Peridotite ( ) is a dense, coarse-grained
igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...
consisting mostly of the silicate minerals
olivine
The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickl ...
and
pyroxene
The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
. Peridotite is
ultramafic
Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are composed ...
, as the rock contains less than 45%
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
. It is high in
magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
(Mg
2+), reflecting the high proportions of magnesium-rich olivine, with appreciable
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
. Peridotite is derived from
Earth's mantle
Earth's mantle is a layer of silicate rock between the crust and the outer core. It has a mass of 4.01 × 1024 kg and thus makes up 67% of the mass of Earth. It has a thickness of making up about 84% of Earth's volume. It is predominantly sol ...
, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered
igneous
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or ...
complexes vary widely, reflecting the relative proportions of
pyroxene
The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
s,
chromite
Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging to the spinel group. The element magnesium can s ...
,
plagioclase
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more prope ...
, and
amphibole
Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is A ...
.
Peridotite is the dominant rock of the
upper part of Earth's mantle. The compositions of peridotite
nodules found in certain basalts are of special interest along with
diamond pipes (
kimberlite
Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of ...
), because they provide samples of Earth's mantle brought up from depths ranging from about 30 km to 200 km or more. Some of the nodules preserve
isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers) ...
ratios of
osmium
Osmium (from Greek grc, ὀσμή, osme, smell, label=none) is a chemical element with the symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition metal in the platinum group that is found as a trace element in alloys, mos ...
and other elements that record processes that occurred when Earth was formed, and so they are of special interest to
paleogeologists because they provide clues to the early composition of Earth's mantle and the complexities of the processes that occurred.
The word ''peridotite'' comes from the gemstone
peridot
Peridot ( /ˈpɛr.ɪˌdɒt, -ˌdoʊ/ ''PERR-ih-dot, -doh''), sometimes called chrysolite, is a deep yellowish-green transparent variety of olivine. Peridot is one of the few gemstones that only occurs in one color.
Peridot can be found in ...
, which consists of pale green olivine. Classic peridotite is bright green with some specks of black, although most hand samples tend to be darker green. Peridotitic outcrops typically range from earthy bright yellow to dark green; this is because olivine is easily weathered to
iddingsite
Iddingsite is a microcrystalline rock that is derived from alteration of olivine. It is usually studied as a mineral, and consists of a mixture of remnant olivine, clay minerals, iron oxides, and ferrihydrites. Debates over iddingsite's non-defi ...
. While green and yellow are the most common colors, peridotitic rocks may exhibit a wide range of colors including blue, brown, and red.
Classification
![Peridotite Olivine-Orthopyroxene-Clinopyroxene - Common Peridotites highlighted](https://upload.wikimedia.org/wikipedia/commons/a/ae/Peridotite_Olivine-Orthopyroxene-Clinopyroxene_-_Common_Peridotites_highlighted.png)
Coarse-grained igneous rocks in which
mafic
A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include ...
minerals (minerals rich in
magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
and
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
) make up over 90% of the volume of the rock are classified as
ultramafic rocks
Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are composed ...
.
Such rocks typically contain less than 45 wt% silica. Ultramafic rocks are further classified by their relative proportions of
olivine
The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickl ...
,
orthopyroxene
The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
,
clinopyroxene
The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...
, and
hornblende
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks ...
, which are the most abundant families of mafic minerals in most ultramafic rocks. Peridotite is then defined as coarse-grained ultramafic rock in which olivine makes up 40% or more of the total volume of these four mineral families in the rock.
Peridotites are further classified as follows:
*
Dunite
Dunite (), also known as olivinite (not to be confused with the mineral olivenite), is an intrusive igneous rock of ultramafic composition and with phaneritic (coarse-grained) texture. The mineral assemblage is greater than 90% olivine, with mi ...
: more than 90% olivine
: Dunite is found as prominent veins in the peridotite layer of
ophiolites
An ophiolite is a section of Earth's oceanic crust and the underlying upper mantle that has been uplifted and exposed above sea level and often emplaced onto continental crustal rocks.
The Greek word ὄφις, ''ophis'' (''snake'') is found i ...
