Polaritonics is an intermediate regime between
photonics
Photonics is a branch of optics that involves the application of generation, detection, and manipulation of light in form of photons through emission, transmission, modulation, signal processing, switching, amplification, and sensing. Though ...
and sub-microwave
electronics
The field of electronics is a branch of physics and electrical engineering that deals with the emission, behaviour and effects of electrons using electronic devices. Electronics uses active devices to control electron flow by amplification ...
(see Fig. 1). In this regime, signals are carried by an admixture of
electromagnetic
In physics, electromagnetism is an interaction that occurs between particles with electric charge. It is the second-strongest of the four fundamental interactions, after the strong force, and it is the dominant force in the interactions of a ...
and lattice vibrational
wave
In physics, mathematics, and related fields, a wave is a propagating dynamic disturbance (change from equilibrium) of one or more quantities. Waves can be periodic, in which case those quantities oscillate repeatedly about an equilibrium (res ...
s known as phonon-
polaritons
In physics, polaritons are quasiparticles resulting from strong coupling of electromagnetic waves with an electric or magnetic dipole-carrying excitation. They are an expression of the common quantum phenomenon known as level repulsion, also ...
, rather than
current
Currents, Current or The Current may refer to:
Science and technology
* Current (fluid), the flow of a liquid or a gas
** Air current, a flow of air
** Ocean current, a current in the ocean
*** Rip current, a kind of water current
** Current (stre ...
s or
photons
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they alway ...
. Since phonon-polaritons propagate with
frequencies
Frequency is the number of occurrences of a repeating event per unit of time. It is also occasionally referred to as ''temporal frequency'' for clarity, and is distinct from ''angular frequency''. Frequency is measured in hertz (Hz) which is eq ...
in the range of hundreds of
gigahertz
The hertz (symbol: Hz) is the unit of frequency in the International System of Units (SI), equivalent to one event (or cycle) per second. The hertz is an SI derived unit whose expression in terms of SI base units is s−1, meaning that one h ...
to several
terahertz, polaritonics bridges the gap between electronics and photonics. A compelling motivation for polaritonics is the demand for high speed
signal processing
Signal processing is an electrical engineering subfield that focuses on analyzing, modifying and synthesizing ''signals'', such as audio signal processing, sound, image processing, images, and scientific measurements. Signal processing techniq ...
and linear and nonlinear terahertz
spectroscopy
Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter wa ...
. Polaritonics has distinct advantages over electronics, photonics, and traditional terahertz spectroscopy in that it offers the potential for a fully integrated platform that supports terahertz wave generation, guidance, manipulation, and readout in a single patterned material.
Polaritonics, like electronics and photonics, requires three elements: robust waveform generation, detection, and guidance and control. Without all three, polaritonics would be reduced to just phonon-polaritons, just as electronics and photonics would be reduced to just electromagnetic radiation. These three elements can be combined to enable device functionality similar to that in electronics and photonics.
Illustration
To illustrate the functionality of polaritonic devices, consider the hypothetical circuit in Fig. 2 (right). The optical excitation pulses that generate phonon-polaritons, in the top left and bottom right of the crystal, enter normal to the crystal face (into the page). The resulting phonon-polaritons will travel laterally away from the excitation regions. Entrance into the
waveguide
A waveguide is a structure that guides waves, such as electromagnetic waves or sound, with minimal loss of energy by restricting the transmission of energy to one direction. Without the physical constraint of a waveguide, wave intensities de ...
s is facilitated by reflective and focusing structures. Phonon-polaritons are guided through the circuit by terahertz waveguides carved into the crystal. Circuit functionality resides in the interferometer structure at the top and the coupled waveguide structure at the bottom of the circuit. The latter employs a
photonic bandgap structure with a defect (yellow) that could provide
bistability
In a dynamical system, bistability means the system has two stable equilibrium states. Something that is bistable can be resting in either of two states. An example of a mechanical device which is bistable is a light switch. The switch lever ...
for the coupled waveguide.
