Palinuro Seamount
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Palinuro Seamount is a seamount in the
Tyrrhenian Sea The Tyrrhenian Sea (; it, Mar Tirreno , french: Mer Tyrrhénienne , sc, Mare Tirrenu, co, Mari Tirrenu, scn, Mari Tirrenu, nap, Mare Tirreno) is part of the Mediterranean Sea off the western coast of Italy. It is named for the Tyrrhenian pe ...
. It is an elongated long complex of volcanoes north of the Aeolian Islands with multiple potential
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcano eruption. When large volumes of magma are erupted over a short time, structural support for the rock above the magma chamber is ...
s. The shallowest point lies at depth and formed an island during past episodes of low sea level. Palinuro was active during the last 800,000 years and is likely the source for a 10,000 years old
tephra Tephra is fragmental material produced by a volcanic eruption regardless of composition, fragment size, or emplacement mechanism. Volcanologists also refer to airborne fragments as pyroclasts. Once clasts have fallen to the ground, they re ...
layer in Italy. Ongoing
seismicity Seismicity is a measure encompassing earthquake occurrences, mechanisms, and magnitude at a given geographical location. As such, it summarizes a region's seismic activity. The term was coined by Beno Gutenberg and Charles Francis Richter in 19 ...
occurs at the seamount, which may be a
tsunami A tsunami ( ; from ja, 津波, lit=harbour wave, ) is a series of waves in a water body caused by the displacement of a large volume of water, generally in an ocean or a large lake. Earthquakes, volcanic eruptions and other underwater exp ...
hazard. The volcanic activity may somehow relate to the subduction of the Ionian Sea farther east. Diffuse
hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
activity takes place on Palinuro Seamount, which has led to the deposition of sulfide deposits in the seafloor that could be used as a source of
ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
s for rare metals. Italy has declared the seamount a protected area, where
alga Algae (; singular alga ) is an informal term for a large and diverse group of photosynthetic eukaryotic organisms. It is a polyphyletic grouping that includes species from multiple distinct clades. Included organisms range from unicellular mic ...
e and
deep water coral The habitat of deep-water corals, also known as cold-water corals, extends to deeper, darker parts of the oceans than tropical corals, ranging from near the surface to the abyss, beyond where water temperatures may be as cold as . Deep-water cor ...
s occur.


Geography and geomorphology

Palinuro lies north of the Aeolian Islands, in the
Tyrrhenian Sea The Tyrrhenian Sea (; it, Mar Tirreno , french: Mer Tyrrhénienne , sc, Mare Tirrenu, co, Mari Tirrenu, scn, Mari Tirrenu, nap, Mare Tirreno) is part of the Mediterranean Sea off the western coast of Italy. It is named for the Tyrrhenian pe ...
. Marsili Seamount lies about southwest from Palinuro and Glabro Seamount east of Palinuro. The Palinuro seamount is one of the largest in the Tyrrhenian Sea and is also known as Palinuro-Strabo seamount. The seamount is about high. It has a - long and wide east-west elongated shape. It is asymmetric, with the northern slopes less steep as they descend to depth than the southern slopes. There are traces of mass failures along the seamount, especially on its southern flank, and of east-west trending
faulting In geology, a fault is a planar fracture or discontinuity in a volume of rock across which there has been significant displacement as a result of rock-mass movements. Large faults within Earth's crust result from the action of plate tectonic ...
. At least eight separate volcanoes make up Palinuro. A horseshoe shaped
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcano eruption. When large volumes of magma are erupted over a short time, structural support for the rock above the magma chamber is ...
is located in the western part of the seamount, and is wide. It may be related to a
sector collapse A sector collapse is the collapse of a portion of a volcano due to a phreatic eruption, an earthquake, or the intervention of new magma. Occurring on many volcanoes, sector collapses are generally one of the most hazardous volcanic events, and will ...
and has been modified by erosion and renewed volcanism at its rim. To its west is another potential, wide sediment-filled caldera at the western end of the volcano. On the eastern end of Palinuro lies another potential caldera, also filled with sediment, as well as an uneroded crater. In the central area of Palinuro, but still within the eastern sector, lies the summit region: Two flat-topped cones known as "Pjotr's cones", and wide. The smaller of which rises to - depth below sea level; it is the shallowest point of Palinuro. The flat-topped cones formed through erosion and feature
marine terrace A raised beach, coastal terrace,Pinter, N (2010): 'Coastal Terraces, Sealevel, and Active Tectonics' (educational exercise), from 2/04/2011or perched coastline is a relatively flat, horizontal or gently inclined surface of marine origin,Pira ...
s, which may have formed when sea levels were so low that the summit of Palinuro rose above the sea. Gullies, rocky outcrops and crater remnants are found on the flat-topped cones. Rocky outcrops are scarce in the central part of Palinuro seamount, which is largely covered with sediments.