, which are interpreted as slices of oceanic lithosphere (crust and upper mantle) thrust onto continents. Dunite also occurs as a
cumulate
Cumulate rocks are igneous rocks formed by the accumulation of crystals from a magma either by settling or floating. Cumulate rocks are named according to their texture; cumulate texture is diagnostic of the conditions of formation of this group o ...
in
layered intrusion
A layered intrusion is a large sill-like body of igneous rock which exhibits vertical layering or differences in composition and texture. These intrusions can be many kilometres in area covering from around to over and several hundred metres to ...
s, where olivine crystallized out of a slowly cooling body of
magma
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
and accumulated on the floor of the magma body to form the lowest layer of the intrusion. Dunite almost always contains accessory
chromite
Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging to the spinel group. The element magnesium can s ...
.
*
Kimberlite
Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of ...
: formed in
volcanic pipe
Volcanic pipes or volcanic conduits are subterranean geological structures formed by the violent, supersonic eruption of deep-origin volcanoes. They are considered to be a type of ''diatreme''. Volcanic pipes are composed of a deep, narrow cone of ...
s and at least 35% olivine
: Kimberlite is a highly
breccia
Breccia () is a rock composed of large angular broken fragments of minerals or rocks cemented together by a fine-grained matrix.
The word has its origins in the Italian language, in which it means "rubble". A breccia may have a variety of di ...
ted variant of peridotite formed in
volcanic pipe
Volcanic pipes or volcanic conduits are subterranean geological structures formed by the violent, supersonic eruption of deep-origin volcanoes. They are considered to be a type of ''diatreme''. Volcanic pipes are composed of a deep, narrow cone of ...
s and is known for being the host rock to diamonds. Unlike other forms of peridotite, kimberlite is quite rare.
* Pyroxene peridotite: From 40% to 90% olivine and less than 5% hornblende
**
Harzburgite
Harzburgite, an ultramafic, igneous rock, is a variety of peridotite consisting mostly of the two minerals olivine and low-calcium (Ca) pyroxene ( enstatite); it is named for occurrences in the Harz Mountains of Germany. It commonly contains a ...
: less than 5% clinopyroxene
:: Harzburgite makes up the bulk of the peridotite layer of
ophiolites
An ophiolite is a section of Earth's oceanic crust and the underlying upper mantle that has been uplifted and exposed above sea level and often emplaced onto continental crustal rocks.
The Greek word ὄφις, ''ophis'' (''snake'') is found i ...
. It is interpreted as depleted mantle rock, from which
basaltic
Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90% of a ...
magma has been extracted. It also forms as a cumulate in Type I layered intrusions, forming a layer just above the dunite layer. Harzburgite likely makes up most of the mantle lithosphere underneath continental
craton
A craton (, , or ; from grc-gre, κράτος "strength") is an old and stable part of the continental lithosphere, which consists of Earth's two topmost layers, the crust and the uppermost mantle. Having often survived cycles of merging and ...
s.
:*
Wehrlite: less than 5% orthopyroxene
:: Wehrlite makes up part of the transition zone between the peridotite layer and overlying
gabbro
Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is che ...
layer of
ophiolites
An ophiolite is a section of Earth's oceanic crust and the underlying upper mantle that has been uplifted and exposed above sea level and often emplaced onto continental crustal rocks.
The Greek word ὄφις, ''ophis'' (''snake'') is found i ...
. In Type II layered intrusions, it takes the place of harzburgite as the layer just above the dunite layer.
:*
Lherzolite
Lherzolite is a type of ultramafic igneous rock. It is a coarse-grained rock consisting of 40 to 90% olivine along with significant orthopyroxene and lesser amounts of calcic chromium-rich clinopyroxene. Minor minerals include chromium and alu ...
: intermediate content of clinopyroxene and orthopyroxene
:: Lherzolite is thought to make up much of the upper mantle. It has almost exactly the composition of a mixture of three parts harzburgite and one part
tholeiitic basalt
The tholeiitic magma series is one of two main magma series in subalkaline igneous rocks, the other being the calc-alkaline series. A magma series is a chemically distinct range of magma compositions that describes the evolution of a mafic magma i ...
(''
pyrolite Pyrolite is a term used to characterize a model composition of the Earth's mantle. This model is based on that a pyrolite source can produce the Mid-Ocean Ridge Basalt by partial melting. It was first proposed by Ted Ringwood (1962) as being 1 part ...
