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Angular Momentum Operator
In quantum mechanics, the angular momentum operator is one of several related operators analogous to classical angular momentum. The angular momentum operator plays a central role in the theory of atomic and molecular physics and other quantum problems involving rotational symmetry. Such an operator is applied to a mathematical representation of the physical state of a system and yields an angular momentum value if the state has a definite value for it. In both classical and quantum mechanical systems, angular momentum (together with linear momentum and energy) is one of the three fundamental properties of motion.Introductory Quantum Mechanics, Richard L. Liboff, 2nd Edition, There are several angular momentum operators: total angular momentum (usually denoted J), orbital angular momentum (usually denoted L), and spin angular momentum (spin for short, usually denoted S). The term ''angular momentum operator'' can (confusingly) refer to either the total or the orbital angular momen ...
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Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limits to ...
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Photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they always move at the speed of light in vacuum, (or about ). The photon belongs to the class of bosons. As with other elementary particles, photons are best explained by quantum mechanics and exhibit wave–particle duality, their behavior featuring properties of both waves and particles. The modern photon concept originated during the first two decades of the 20th century with the work of Albert Einstein, who built upon the research of Max Planck. While trying to explain how matter and electromagnetic radiation could be in thermal equilibrium with one another, Planck proposed that the energy stored within a material object should be regarded as composed of an integer number of discrete, equal-sized parts. To explain the photoelectric effect, Eins ...
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Structure Constant
In mathematics, the structure constants or structure coefficients of an algebra over a field are used to explicitly specify the product of two basis vectors in the algebra as a linear combination. Given the structure constants, the resulting product is bilinear and can be uniquely extended to all vectors in the vector space, thus uniquely determining the product for the algebra. Structure constants are used whenever an explicit form for the algebra must be given. Thus, they are frequently used when discussing Lie algebras in physics, as the basis vectors indicate specific directions in physical space, or correspond to specific particles. Recall that Lie algebras are algebras over a field, with the bilinear product being given by the Lie bracket or commutator. Definition Given a set of basis vectors \ for the underlying vector space of the algebra, the structure constants or structure coefficients c_^ express the multiplication \cdot of pairs of vectors as a linear combinati ...
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Lie Algebra
In mathematics, a Lie algebra (pronounced ) is a vector space \mathfrak g together with an Binary operation, operation called the Lie bracket, an Alternating multilinear map, alternating bilinear map \mathfrak g \times \mathfrak g \rightarrow \mathfrak g, that satisfies the Jacobi identity. The Lie bracket of two vectors x and y is denoted [x,y]. The vector space \mathfrak g together with this operation is a non-associative algebra, meaning that the Lie bracket is not necessarily associative property, associative. Lie algebras are closely related to Lie groups, which are group (mathematics), groups that are also smooth manifolds: any Lie group gives rise to a Lie algebra, which is its tangent space at the identity. Conversely, to any finite-dimensional Lie algebra over real or complex numbers, there is a corresponding connected space, connected Lie group unique up to finite coverings (Lie's third theorem). This Lie group–Lie algebra correspondence, correspondence allows one ...
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Connection To Commutation Relations
Connection may refer to: Mathematics *Connection (algebraic framework) *Connection (mathematics), a way of specifying a derivative of a geometrical object along a vector field on a manifold *Connection (affine bundle) * Connection (composite bundle) *Connection (fibred manifold) *Connection (principal bundle), gives the derivative of a section of a principal bundle *Connection (vector bundle), differentiates a section of a vector bundle along a vector field *Cartan connection, achieved by identifying tangent spaces with the tangent space of a certain model Klein geometry *Ehresmann connection, gives a manner for differentiating sections of a general fibre bundle *Electrical connection, allows the flow of electrons *Galois connection, a type of correspondence between two partially ordered sets *Affine connection, a geometric object on a smooth manifold which connects nearby tangent spaces *Levi-Civita connection, used in differential geometry and general relativity; differentiates ...
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Poisson Bracket
In mathematics and classical mechanics, the Poisson bracket is an important binary operation in Hamiltonian mechanics, playing a central role in Hamilton's equations of motion, which govern the time evolution of a Hamiltonian dynamical system. The Poisson bracket also distinguishes a certain class of coordinate transformations, called ''canonical transformations'', which map canonical coordinate systems into canonical coordinate systems. A "canonical coordinate system" consists of canonical position and momentum variables (below symbolized by q_i and p_i, respectively) that satisfy canonical Poisson bracket relations. The set of possible canonical transformations is always very rich. For instance, it is often possible to choose the Hamiltonian itself H =H(q, p, t) as one of the new canonical momentum coordinates. In a more general sense, the Poisson bracket is used to define a Poisson algebra, of which the algebra of functions on a Poisson manifold is a special case. There are ot ...
