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This article concerns the
rotation Rotation or rotational/rotary motion is the circular movement of an object around a central line, known as an ''axis of rotation''. A plane figure can rotate in either a clockwise or counterclockwise sense around a perpendicular axis intersect ...
operator, as it appears in
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
.


Quantum mechanical rotations

With every physical rotation R, we postulate a quantum mechanical rotation operator \widehat(R) : H\to H that is the rule that assigns to each vector in the space H the vector , \alpha \rangle_R = \widehat(R) , \alpha \rangle that is also in H. We will show that, in terms of the generators of rotation, \widehat (\mathbf,\phi) = \exp \left( -i \phi \frac \right), where \mathbf is the rotation axis, \widehat is
angular momentum Angular momentum (sometimes called moment of momentum or rotational momentum) is the rotational analog of Momentum, linear momentum. It is an important physical quantity because it is a Conservation law, conserved quantity – the total ang ...
operator, and \hbar is the
reduced Planck constant The Planck constant, or Planck's constant, denoted by h, is a fundamental physical constant of foundational importance in quantum mechanics: a photon's energy is equal to its frequency multiplied by the Planck constant, and the wavelength of a ...
.


The translation operator

The
rotation Rotation or rotational/rotary motion is the circular movement of an object around a central line, known as an ''axis of rotation''. A plane figure can rotate in either a clockwise or counterclockwise sense around a perpendicular axis intersect ...
operator \operatorname(z, \theta), with the first argument z indicating the rotation
axis An axis (: axes) may refer to: Mathematics *A specific line (often a directed line) that plays an important role in some contexts. In particular: ** Coordinate axis of a coordinate system *** ''x''-axis, ''y''-axis, ''z''-axis, common names ...
and the second \theta the rotation angle, can operate through the translation operator \operatorname(a) for infinitesimal rotations as explained below. This is why, it is first shown how the translation operator is acting on a particle at position x (the particle is then in the
state State most commonly refers to: * State (polity), a centralized political organization that regulates law and society within a territory **Sovereign state, a sovereign polity in international law, commonly referred to as a country **Nation state, a ...
, x\rangle according to
Quantum Mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
). Translation of the particle at position x to position x + a: \operatorname(a), x\rangle = , x + a\rangle Because a translation of 0 does not change the position of the particle, we have (with 1 meaning the
identity operator Graph of the identity function on the real numbers In mathematics, an identity function, also called an identity relation, identity map or identity transformation, is a function that always returns the value that was used as its argument, unc ...
, which does nothing): \operatorname(0) = 1 \operatorname(a) \operatorname(da), x\rangle = \operatorname(a), x + da\rangle = , x + a + da\rangle = \operatorname(a + da), x\rangle \Rightarrow \operatorname(a) \operatorname(da) = \operatorname(a + da)
Taylor Taylor, Taylors or Taylor's may refer to: People * Taylor (surname) ** List of people with surname Taylor * Taylor (given name), including Tayla and Taylah * Taylor sept, a branch of Scottish clan Cameron * Justice Taylor (disambiguation) ...
development gives: \operatorname(da) = \operatorname(0) + \frac da + \cdots = 1 - \frac p_x da with p_x = i \hbar \frac From that follows: \operatorname(a + da) = \operatorname(a) \operatorname(da) = \operatorname(a)\left(1 - \frac p_x da\right) \Rightarrow \frac = \frac = - \frac p_x \operatorname(a) This is a differential equation with the solution \operatorname(a) = \exp\left(- \frac p_x a\right). Additionally, suppose a
Hamiltonian Hamiltonian may refer to: * Hamiltonian mechanics, a function that represents the total energy of a system * Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system ** Dyall Hamiltonian, a modified Hamiltonian ...
H is independent of the x position. Because the translation operator can be written in terms of p_x, and _x,H= 0, we know that , \operatorname(a)0. This result means that linear
momentum In Newtonian mechanics, momentum (: momenta or momentums; more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. ...
for the system is conserved.