Geology

The
African Plate The African Plate is a major tectonic plate that includes much of the continent of Africa (except for its easternmost part) and the adjacent oceanic crust to the west and south. It is bounded by the North American Plate and South American Plate ...
and
Eurasian Plate The Eurasian Plate is a tectonic plate that includes most of the continent of Eurasia (a landmass consisting of the traditional continents of Europe and Asia), with the notable exceptions of the Indian subcontinent, the Arabian subcontinent and ...
are converging across the
Mediterranean The Mediterranean Sea is a sea connected to the Atlantic Ocean, surrounded by the Mediterranean Basin and almost completely enclosed by land: on the north by Western Europe, Western and Southern Europe and Anatolia, on the south by North Africa ...
, leading to tectonic activity in the region including the subduction of the Ionian Sea (Calabrian subduction) and the eastward migration of this subduction. The southern Tyrrhenian Sea is a back-arc basin which began to form 11 million years ago through crustal extension behind the eastward-shifting Ionian subduction, and is a complex geodynamic system. It features several volcanoes, including the Aeolian Islands
volcanic arc A volcanic arc (also known as a magmatic arc) is a belt of volcanoes formed above a subducting oceanic tectonic plate, with the belt arranged in an arc shape as seen from above. Volcanic arcs typically parallel an oceanic trench, with the arc lo ...
generated by the Ionian subduction, the Marsili Seamount that appears to have formed on a
spreading ridge A mid-ocean ridge (MOR) is a seafloor mountain system formed by plate tectonics. It typically has a depth of about and rises about above the deepest portion of an ocean basin. This feature is where seafloor spreading takes place along a diver ...
-like structure, and Palinuro which has an unclear origin but may somehow relate to subduction as well. A 2017 proposal relates the volcanism of Palinuro and neighbouring seamounts except Marsili to the upwelling of asthenospheric mantle below the northern margin of the Calabrian subduction zone, and from underneath the descending Ionian
slab Slab or SLAB may refer to: Physical materials * Concrete slab, a flat concrete plate used in construction * Stone slab, a flat stone used in construction * Slab (casting), a length of metal * Slab (geology), that portion of a tectonic plate tha ...
. The seamount may be located at the margin between the oceanic Marsili basin to the south, and the
continental slope A continental margin is the outer edge of continental crust abutting oceanic crust under coastal waters. It is one of the three major zones of the ocean floor, the other two being deep-ocean basins and mid-ocean ridges. The continental margin ...
and sedimentary basin of the Salerno Gulf to the north. The east-west trending strike-slip fault that Palinuro seamount formed on may be the northern margin of the Calabrian subduction zone ("subduction-transform edge propagator") and continues through Glabro, Enotrio and Ovidio seamounts and then on land as the Cetraro-Rossano Line. This lineament also appears to separate a tectonically stable northern domain of Italy from a slowly uplifting southern domain. A second, northeastward trending lineament continues on land as the Palinuro-Sant' Arcangelo lineament.