'') and is the likely source rock for basaltic magma. It is found as rare
xenolith
A xenolith ("foreign rock") is a rock fragment (country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in igne ...
s in basalt, such as those of
Kilbourne Hole
Kilbourne Hole is a maar volcanic crater, located west of the Franklin Mountains of El Paso, Texas, in the Potrillo volcanic field of Doña Ana County, New Mexico. Another maar, Hunt's Hole, lies just two miles south of Kilbourne Hole. Kilbour ...
in southern New Mexico, US, and at
Oahu
Oahu () (Hawaiian language, Hawaiian: ''Oʻahu'' ()), also known as "The Gathering place#Island of Oʻahu as The Gathering Place, Gathering Place", is the third-largest of the Hawaiian Islands. It is home to roughly one million people—over t ...
, Hawaii, US.
* Hornblende peridotite: From 40% to 90% olivine and less than 5% pyroxene
: Hornblende peridotite is found as rare xenoliths in
andesite
Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predomi ...
s above
subduction zones
Subduction is a geological process in which the oceanic lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, the ...
. They are direct evidence of alteration of mantle rock by fluids released by the subducting
slab
Slab or SLAB may refer to:
Physical materials
* Concrete slab, a flat concrete plate used in construction
* Stone slab, a flat stone used in construction
* Slab (casting), a length of metal
* Slab (geology), that portion of a tectonic plate that i ...
.
* Pyroxene hornblende peridotite: Intermediate between pyroxene peridotite and hornblende peridotite
: Pyroxene hornblende peridotite is found as rare xenoliths, such as those of
Wilcza Góra in southwest Poland. Here it likely formed by alteration of mantle rock by carbonated hydrous silicic fluids associated with volcanism.
Composition
Mantle peridotite is highly enriched in magnesium, with a typical magnesium number of 89. In other words, of the total content of iron plus magnesium, 89
mol%
In chemistry, the mole fraction or molar fraction (''xi'' or ) is defined as unit of the amount of a constituent (expressed in moles), ''ni'', divided by the total amount of all constituents in a mixture (also expressed in moles), ''n''tot. This ex ...
is magnesium. This is reflected in the composition of the mafic minerals making up the peridotite.
Olivine is the essential mineral found in all peridotites. It is a magnesium
orthosilicate
In chemistry, orthosilicate is the anion , or any of its salts and esters. It is one of the silicate anions. It is occasionally called the silicon tetroxide anion or group.C. A. Kumins, and A. E. Gessler (1953), "Short-Cycle Syntheses of Ultrama ...
containing some iron with the variable formula . The magnesium-rich olivine of peridotites is typically olive-green in color.
Pyroxenes are chain silicates having the variable formula comprising a large group of different minerals. These are divided into orthopyroxenes (with an
orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a r ...
crystal structure) and clinopyroxenes (with a
monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...
crystal structure). This distinction is important in the classification of pyroxene peridotites
since clinopyroxene melts more easily than orthopyroxene or olivine. The most common orthopyroxene is
enstatite
Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and m ...
, , in which iron substitutes for some of the magnesium. The most important clinopyroxene is
diopside
Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
, , again with some substitution of iron for magnesium (
hedenbergite
Hedenbergite, Ca Fe Si2 O6, is the iron rich end member of the pyroxene group having a monoclinic crystal system. The mineral is extremely rarely found as a pure substance, and usually has to be synthesized in a lab. It was named in 1819 after M ...
, ). Ultramafic rock in which the fraction of pyroxenes exceeds 60% are classified as
pyroxenite
Pyroxenite is an ultramafic igneous rock consisting essentially of minerals of the pyroxene group, such as augite, diopside, hypersthene, bronzite or enstatite. Pyroxenites are classified into clinopyroxenites, orthopyroxenites, and the websteri ...
s rather than peridotites. Pyroxenes are typically dark in color.
Hornblende is an
amphibole
Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is A ...
, a group of minerals resembling pyroxenes but with a double chain structure incorporating water. Hornblende itself has a highly variable composition, ranging from
tschermakite
The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the therm ...
() to
pargasite
Pargasite is a complex inosilicate mineral of the amphibole group with formula NaCa2(Mg4Al)(Si6Al2)O22(OH)2.
It was first described for an occurrence in Pargas, Finland in 1814 and named for the locality.
It occurs in high temperature regional ...
() with many other variations in composition. It is present in peridotite mostly as a consequence of alteration by hydrous fluids.
[
Although peridotites are classified by their content of olivine, pyroxenes, and hornblende, a number of other mineral families are characteristically present in peridotites and may make up a significant fraction of their composition. For example, chromite is sometimes present in amounts of up to 50%. (A chromite composition above 50% reclassifies the rock as a ''peridotitic chromitite''.) Other common accessory minerals include ]spinel
Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , which means ''spine'' in reference to its pointed crystals.