In relation to the orbital angular momentum

Classically we have for the
angular momentum Angular momentum (sometimes called moment of momentum or rotational momentum) is the rotational analog of Momentum, linear momentum. It is an important physical quantity because it is a Conservation law, conserved quantity – the total ang ...
\mathbf L = \mathbf r \times \mathbf p. This is the same in
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
considering \mathbf r and \mathbf p as operators. Classically, an infinitesimal rotation dt of the vector \mathbf r = (x,y,z) about the z-axis to \mathbf r' = (x',y',z) leaving z unchanged can be expressed by the following infinitesimal translations (using
Taylor approximation In calculus, Taylor's theorem gives an approximation of a k-times differentiable function around a given point by a polynomial of degree k, called the k-th-order Taylor polynomial. For a smooth function, the Taylor polynomial is the truncation a ...
): \begin x' &= r \cos(t + dt) = x - y \, dt + \cdots \\ y' &= r \sin(t + dt) = y + x \, dt + \cdots \end From that follows for states: \operatorname(z, dt), r\rangle = \operatorname(z, dt), x, y, z\rangle = , x - y \, dt, y + x \, dt, z\rangle = \operatorname_x(-y \, dt) \operatorname_y(x \, dt), x, y, z\rangle = \operatorname_x(-y \, dt) \operatorname_y(x \, dt) , r\rangle And consequently: \operatorname(z, dt) = \operatorname_x (-y \, dt) \operatorname_y(x \, dt) Using T_k(a) = \exp\left(- \frac p_k a\right) from above with k = x,y and Taylor expansion we get: \operatorname(z,dt)=\exp\left \frac \left(x p_y - y p_x\right) dt\right= \exp\left(-\frac L_z dt\right) = 1-\fracL_z dt + \cdots with L_z = x p_y - y p_x the z-component of the angular momentum according to the classical
cross product In mathematics, the cross product or vector product (occasionally directed area product, to emphasize its geometric significance) is a binary operation on two vectors in a three-dimensional oriented Euclidean vector space (named here E), and ...
. To get a rotation for the angle t, we construct the following differential equation using the condition \operatorname(z, 0) = 1 : \begin &\operatorname(z, t + dt) = \operatorname(z, t) \operatorname(z, dt) \\ .1ex\Rightarrow & \frac = \frac = \operatorname(z, t) \frac = - \frac L_z \operatorname(z, t) \\ .1ex\Rightarrow & \operatorname(z, t) = \exp\left(- \frac\, t \, L_z\right) \end Similar to the translation operator, if we are given a Hamiltonian H which rotationally symmetric about the z-axis, _z,H0 implies operatorname(z,t),H0. This result means that angular momentum is conserved. For the spin angular momentum about for example the y-axis we just replace L_z with S_y = \frac \sigma_y (where \sigma_y is the Pauli Y matrix) and we get the spin rotation operator \operatorname(y, t) = \exp\left(- i \frac \sigma_y\right).


Effect on the spin operator and quantum states

Operators can be represented by
matrices Matrix (: matrices or matrixes) or MATRIX may refer to: Science and mathematics * Matrix (mathematics), a rectangular array of numbers, symbols or expressions * Matrix (logic), part of a formula in prenex normal form * Matrix (biology), the ...
. From
linear algebra Linear algebra is the branch of mathematics concerning linear equations such as :a_1x_1+\cdots +a_nx_n=b, linear maps such as :(x_1, \ldots, x_n) \mapsto a_1x_1+\cdots +a_nx_n, and their representations in vector spaces and through matrix (mathemat ...
one knows that a certain matrix A can be represented in another basis through the transformation A' = P A P^ where P is the basis transformation matrix. If the vectors b respectively c are the z-axis in one basis respectively another, they are perpendicular to the y-axis with a certain angle t between them. The spin operator S_b in the first basis can then be transformed into the spin operator S_c of the other basis through the following transformation: S_c = \operatorname(y, t) S_b \operatorname^(y, t) From standard quantum mechanics we have the known results S_b , b+\rangle = \frac , b+\rangle and S_c , c+\rangle = \frac , c+\rangle where , b+\rangle and , c+\rangle are the top spins in their corresponding bases. So we have: \frac , c+\rangle = S_c , c+\rangle = \operatorname(y, t) S_b \operatorname^(y, t) , c+\rangle \Rightarrow S_b \operatorname^(y, t) , c+\rangle = \frac \operatorname^(y, t) , c+\rangle Comparison with S_b , b+\rangle = \frac , b+\rangle yields , b+\rangle = D^(y, t) , c+\rangle. This means that if the state , c+\rangle is rotated about the y-axis by an angle t, it becomes the state , b+\rangle, a result that can be generalized to arbitrary axes.


See also

* Symmetry in quantum mechanics * Spherical basis * Optical phase space


References

*L.D. Landau and E.M. Lifshitz: ''Quantum Mechanics: Non-Relativistic Theory'', Pergamon Press, 1985 *P.A.M. Dirac: ''The Principles of Quantum Mechanics'', Oxford University Press, 1958 *R.P. Feynman, R.B. Leighton and M. Sands: ''The Feynman Lectures on Physics'', Addison-Wesley, 1965 {{DEFAULTSORT:Rotation Operator (Quantum Mechanics) Rotational symmetry Quantum operators Unitary operators