Composition

Dredging has yielded
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
and
basaltic andesite Basaltic andesite is a volcanic rock that is intermediate in composition between basalt and andesite. It is composed predominantly of augite and plagioclase. Basaltic andesite can be found in volcanoes around the world, including in Central Amer ...
, which define a
calc-alkaline The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic m ...
rock suite.
Phenocryst 300px, feldspathic phenocrysts. This granite, from the Switzerland">Swiss side of the Mont Blanc massif, has large white plagioclase phenocrysts, triclinic minerals that give trapezoid shapes when cut through). 1 euro coins, 1 euro coin (diameter ...
s include
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...
and pyroxene.


Biology

Dense and large stands of
deep water coral The habitat of deep-water corals, also known as cold-water corals, extends to deeper, darker parts of the oceans than tropical corals, ranging from near the surface to the abyss, beyond where water temperatures may be as cold as . Deep-water cor ...
s and
coralline alga Coralline algae are red algae in the order Corallinales. They are characterized by a thallus that is hard because of calcareous deposits contained within the cell walls. The colors of these algae are most typically pink, or some other shade of ...
e grow on Palinuro, the latter particularly around the summit. Holothurians, melon sea urchins, nematodes, sabellids, serpulid worms,
spiny lobster Spiny lobsters, also known as langustas, langouste, or rock lobsters, are a family (Palinuridae) of about 60 species of achelate crustaceans, in the Decapoda Reptantia. Spiny lobsters are also, especially in Australia, New Zealand, Ireland, So ...
s,
sponge Sponges, the members of the phylum Porifera (; meaning 'pore bearer'), are a basal animal clade as a sister of the diploblasts. They are multicellular organisms that have bodies full of pores and channels allowing water to circulate throug ...
s, tube-dwelling anemones,
tunicate A tunicate is a marine invertebrate animal, a member of the subphylum Tunicata (). It is part of the Chordata, a phylum which includes all animals with dorsal nerve cords and notochords (including vertebrates). The subphylum was at one time ...
s and yellow gorgonians live there as well. Lower on the slopes algae become rarer and sponges more frequent, and
black coral Antipatharians, also known as black corals or thorn corals, are an order of soft deep-water corals. These corals can be recognized by their jet-black or dark brown chitin skeletons, surrounded by the polyps (part of coral that is alive). Antipat ...
s dominate at maximum depths.
Dolphin A dolphin is an aquatic mammal within the infraorder Cetacea. Dolphin species belong to the families Delphinidae (the oceanic dolphins), Platanistidae (the Indian river dolphins), Iniidae (the New World river dolphins), Pontoporiidae (the ...
s,
fish Fish are aquatic, craniate, gill-bearing animals that lack limbs with digits. Included in this definition are the living hagfish, lampreys, and cartilaginous and bony fish as well as various extinct related groups. Approximately 95% of ...
and
shark Sharks are a group of elasmobranch fish characterized by a cartilaginous skeleton, five to seven gill slits on the sides of the head, and pectoral fins that are not fused to the head. Modern sharks are classified within the clade Selachi ...
s complete the fauna of Palinuro. There are traces of human disturbances such as abandoned long-lines and coral colonies damaged by dredging.
Fossil A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
alga Algae (; singular alga ) is an informal term for a large and diverse group of photosynthetic eukaryotic organisms. It is a polyphyletic grouping that includes species from multiple distinct clades. Included organisms range from unicellular mic ...
e, bivalves, bryozoans,
coral Corals are marine invertebrates within the class Anthozoa of the phylum Cnidaria. They typically form compact colonies of many identical individual polyps. Coral species include the important reef builders that inhabit tropical oceans and ...
s,
echinoid Sea urchins () are spiny, globular echinoderms in the class Echinoidea. About 950 species of sea urchin live on the seabed of every ocean and inhabit every depth zone from the intertidal seashore down to . The spherical, hard shells (tests) of ...
s, gastropods, mussels and calcareous worm tubes have been dredged from Palinuro. When it was an emergent island during cold periods, Palinuro may have formed a stepping stone for plants. It still reaches into the photic zone of the sea, allowing the growth of
alga Algae (; singular alga ) is an informal term for a large and diverse group of photosynthetic eukaryotic organisms. It is a polyphyletic grouping that includes species from multiple distinct clades. Included organisms range from unicellular mic ...
e. Small hydrothermal deposits with the shape of chimneys are covered by
microbial mat A microbial mat is a multi-layered sheet of microorganisms, mainly bacteria and archaea, or bacteria alone. Microbial mats grow at interfaces between different types of material, mostly on submerged or moist surfaces, but a few survive in deserts ...
s and there are bushes of
tube worm A tubeworm is any worm-like sessile invertebrate that anchors its tail to an underwater surface and secretes around its body a mineral tube, into which it can withdraw its entire body. Tubeworms are found among the following taxa: * Annelida, the ...
s. However,
remotely operated vehicle A remotely operated underwater vehicle (technically ROUV or just ROV) is a tethered underwater mobile device, commonly called ''underwater robot''. Definition This meaning is different from remote control vehicles operating on land or in the a ...
s have not identified substantial hydrothermal vent-associated communities. Italy has declared Palinuro a protected area as part of the European Natura 2000 project.