Properties
S ...
, garnet
Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different s ...
, biotite
Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more alumino ...
, or magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With the ...
. A peridotite containing significant amounts of one of these minerals may have its classification refined accordingly; for example, if a lhertzolite contains up to 5% spinel, it is a ''spinel-bearing lhertzolite'', while for amounts up to 50%, it would be classified as a ''spinel lhertzolite''. The accessory minerals can be useful for estimating the depth of formation of the peridotite. For example, the aluminium in lhertzolite is present as plagioclase
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more prope ...
at depths shallower than about , while it is present as spinel between 20 km and and as garnet below 60 km.
Distribution and location
Peridotite is the dominant rock of the Earth's mantle above a depth of about 400 km; below that depth, olivine is converted to the higher-pressure mineral wadsleyite
Wadsleyite is an orthorhombic mineral with the formula β-(Mg,Fe)2SiO4. It was first found in nature in the Peace River meteorite from Alberta, Canada. It is formed by a phase transformation from olivine (α-(Mg,Fe)2SiO4) under increasing pressu ...
.
Oceanic plates consist of up to about 100 km of peridotite covered by a thin crust. The crust, commonly about 6 km thick, consists of basalt, gabbro, and minor sediments. The peridotite below the ocean crust, "abyssal peridotite," is found on the walls of rifts in the deep sea floor. Oceanic plates are usually subducted back into the mantle in subduction zones
Subduction is a geological process in which the oceanic lithosphere is recycled into the Earth's mantle at convergent boundaries. Where the oceanic lithosphere of a tectonic plate converges with the less dense lithosphere of a second plate, the ...
. However, pieces can be emplaced into or overthrust on continental crust
Continental crust is the layer of igneous, sedimentary, and metamorphic rocks that forms the geological continents and the areas of shallow seabed close to their shores, known as continental shelves. This layer is sometimes called ''sial'' be ...
by a process called obduction
Obduction is a geological process whereby denser oceanic crust (and even upper mantle) is scraped off a descending ocean plate at a convergent plate boundary and thrust on top of an adjacent plate. When oceanic and continental plates converge, ...
, rather than carried down into the mantle. The emplacement may occur during orogenies, as during collisions of one continent with another or with an island arc
Island arcs are long chains of active volcanoes with intense seismic activity found along convergent tectonic plate boundaries. Most island arcs originate on oceanic crust and have resulted from the descent of the lithosphere into the mantle alon ...
. The pieces of oceanic plates emplaced within continental crust are referred to as ophiolites
An ophiolite is a section of Earth's oceanic crust and the underlying upper mantle that has been uplifted and exposed above sea level and often emplaced onto continental crustal rocks.
The Greek word ὄφις, ''ophis'' (''snake'') is found i ...
. Typical ophiolites consist mostly of peridotite plus associated rocks such as gabbro
Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is che ...
, pillow basalt
Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90% of a ...
, diabase sill-and-dike complexes, and red chert. ''Alpine peridotite'' or ''orogenic peridotite massif'' is an older term for an ophiolite emplaced in a mountain belt during a continent-continent plate collision.
Peridotites also occur as fragments (xenolith
A xenolith ("foreign rock") is a rock fragment (country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in igne ...
s) carried up by magmas from the mantle. Among the rocks that commonly include peridotite xenoliths are basalt
Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...
and kimberlite
Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of ...
. Although kimberlite
Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of ...
is a variant of peridotite, kimberlite is also considered as breccia
Breccia () is a rock composed of large angular broken fragments of minerals or rocks cemented together by a fine-grained matrix.
The word has its origins in the Italian language, in which it means "rubble". A breccia may have a variety of di ...
ted volcanic material as well, which is why it is referred to as a source of peridotite xenoliths. Peridotite xenoliths contain osmium and other elements whose stable isotope ratio
The term stable isotope has a meaning similar to stable nuclide, but is preferably used when speaking of nuclides of a specific element. Hence, the plural form stable isotopes usually refers to isotopes of the same element. The relative abundanc ...
s provide clues on the formation and evolution of the Earth's mantle. Such xenoliths originate from depths of up to nearly or more.