Waveform generation
Phonon-polaritons generated in
ferroelectric
Ferroelectricity is a characteristic of certain materials that have a spontaneous electric polarization that can be reversed by the application of an external electric field. All ferroelectrics are also piezoelectric and pyroelectric, with the add ...
crystals propagate nearly laterally to the excitation pulse due to the high
dielectric
In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the mate ...
constants of
ferroelectric
Ferroelectricity is a characteristic of certain materials that have a spontaneous electric polarization that can be reversed by the application of an external electric field. All ferroelectrics are also piezoelectric and pyroelectric, with the add ...
crystals, facilitating easy separation of phonon-polaritons from the excitation pulses that generated them. Phonon-polaritons are therefore available for direct observation, as well as coherent manipulation, as they move from the excitation region into other parts of the crystal. Lateral propagation is paramount to a polaritonic platform in which generation and propagation take place in a single crystal. A full treatment of the
Cherenkov-radiation-like terahertz wave response reveals that in general, there is also a forward propagation component that must be considered in many cases.
Signal detection
Direct observation of phonon-polariton propagation was made possible by real-space imaging, in which the spatial and temporal profiles of phonon-polaritons are imaged onto a
CCD camera
A charge-coupled device (CCD) is an integrated circuit containing an array of linked, or coupled, capacitors. Under the control of an external circuit, each capacitor can transfer its electric charge to a neighboring capacitor. CCD sensors are a ...
using Talbot phase-to-amplitude conversion. This by itself was an extraordinary breakthrough. It was the first time that electromagnetic waves were imaged directly, appearing much like ripples in a pond when a rock plummets through the water's surface (see Fig. 3). Real-space imaging is the preferred detection technique in polaritonics, though other more conventional techniques like optical Kerr-gating, time resolved
diffraction
Diffraction is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a s ...
, interferometric probing, and terahertz field induced
second-harmonic generation
Second-harmonic generation (SHG, also called frequency doubling) is a nonlinear optical process in which two photons with the same frequency interact with a nonlinear material, are "combined", and generate a new photon with twice the energy of ...
are useful in some applications where real-space imaging is not easily employed. For example, patterned materials with feature sizes on the order of a few tens of
micrometre
The micrometre ( international spelling as used by the International Bureau of Weights and Measures; SI symbol: μm) or micrometer (American spelling), also commonly known as a micron, is a unit of length in the International System of Unit ...
s cause parasitic scattering of the imaging light. Phonon-polariton detection is then only possible by focusing a more conventional probe, like those mentioned before, into an unblemished region of the crystal.
Guidance and control
The last element requisite to polaritonics is guidance and control. Complete lateral propagation parallel to the crystal plane is achieved by generating phonon-polaritons in crystals of thickness on the order of the phonon-polariton wavelength. This forces propagation to take place in one or more of the available slab waveguide modes. However, dispersion in these modes can be radically different from that in bulk propagation, and in order to exploit this, the dispersion must be understood.
Control and guidance of phonon-polariton propagation may also be achieved by guided wave, reflective, diffractive, and dispersive elements, as well as photonic and effective index crystals that can be integrated directly into the host crystal. However,
lithium niobate
Lithium niobate () is a non-naturally-occurring salt consisting of niobium, lithium, and oxygen. Its single crystals are an important material for optical waveguides, mobile phones, piezoelectric sensors, optical modulators and various other linea ...
,
lithium tantalate
Lithium tantalate ( Li Ta O3) is a perovskite which possesses unique optical, piezoelectric and pyroelectric properties which make it valuable for nonlinear optics, passive infrared sensors such as motion detectors, terahertz generation and detec ...