Eruption history

Palinuro was active between 800,000 and 300,000 years ago. The growth of the seamount was probably protracted and complex and there appears to be a clear distinction between the eastern and western sectors of Palinuro, and the eastern half may be still active. Magnetic analysis indicates that fresh lavas occur in the eastern half of Palinuro while the western half shows evidence of
hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
alteration. The PL-1
volcanic ash Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, created during volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used to refer ...
layer, which has been detected in marine sediment cores and on land in Italy, has been interpreted to come from Palinuro. It has been dated to 8040
BCE Common Era (CE) and Before the Common Era (BCE) are year notations for the Gregorian calendar (and its predecessor, the Julian calendar), the world's most widely used calendar era. Common Era and Before the Common Era are alternatives to the or ...
, and may have been emitted from an emergent Palinuro when sea levels were lower.


Recent activity and hazards

Palinuro or its southeastern sector may still be active, as volcanic
seismicity Seismicity is a measure encompassing earthquake occurrences, mechanisms, and magnitude at a given geographical location. As such, it summarizes a region's seismic activity. The term was coined by Beno Gutenberg and Charles Francis Richter in 19 ...
has been detected between Palinuro and the Calabrian coast. Seismicity at low depths, perhaps linked to hydrothermal activity, has also been recorded. Microearthquakes between depth may mark a melt storage zone. Volcanic edifices are often unstable and prone to mass failures, and submarine volcanoes and volcanoes next to the seas can cause devastating
tsunami A tsunami ( ; from ja, 津波, lit=harbour wave, ) is a series of waves in a water body caused by the displacement of a large volume of water, generally in an ocean or a large lake. Earthquakes, volcanic eruptions and other underwater exp ...
s like the 2018 Sunda Strait tsunami caused by a collapse of
Anak Krakatau Anak Krakatoa ( id, Anak Krakatau)English translation and common name: ''Child of Krakatoa'' is a volcanic island in Indonesia. On 29 December 1927, Anak Krakatoa first emerged from the caldera formed in 1883 by the explosive volcanic eruption ...
volcano, which killed 437 people. Palinuro seamount shows evidence of past instability - including collapses that post-date the last glacial maximum 18,000-20,000 years ago, and seismicity and hydrothermal activity - which tend to weaken volcanic edifices - could contribute to future collapses on the volcano. Some collapse scenarios could generate waves several metres high that would impact Sicily and Campania.


