Photoconductivity is an

optical Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultravio ...

and

electrical phenomenon This is a list of electrical phenomena. Electrical phenomena are a somewhat arbitrary division of electromagnetic phenomena. Some examples are: * Biefeld–Brown effect — Thought by the person who coined the name, Thomas Townsend Brown, to ...

in which a material becomes more

electrically conductive Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allow ...

due to the absorption of

electromagnetic radiation In physics, electromagnetic radiation (EMR) consists of waves of the electromagnetic (EM) field, which propagate through space and carry momentum and electromagnetic radiant energy. It includes radio waves, microwaves, infrared, (visible) li ...

such as

visible light Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 te ...

ultraviolet Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30 PHz) to 400 nm (750 THz), shorter than that of visible light, but longer than X-rays. UV radiation ...

light,

infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...

light, or gamma radiation. When light is absorbed by a material such as a

semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. ...

, the number of free electrons and holes increases, resulting in increased electrical conductivity. To cause excitation, the light that strikes the semiconductor must have enough energy to raise electrons across the

band gap In solid-state physics, a band gap, also called an energy gap, is an energy range in a solid where no electronic states can exist. In graphs of the electronic band structure of solids, the band gap generally refers to the energy difference ( ...

, or to excite the impurities within the band gap. When a

bias Bias is a disproportionate weight ''in favor of'' or ''against'' an idea or thing, usually in a way that is closed-minded, prejudicial, or unfair. Biases can be innate or learned. People may develop biases for or against an individual, a group ...

voltage Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to ...

and a load resistor are used in series with the semiconductor, a voltage drop across the load resistors can be measured when the change in electrical conductivity of the material varies the current through the circuit. Classic examples of photoconductive materials include: * photographic film: Kodachrome, Fujifilm, Agfachrome, Ilford, ''etc.'', based on silver sulfide and silver bromide. * the

conductive polymer Conductive polymers or, more precisely, intrinsically conducting polymers (ICPs) are organic polymers that conduct electricity. Such compounds may have metallic conductivity or can be semiconductors. The biggest advantage of conductive polymers ...

poly vinylcarbazole, used extensively in

photocopy A photocopier (also called copier or copy machine, and formerly Xerox machine, the generic trademark) is a machine that makes copies of documents and other visual images onto paper or plastic film quickly and cheaply. Most modern photocopiers ...

ing (

xerography Xerography is a dry photocopying technique. Originally called electrophotography, it was renamed xerography—from the roots el, ξηρός, label=none ''xeros'', meaning "dry" and -γραφία ''-graphia'', meaning "writing"—to emphasize ...

); *

lead sulfide Lead sulfide refers to two compounds containing lead and sulfur: * Lead(II) sulfide, PbS, containing lead in the +2 oxidation state, naturally occurring as the mineral galena *Lead(IV) sulfide Lead(IV) sulfide is a chemical compound with the formu ...

, used in infrared detection applications, such as the U.S. Sidewinder and Soviet (now Russian)

Atoll An atoll () is a ring-shaped island, including a coral rim that encircles a lagoon partially or completely. There may be coral islands or cays on the rim. Atolls are located in warm tropical or subtropical oceans and seas where corals can gr ...

heat-seeking Infrared homing is a passive weapon guidance system which uses the infrared (IR) light emission from a target to track and follow it seamlessly. Missiles which use infrared seeking are often referred to as "heat-seekers" since infrared is rad ...

missile In military terminology, a missile is a guided airborne ranged weapon capable of self-propelled flight usually by a jet engine or rocket motor. Missiles are thus also called guided missiles or guided rockets (when a previously unguided rocke ...

s; *

selenium Selenium is a chemical element with the symbol Se and atomic number 34. It is a nonmetal (more rarely considered a metalloid) with properties that are intermediate between the elements above and below in the periodic table, sulfur and tellurium, ...

, employed in early television and

. Molecular photoconductors include organic, inorganic, and – more rarely – coordination compounds.

Applications

When a photoconductive material is connected as part of a circuit, it functions as a resistor whose resistance depends on the light intensity. In this context, the material is called a

photoresistor A photoresistor (also known as a photocell, or light-dependent resistor, LDR, or photo-conductive cell) is a passive component that decreases resistance with respect to receiving luminosity (light) on the component's sensitive surface. The resi ...

(also called ''light-dependent resistor'' or ''photoconductor''). The most common application of photoresistors is as

photodetector Photodetectors, also called photosensors, are sensors of light or other electromagnetic radiation. There is a wide variety of photodetectors which may be classified by mechanism of detection, such as photoelectric or photochemical effects, or ...

s, i.e. devices that measure light intensity. Photoresistors are not the ''only'' type of photodetector—other types include

charge-coupled device A charge-coupled device (CCD) is an integrated circuit containing an array of linked, or coupled, capacitors. Under the control of an external circuit, each capacitor can transfer its electric charge to a neighboring capacitor. CCD sensors are a ...

s (CCDs), photodiodes and

phototransistor A photodiode is a light-sensitive semiconductor diode. It produces current when it absorbs photons. The package of a photodiode allows light (or infrared or ultraviolet radiation, or X-rays) to reach the sensitive part of the device. The packa ...

s—but they are among the most common. Some photodetector applications in which photoresistors are often used include camera light meters, street lights, clock radios,

infrared detector An infrared detector is a detector that reacts to infrared (IR) radiation. The two main types of detectors are thermal and photonic (photodetectors). The thermal effects of the incident IR radiation can be followed through many temperature depen ...

s, nanophotonic systems and low-dimensional photo-sensors devices.

Sensitization

Sensitization is an important engineering procedure to amplify the response of photoconductive materials. The photoconductive gain is proportional to the lifetime of photo-excited carriers (either electrons or holes). Sensitization involves intentional impurity doping that saturates native recombination centers with a short characteristic lifetime, and replacing these centers with new recombination centers having a longer lifetime. This procedure, when done correctly, results in an increase in the photoconductive gain of several orders of magnitude and is used in the production of commercial photoconductive devices. The text by Albert Rose is the work of reference for sensitization.

Negative photoconductivity

Some materials exhibit deterioration in photoconductivity upon exposure to illumination. One prominent example is hydrogenated amorphous silicon (a-Si:H) in which a metastable reduction in photoconductivity is observable (see

Staebler–Wronski effect The Staebler–Wronski Effect (SWE) refers to light-induced metastable changes in the properties of hydrogenated amorphous silicon. The defect density of hydrogenated amorphous silicon (a-Si:H) increases with light exposure, causing an increase in ...

). Other materials that were reported to exhibit negative photoconductivity include molybdenum disulfide,

graphene Graphene () is an allotrope of carbon consisting of a single layer of atoms arranged in a hexagonal lattice nanostructure.

, indium arsenide

nanowire A nanowire is a nanostructure in the form of a wire with the diameter of the order of a nanometre (10−9 metres). More generally, nanowires can be defined as structures that have a thickness or diameter constrained to tens of nanometers or less ...

s, decorated carbon nanotubes, and metal

nanoparticle A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 10 ...

Magnetic photoconductivity

In 2016 it was demonstrated that in some photoconductive material a magnetic order can exist. One prominent example is CH₃NH₃(Mn:Pb)I₃. In this material a light induced magnetization melting was also demonstrated thus could be used in magneto optical devices and data storage.

Photoconductivity spectroscopy

The characterization technique called photoconductivity spectroscopy (also known as photocurrent spectroscopy) is widely used in studying optoelectronic properties of semiconductors.

References