, and other
perovskite
Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as (XIIA2+VIB4+X2−3), known as ...
s are impermeable to the standard techniques of material patterning. In fact, the only
etchant known to be even marginally successful is
hydrofluoric acid
Hydrofluoric acid is a Solution (chemistry), solution of hydrogen fluoride (HF) in water. Solutions of HF are colourless, acidic and highly Corrosive substance, corrosive. It is used to make most fluorine-containing compounds; examples include th ...
(HF), which etches slowly and predominantly in the direction of the crystal optic axis.
Laser Micromachining
Femtosecond laser
micromachining is used for device fabrication by milling 'air' holes and/or troughs into ferroelectric crystals by directing them through the focus region of a femtosecond laser beam. . The advantages of femtosecond laser micromachining for a wide range of materials have been well documented. In brief, free electrons are created within the beam focus through
multiphoton excitation
Excitation, excite, exciting, or excitement may refer to:
* Excitation (magnetic), provided with an electrical generator or alternator
* Excite Ballpark, located in San Jose, California
* Excite (web portal), web portal owned by IAC
* Electron exc ...
. Because the peak intensity of a
femtosecond laser
Mode locking is a technique in optics by which a laser can be made to produce pulses of light of extremely short duration, on the order of picoseconds (10−12 s) or femtoseconds (10−15 s). A laser operated in this way is sometimes r ...
pulse is many orders of magnitude higher than that from longer pulse or continuous wave lasers, the electrons are rapidly excited, heated to form a
quantum plasma. Particularly in dielectric materials, the electrostatic instability, induced by the
plasma
Plasma or plasm may refer to:
Science
* Plasma (physics), one of the four fundamental states of matter
* Plasma (mineral), a green translucent silica mineral
* Quark–gluon plasma, a state of matter in quantum chromodynamics
Biology
* Blood pla ...
, of the remaining lattice
ions
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conven ...
results in ejection of these ions and hence
ablation
Ablation ( la, ablatio – removal) is removal or destruction of something from an object by vaporization, chipping, erosion, erosive processes or by other means. Examples of ablative materials are described below, and include spacecraft materi ...
of the material, leaving a material void in the laser focus region. Also, since the pulse duration and ablation time scales are much faster than the
thermalization
In physics, thermalisation is the process of physical bodies reaching thermal equilibrium through mutual interaction. In general the natural tendency of a system is towards a state of equipartition of energy and uniform temperature that maximizes ...
time, femtosecond laser micromachining does not suffer from the adverse effects of a heat-affected-zone, like cracking and melting in regions neighboring the intended damage region.
See also
*
Electronics
The field of electronics is a branch of physics and electrical engineering that deals with the emission, behaviour and effects of electrons using electronic devices. Electronics uses active devices to control electron flow by amplification ...
*
Photonics
Photonics is a branch of optics that involves the application of generation, detection, and manipulation of light in form of photons through emission, transmission, modulation, signal processing, switching, amplification, and sensing. Though ...
*
Polariton
In physics, polaritons are quasiparticles resulting from strong coupling of electromagnetic waves with an electric or magnetic dipole-carrying excitation. They are an expression of the common quantum phenomenon known as level repulsion, also ...
*
Spintronics
Spintronics (a portmanteau meaning spin transport electronics), also known as spin electronics, is the study of the intrinsic spin of the electron and its associated magnetic moment, in addition to its fundamental electronic charge, in solid-sta ...
*
Polariton laser A polariton laser is a novel type of laser source that exploits the coherent nature of Bose condensates of exciton-polaritons in semiconductors to achieve ultra-low threshold lasing.
In 1996, Imamoglu ''et al.'' proposed such a novel type of coher ...
External references
*
*
* David W. Ward
Polaritonics: An Intermediate Regime between Electronics and Photonics Ph.D. Thesis, Massachusetts Institute of Technology, 2005. This is the main reference for this article.
*
*
*
*
*
External links
The research groupat
MIT
The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of the m ...
that invented polaritonics.
References
{{Reflist
Photonics
Nanoelectronics
Solid state engineering