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Kronecker Delta
In mathematics, the Kronecker delta (named after Leopold Kronecker) is a function of two variables, usually just non-negative integers. The function is 1 if the variables are equal, and 0 otherwise: \delta_ = \begin 0 &\text i \neq j, \\ 1 &\text i=j. \end or with use of Iverson brackets: \delta_ = =j, where the Kronecker delta is a piecewise function of variables and . For example, , whereas . The Kronecker delta appears naturally in many areas of mathematics, physics and engineering, as a means of compactly expressing its definition above. In linear algebra, the identity matrix has entries equal to the Kronecker delta: I_ = \delta_ where and take the values , and the inner product of vectors can be written as \mathbf\cdot\mathbf = \sum_^n a_\delta_b_ = \sum_^n a_ b_. Here the Euclidean vectors are defined as -tuples: \mathbf = (a_1, a_2, \dots, a_n) and \mathbf= (b_1, b_2, ..., b_n) and the last step is obtained by using the values of the Kronecker delta ...
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Canonical Commutation Relation
In quantum mechanics, the canonical commutation relation is the fundamental relation between canonical conjugate quantities (quantities which are related by definition such that one is the Fourier transform of another). For example, hat x,\hat p_x= i\hbar \mathbb between the position operator and momentum operator in the direction of a point particle in one dimension, where is the commutator of and , is the imaginary unit, and is the reduced Planck's constant , and \mathbb is the unit operator. In general, position and momentum are vectors of operators and their commutation relation between different components of position and momentum can be expressed as hat r_i,\hat p_j= i\hbar \delta_ \mathbb. where \delta_ is the Kronecker delta. This relation is attributed to Werner Heisenberg, Max Born and Pascual Jordan (1925), who called it a "quantum condition" serving as a postulate of the theory; it was noted by E. Kennard (1927) to imply the Heisenberg uncertainty principl ...
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Levi-Civita Symbol
In mathematics, particularly in linear algebra, tensor analysis, and differential geometry, the Levi-Civita symbol or Levi-Civita epsilon represents a collection of numbers; defined from the sign of a permutation of the natural numbers , for some positive integer . It is named after the Italian mathematician and physicist Tullio Levi-Civita. Other names include the permutation symbol, antisymmetric symbol, or alternating symbol, which refer to its antisymmetric property and definition in terms of permutations. The standard letters to denote the Levi-Civita symbol are the Greek lower case epsilon or , or less commonly the Latin lower case . Index notation allows one to display permutations in a way compatible with tensor analysis: \varepsilon_ where ''each'' index takes values . There are indexed values of , which can be arranged into an -dimensional array. The key defining property of the symbol is ''total antisymmetry'' in the indices. When any two indices are interchanged, e ...
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Commutator (ring Theory)
In mathematics, the commutator gives an indication of the extent to which a certain binary operation fails to be commutative. There are different definitions used in group theory and ring theory. Group theory The commutator of two elements, and , of a group , is the element : . This element is equal to the group's identity if and only if and commute (from the definition , being equal to the identity if and only if ). The set of all commutators of a group is not in general closed under the group operation, but the subgroup of ''G'' generated by all commutators is closed and is called the ''derived group'' or the ''commutator subgroup'' of ''G''. Commutators are used to define nilpotent and solvable groups and the largest abelian quotient group. The definition of the commutator above is used throughout this article, but many other group theorists define the commutator as :. Identities (group theory) Commutator identities are an important tool in group theory. The expr ...
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Commutation Relation
In mathematics, the commutator gives an indication of the extent to which a certain binary operation fails to be commutative. There are different definitions used in group theory and ring theory. Group theory The commutator of two elements, and , of a group , is the element : . This element is equal to the group's identity if and only if and commute (from the definition , being equal to the identity if and only if ). The set of all commutators of a group is not in general closed under the group operation, but the subgroup of ''G'' generated by all commutators is closed and is called the ''derived group'' or the ''commutator subgroup'' of ''G''. Commutators are used to define nilpotent and solvable groups and the largest abelian quotient group. The definition of the commutator above is used throughout this article, but many other group theorists define the commutator as :. Identities (group theory) Commutator identities are an important tool in group theory. The expr ...
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Spin–orbit Interaction
In quantum physics, the spin–orbit interaction (also called spin–orbit effect or spin–orbit coupling) is a relativistic interaction of a particle's spin with its motion inside a potential. A key example of this phenomenon is the spin–orbit interaction leading to shifts in an electron's atomic energy levels, due to electromagnetic interaction between the electron's magnetic dipole, its orbital motion, and the electrostatic field of the positively charged nucleus. This phenomenon is detectable as a splitting of spectral lines, which can be thought of as a Zeeman effect product of two relativistic effects: the apparent magnetic field seen from the electron perspective and the magnetic moment of the electron associated with its intrinsic spin. A similar effect, due to the relationship between angular momentum and the strong nuclear force, occurs for protons and neutrons moving inside the nucleus, leading to a shift in their energy levels in the nucleus shell model. In the fi ...
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