The volcanic equivalent of peridotites are komatiite
Komatiite () is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% MgO. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite wa ...
s, which were mostly erupted early in the Earth's history and are rare in rocks younger than Archean
The Archean Eon ( , also spelled Archaean or Archæan) is the second of four geologic eons of Earth's history, representing the time from . The Archean was preceded by the Hadean Eon and followed by the Proterozoic.
The Earth
Earth ...
in age.
Small pieces of peridotite have been found in lunar breccias.
The rocks of the peridotite family are uncommon at the surface and are highly unstable, because olivine reacts quickly with water at typical temperatures of the upper crust and at the Earth's surface. Many, if not most, surface outcrops have been at least partly altered to serpentinite
Serpentinite is a rock composed predominantly of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called ''serpentine'' or ''ser ...
, a process in which the pyroxenes and olivines are converted to green serpentine.[ This hydration reaction involves considerable increase in volume with concurrent deformation of the original textures.] Serpentinites are mechanically weak and so flow readily within the earth. Distinctive plant communities grow in soils developed on serpentinite, because of the unusual composition of the underlying rock. One mineral in the serpentine group, chrysotile
Chrysotile or white asbestos is the most commonly encountered form of asbestos, accounting for approximately 95% of the asbestos in the United StatesOccupational Safety and Health Administration, U.S. Department of Labor (2007)29 C.F.R.&nbs ...
, is a type of asbestos.
Color, morphology, and texture
Most peridotite is green in color due to its high olivine content. However, peridotites can range in color from greenish-gray to nearly black to pale yellowish-green. Peridotite weathers to form a distinctive brown crust in subaerial exposures and to a deep orange color in submarine exposures.
Peridotites can take on a massive form or may be in layers on a variety of size scales. Layered peridotites may form the base layers of layered intrusions. These are characterized by cumulate texture
Cumulate rocks are igneous rocks formed by the accumulation of crystals from a magma either by settling or floating. Cumulate rocks are named according to their rock microstructure, texture; cumulate texture is diagnostic of the conditions of form ...
s, characterized by a fabric
Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the ...
of coarse (>5mm) interlocking euhedral (well-formed) crystals in a groundmass of finer crystals formed from liquid magma trapped in the cumulate. Many show poikilitic texture in which crystallization of this liquid has produced crystals that overgrow and enclose the original cumulus crystals (called ''chadrocrysts'').
Another texture is a ''well-annealed'' texture of equal sized anhedral crystals with straight grain boundaries intersecting at 120°. This may result when slow cooling allowed recrystallization to minimize surface energy. Cataclastic texture, showing irregular fractures and deformation twinning
Crystal twinning occurs when two or more adjacent crystals of the same mineral are oriented so that they share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals that are tightl ...
of olivine grains, is common in peridotites because of the deformation associated with their tectonic mode of emplacement.
Origin
Peridotites have two primary modes of origin: as mantle rocks formed during the accretion and differentiation of the Earth, or as cumulate rocks formed by precipitation of olivine ± pyroxenes from basaltic or ultramafic magmas. These magmas are ultimately derived from the upper mantle
The upper mantle of Earth is a very thick layer of rock inside the planet, which begins just beneath the crust (at about under the oceans and about under the continents) and ends at the top of the lower mantle at . Temperatures range from appro ...
by partial melting of mantle peridotites.
Mantle peridotites are sampled as ophiolites in collisional mountain ranges, as xenoliths in basalt or kimberlite, or as abyssal peridotites (sampled from ocean floor). These rocks represent either fertile mantle (lherzolite) or partially depleted mantle (harzburgite, dunite). Alpine peridotites may be either of the ophiolite association and representing the uppermost mantle below ocean basins, or masses of subcontinental mantle emplaced along thrust faults in mountain belts.
Layered peridotites are igneous sediments and form by mechanical accumulation of dense olivine crystals. They form from mantle-derived magmas, such as those of basalt composition. Peridotites associated with Alaskan-type ultramafic complexes are cumulates that probably formed in the root zones of volcanoes. Cumulate peridotites are also formed in komatiite
Komatiite () is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% MgO. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite wa ...
lava flows.
Associated rocks
Komatiite
Komatiite () is a type of ultramafic mantle-derived volcanic rock defined as having crystallised from a lava of at least 18 wt% MgO. Komatiites have low silicon, potassium and aluminium, and high to extremely high magnesium content. Komatiite wa ...
s are high temperature partial melts of peridotite characterized by a high degree of partial melting deep below the surface.
