Quantum Ergodicity
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quantum chaos Quantum chaos is a branch of physics which studies how chaos theory, chaotic classical dynamical systems can be described in terms of quantum theory. The primary question that quantum chaos seeks to answer is: "What is the relationship betwee ...
, a branch of
mathematical physics Mathematical physics refers to the development of mathematics, mathematical methods for application to problems in physics. The ''Journal of Mathematical Physics'' defines the field as "the application of mathematics to problems in physics and t ...
, quantum ergodicity is a property of the quantization of classical mechanical systems that are
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in the sense of exponential sensitivity to initial conditions. Quantum ergodicity states, roughly, that in the high-energy limit, the probability distributions associated to
energy eigenstates In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of heat ...
of a quantized
ergodic In mathematics, ergodicity expresses the idea that a point of a moving system, either a dynamical system or a stochastic process, will eventually visit all parts of the space that the system moves in, in a uniform and random sense. This implies tha ...
Hamiltonian Hamiltonian may refer to: * Hamiltonian mechanics, a function that represents the total energy of a system * Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system ** Dyall Hamiltonian, a modified Hamiltonian ...
tend to a uniform distribution in the classical
phase space In dynamical system theory, a phase space is a space in which all possible states of a system are represented, with each possible state corresponding to one unique point in the phase space. For mechanical systems, the phase space usually ...
. This is consistent with the intuition that the flows of ergodic systems are equidistributed in phase space. By contrast, classical
completely integrable system In mathematics, integrability is a property of certain dynamical systems. While there are several distinct formal definitions, informally speaking, an integrable system is a dynamical system with sufficiently many conserved quantities, or first ...
s generally have periodic orbits in phase space, and this is exhibited in a variety of ways in the high-energy limit of the eigenstates: typically, some form of concentration occurs in the semiclassical limit \hbar \rightarrow 0. The model case of a Hamiltonian is the geodesic Hamiltonian on the cotangent bundle of a
compact Compact as used in politics may refer broadly to a pact or treaty; in more specific cases it may refer to: * Interstate compact * Blood compact, an ancient ritual of the Philippines * Compact government, a type of colonial rule utilized in British ...
Riemannian manifold In differential geometry, a Riemannian manifold or Riemannian space , so called after the German mathematician Bernhard Riemann, is a real manifold, real, smooth manifold ''M'' equipped with a positive-definite Inner product space, inner product ...
. The quantization of the geodesic flow is given by the
fundamental solution In mathematics, a fundamental solution for a linear partial differential operator is a formulation in the language of distribution theory of the older idea of a Green's function (although unlike Green's functions, fundamental solutions do not ad ...
of the
Schrödinger equation The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the ...
:U_t=\exp(it\sqrt) where \sqrt is the square root of the
Laplace–Beltrami operator In differential geometry, the Laplace–Beltrami operator is a generalization of the Laplace operator to functions defined on submanifolds in Euclidean space and, even more generally, on Riemannian and pseudo-Riemannian manifolds. It is named af ...
. The quantum ergodicity theorem of Shnirelman 1974, Zelditch, and
Yves Colin de Verdière Yves Colin de Verdière is a French mathematician. Life He studied at the École Normale Supérieure in Paris in the late 1960s, obtained his Ph.D. in 1973, and then spent the bulk of his working life as faculty at Joseph Fourier University in ...
states that a compact Riemannian manifold whose
unit tangent bundle In Riemannian geometry, the unit tangent bundle of a Riemannian manifold (''M'', ''g''), denoted by T1''M'', UT(''M'') or simply UT''M'', is the unit sphere bundle for the tangent bundle T(''M''). It is a fiber bundle over ''M'' whose fiber at ea ...
is ergodic under the geodesic flow is also ergodic in the sense that the probability density associated to the ''n''th eigenfunction of the Laplacian tends weakly to the uniform distribution on the unit cotangent bundle as ''n'' → ∞ in a subset of the natural numbers of
