile material, usually consisting of plutonium blended with natural uranium, reprocessed uranium, or depleted uranium. MOX fuel is an alt ...
as economically unviable.
Standard
ASTM International
ASTM International, formerly known as American Society for Testing and Materials, is an international standards organization that develops and publishes voluntary consensus technical standards for a wide range of materials, products, systems, an ...
has an international standard for artificial seawater
Artificial seawater (abbreviated ASW) is a mixture of dissolved mineral salts (and sometimes vitamins) that simulates seawater. Artificial seawater is primarily used in marine biology and in marine and reef aquaria, and allows the easy preparation ...
: ASTM D1141-98 (Original Standard ASTM D1141-52). It is used in many research testing labs as a reproducible solution for seawater such as tests on corrosion, oil contamination, and detergency evaluation.
See also
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*
*
*
*
*
* global ocean salinity
References
External links
Technical Papers in Marine Science 44, Algorithms for computation of fundamental properties of seawater, ioc-unesco.org, UNESCO 1983
Tables
Tables and software for thermophysical properties of seawater
MIT
*
{{Authority control
Aquatic ecology
Chemical oceanography
Liquid water
Physical oceanography
Oceanographical terminology