Eclogite
Eclogite () is a metamorphic rock containing garnet (almandine-pyrope) hosted in a matrix of sodium-rich pyroxene (omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, zoisite, dol ...
, a rock similar to basalt in composition, is composed primarily of omphacite
Omphacite is a member of the clinopyroxene group of silicate minerals with formula: ( Ca, Na)( Mg, Fe2+, Al) Si2 O6. It is a variably deep to pale green or nearly colorless variety of clinopyroxene. It normally appears in eclogite, which is the ...
(sodic clinopyroxene) and pyrope
The mineral pyrope is a member of the garnet group. Pyrope is the only member of the garnet family to always display red colouration in natural samples, and it is from this characteristic that it gets its name: from the Greek for ''fire'' and ''e ...
-rich garnet. Eclogite is associated with peridotite in some xenolith occurrences; it also occurs with peridotite in rocks metamorphosed
Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causin ...
at high pressures during processes related to subduction.
Economic geology
Peridotite may potentially be used in a low-cost, safe and permanent method of capturing and storing atmospheric CO2 as part of climate change
In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
-related greenhouse gas sequestration. It was already known that peridotite reacts with CO2 to form a solid carbonate
A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
-like limestone or marble mineral; and this process can be sped up a million times or more by simple drilling
Drilling is a cutting process where a drill bit is spun to cut a hole of circular cross-section in solid materials. The drill bit is usually a rotary cutting tool, often multi-point. The bit is pressed against the work-piece and rotated at ra ...
and hydraulic fracturing
Fracking (also known as hydraulic fracturing, hydrofracturing, or hydrofracking) is a well stimulation technique involving the fracturing of bedrock formations by a pressurized liquid. The process involves the high-pressure injection of "frack ...
to allow injection of the CO2 into the subsurface peridotite formation.
Peridotite is named for the gemstone
A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...
peridot
Peridot ( /ˈpɛr.ɪˌdɒt, -ˌdoʊ/ ''PERR-ih-dot, -doh''), sometimes called chrysolite, is a deep yellowish-green transparent variety of olivine. Peridot is one of the few gemstones that only occurs in one color.
Peridot can be found in ...
, a glassy green gem originally mined on St. John's Island in the Red Sea and now mined on the San Carlos Apache Indian Reservation
The San Carlos Apache Indian Reservation (Western Apache: Tsékʼáádn), in southeastern Arizona, United States, was established in 1872 as a reservation for the Chiricahua Apache tribe as well as surrounding Yavapai and Apache bands removed fro ...
in Arizona.
Peridotite that has been hydrated at low temperatures is the protolith for serpentinite
Serpentinite is a rock composed predominantly of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called ''serpentine'' or ''ser ...
, which may include chrysotile asbestos (a form of serpentine) and talc
Talc, or talcum, is a Clay minerals, clay mineral, composed of hydrated magnesium silicate with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thi ...
.
Layered intrusions with cumulate peridotite are typically associated with sulfide or chromite ores. Sulfides associated with peridotites form nickel ores and platinoid metals; most of the platinum
Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver".
Platinu ...
used in the world today is mined from the Bushveld Igneous Complex
The Bushveld Igneous Complex (BIC) is the largest layered igneous intrusion within the Earth's crust. It has been tilted and eroded forming the outcrops around what appears to be the edge of a great geological basin: the Transvaal Basin. It is ...
in South Africa
South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring countri ...
and the Great Dyke
The Great Dyke is a linear geological feature that trends nearly north-south through the centre of Zimbabwe passing just to the west of the capital, Harare. It consists of a band of short, narrow ridges and hills spanning for approximately . The ...
of Zimbabwe
Zimbabwe (), officially the Republic of Zimbabwe, is a landlocked country located in Southeast Africa, between the Zambezi and Limpopo Rivers, bordered by South Africa to the south, Botswana to the south-west, Zambia to the north, and Mozam ...
. The chromite bands found in peridotites are the world's major source of chromium
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.
Chromium metal is valued for its high corrosion resistance and hardne ...
.
References
Further reading
*
* J.-L. Bodinier and M. Godard, 2004, ''Orogenic, Ophiolitic, and Abyssal Peridotites'', in ''The Mantle and Core'' (ed. R. W. Carlson), ''Treatise on Geochemistry'' v. 2, Elsevier-Pergamon, Oxford
External links
{{Igneous rocks
Ultramafic rocks
Plutonic rocks