natural density In number theory, natural density (also referred to as asymptotic density or arithmetic density) is one method to measure how "large" a subset of the set of natural numbers is. It relies chiefly on the probability of encountering members of the de ...
equal to one. Quantum ergodicity can be formulated as a non-commutative analogue of the classical ergodicity ( T. Sunada). Since a classically chaotic system is also ergodic, almost all of its trajectories eventually explore uniformly the entire accessible phase space. Thus, when translating the concept of ergodicity to the quantum realm, it is natural to assume that the eigenstates of the quantum chaotic system would fill the quantum phase space evenly (up to random fluctuations) in the semiclassical limit \hbar \rightarrow 0. The quantum ergodicity theorems of Shnirelman, Zelditch, and
Yves Colin de Verdière Yves Colin de Verdière is a French mathematician. Life He studied at the École Normale Supérieure in Paris in the late 1960s, obtained his Ph.D. in 1973, and then spent the bulk of his working life as faculty at Joseph Fourier University in ...
proves that the expectation value of an operator converges in the semiclassical limit to the corresponding microcanonical classical average. However, the quantum ergodicity theorem leaves open the possibility of eigenfunctions become sparse with serious holes as \hbar \rightarrow 0, leaving large but not macroscopic gaps on the energy manifolds in the phase space. In particular, the theorem allows the existence of a subset of macroscopically nonerdodic states which on the other hand must approach zero measure, i.e., the contribution of this set goes towards zero percent of all eigenstates when \hbar \rightarrow 0. For example, the theorem do not exclude quantum scarring, as the phase space volume of the scars also gradually vanishes in this limit. A quantum eigenstate is scarred by periodic orbit if its probability density is on the classical invariant manifolds near and all along that periodic orbit is systematically enhanced above the classical, statistically expected density along that orbit. In a simplified manner, a quantum scar refers to an eigenstate of whose probability density is enhanced in the neighborhood of a classical periodic orbit when the corresponding classical system is chaotic. In conventional scarring, the responsive periodic orbit is unstable. The instability is a decisive point that separates quantum scars from a more trivial finding that the probability density is enhanced near stable periodic orbits due to the Bohr's correspondence principle. The latter can be viewed as a purely classical phenomenon, whereas in the former quantum interference is important. On the other hand, in the perturbation-induced quantum scarring, some of the high-energy eigenstates of a locally perturbed quantum dot contain scars of short periodic orbits of the corresponding unperturbed system. Even though similar in appearance to ordinary quantum scars, these scars have a fundamentally different origin., In this type of scarring, there are no periodic orbits in the perturbed classical counterpart or they are too unstable to cause a scar in a conventional sense. Conventional and perturbation-induced scars are both a striking visual example of classical-quantum correspondence and of a quantum suppression of chaos (see the figure). In particular, scars are a significant correction to the assumption that the corresponding eigenstates of a classically chaotic Hamiltonian are only featureless and random. In some sense, scars can be considered as an eigenstate counterpart to the quantum ergodicity theorem of how short periodic orbits provide corrections to the universal random matrix theory eigenvalue statistics.


See also

*
Eigenstate thermalization hypothesis The eigenstate thermalization hypothesis (or ETH) is a set of ideas which purports to explain when and why an isolated quantum mechanical system can be accurately described using equilibrium statistical mechanics. In particular, it is devoted to ...
* Ergodic hypothesis *
Quantum chaos Quantum chaos is a branch of physics which studies how chaos theory, chaotic classical dynamical systems can be described in terms of quantum theory. The primary question that quantum chaos seeks to answer is: "What is the relationship betwee ...
*
Scar (physics) Quantum scarring refers to a phenomenon where the Quantum state, eigenstates of a classically chaotic quantum system have enhanced Density matrix, probability density around the paths of unstable classical periodic orbits. The instability of the p ...


External links


Shnirelman theorem, Scholarpedia article


References

* * * {{Citation , last=Sunada, first= T, chapter=Quantum ergodicity , title=Trend in Mathematics , publisher=Birkhauser Verlag, Basel, year=1997 , pages=175–196 Modular forms Chaos theory Ergodic theory Quantum mechanics Quantum chaos theory