Hydrothermal activity and deposits

Diffuse
hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
emissions have been found at Palinuro, which form small chimneys, stained rocks, spires reaching height and warm (>) muds with sulfide-sulfate deposits. The hydrothermal vents are found on the western side of Palinuro, around the horseshoe-shaped caldera, while hydrothermal vent deposits are found throughout the edifice. The vents around the horseshoe-shaped caldera may coincide with the margins of the caldera and thus are structurally controlled. Recent hydrothermal deposits around the summit, which was eroded during low sea level, indicate hydrothermal activity during the
Holocene The Holocene ( ) is the current geological epoch. It began approximately 11,650 cal years Before Present (), after the Last Glacial Period, which concluded with the Holocene glacial retreat. The Holocene and the preceding Pleistocene togeth ...
. The active hydrothermal vents are accompanied by chemical anomalies in the water column, and ships have reported a smell of hydrogen sulfide above the eastern part of Palinuro. Hydrothermal activity is responsible for the deposition of baryte, galena,
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue giv ...
and sphalerite, in the form of sulfide-
sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
deposits. Additional minerals reported are bravoite,
chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...
,
covellite Covellite (also known as covelline) is a rare copper sulfide mineral with the formula CuS. This indigo blue mineral is commonly a secondary mineral in limited abundance and although it is not an important ore of copper itself, it is well known t ...
,
enargite Enargite is a copper arsenic sulfosalt mineral with formula Cu3AsS4. It takes its name from the Greek word , "distinct". Enargite is a steel gray, blackish gray, to violet black mineral with metallic luster. It forms slender orthorhombic prisms as ...
,
marcasite The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...
, luzonite, melnikovite, tennanite,
wurtzite Wurtzite is a zinc and iron sulfide mineral with the chemical formula , a less frequently encountered structural polymorph form of sphalerite. The iron content is variable up to eight percent.Palache, Charles, Harry Berman & Clifford Frondel (19 ...
and lead and silver containing sulfosalts. The sulfide deposits typically have a gel-like appearance and contain bacterial fossils, implying that microbial activity played a major role in their development. They occur in several metres thick deposits, often buried by sediments and in proximity to hydrothermal vents. Such
seafloor massive sulfide deposits Seafloor massive sulfide deposits or SMS deposits, are modern equivalents of ancient volcanogenic massive sulfide ore deposits or VMS deposits. The term has been coined by mineral explorers to differentiate the modern deposit from the ancient. SM ...
are potential sources for metals, both base and precious, and have thus drawn scientific attention. Other reported minerals at Palinuro are
bismuthinite Bismuthinite is a mineral consisting of bismuth(III) sulfide, bismuth sulfide (bismuth, Bi2sulfur, S3). It is an important ore for bismuth. The crystals are steel-grey to off-white with a metallic luster. It is soft enough to be scratched with ...
,
bismuth Bismuth is a chemical element with the symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs ...
tellurides The telluride ion is the anion Te2− and its derivatives. It is analogous to the other chalcogenide anions, the lighter O2−, S2−, and Se2−, and the heavier Po2−. In principle, Te2− is formed by the two-e− reduction of telluri ...
,
stibnite Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2 S3. This soft grey material crystallizes in an orthorhombic space group. It is the most important source for the metalloid antimony. The name is derived from the ...
and traces of
gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile me ...
,
indium Indium is a chemical element with the symbol In and atomic number 49. Indium is the softest metal that is not an alkali metal. It is a silvery-white metal that resembles tin in appearance. It is a post-transition metal that makes up 0.21 parts ...
and
silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...
.
Iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
and
manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
-containing crusts and nodules occur on Palinuro, which probably formed under hydrothermal influence after a transition from high (which emplaced the sulfides) to low temperature hydrothermal activity. They are often found in spatial coincidence with sulfidic deposits which form chimneys. The crusts and nodules contain
manganate In inorganic nomenclature, a manganate is any negatively charged molecular entity with manganese as the central atom.. However, the name is usually used to refer to the tetraoxidomanganate(2−) anion, MnO, also known as manganate(VI) because it ...
plus
aragonite Aragonite is a carbonate mineral, one of the three most common naturally occurring crystal forms of calcium carbonate, (the other forms being the minerals calcite and vaterite). It is formed by biological and physical processes, including pre ...
, calcite,
clinopyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
,
illite Illite is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina ...
,
muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavag ...
,
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...
and
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
. The iron-manganese crusts have commercial potential.


References


Sources

* * * * * * * * * * * * * * * * * * * * * * * * * * {{refend Seamounts of the Mediterranean Landforms of the Tyrrhenian Sea Holocene volcanoes Former islands of Italy Volcanoes of Italy Calderas of Italy Submarine calderas