Plutonium and uranium extraction from nuclear fuel-eng

PUREX (plutonium uranium reduction extraction) is a

chemical A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., wi ...

method used to purify fuel for

nuclear reactor A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat from nu ...

s or

nuclear weapons A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions (thermonuclear bomb), producing a nuclear explosion. Both bomb ...

. PUREX is the ''

de facto ''De facto'' ( ; , "in fact") describes practices that exist in reality, whether or not they are officially recognized by laws or other formal norms. It is commonly used to refer to what happens in practice, in contrast with ''de jure'' ("by la ...

'' standard aqueous

nuclear reprocessing Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the ...

method for the recovery of

uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...

and

plutonium Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibi ...

from used

nuclear fuel Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission. Most nuclear fuels contain heavy fissile actinide elements that are capable of undergoing ...

(

spent nuclear fuel Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor (usually at a nuclear power plant). It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor an ...

, or

irradiated Irradiation is the process by which an object is exposed to radiation. The exposure can originate from various sources, including natural sources. Most frequently the term refers to ionizing radiation, and to a level of radiation that will serve ...

nuclear fuel). It is based on

liquid–liquid extraction Liquid–liquid extraction (LLE), also known as solvent extraction and partitioning, is a method to separate compounds or metal complexes, based on their relative solubilities in two different immiscible liquids, usually water (polar) and an orga ...

ion-exchange. PUREX is applied to

, which consists primarily of very high atomic-weight (

actinoid The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The inform ...

or "actinide") elements (e.g.

americium Americium is a synthetic radioactive chemical element with the symbol Am and atomic number 95. It is a transuranic member of the actinide series, in the periodic table located under the lanthanide element europium, and thus by analogy was na ...

) along with smaller amounts of material composed of lighter atoms, notably the fission products produced by reactor operation. Uranium Reprocessing

The actinoid elements in this case consist primarily of the unconsumed remains of the original fuel (typically

U-235 Uranium-235 (235U or U-235) is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, i.e., it can sustain a nuclear chain reaction. It is the only fissile isotope that exist ...

, U-238, and/or

Pu-239 Plutonium-239 (239Pu or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three main ...

Chemical process

The fuel is first dissolved in

nitric acid Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitri ...

at a concentration around 7 M. Solids are removed by filtration to avoid the formation of

emulsion An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable) owing to liquid-liquid phase separation. Emulsions are part of a more general class of two-phase systems of matter called colloids. Althoug ...

s, referred to as

third phase Third phase is the term for a stable emulsion which forms in a liquid–liquid extraction when the original two phases (aqueous and organic) are mixed. The third phase can be caused by a detergent (surfactant) or a fine solid. While third phase is ...

s in the solvent extraction community. The

organic solvent A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for p ...

consists of 30%

tributyl phosphate Tributyl phosphate, known commonly as TBP, is an organophosphorus compound with the chemical formula (CH3CH2CH2CH2O)3PO. This colourless, odorless liquid finds some applications as an extractant and a plasticizer. It is an ester of phosphoric ac ...

(TBP) in a

hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ex ...

such as

kerosene Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from el, κηρός (''keros'') meaning "wax", and was regi ...

. Uranyl(VI) ions are extracted in the organic phase as UO₂(NO₃)₂·2TBP complexes; plutonium is extracted as similar complexes. The heavier actinides, primarily

and

curium Curium is a transuranic, radioactive chemical element with the symbol Cm and atomic number 96. This actinide element was named after eminent scientists Marie and Pierre Curie, both known for their research on radioactivity. Curium was first inte ...

, and the fission products remain in the aqueous phase. The nature of uranyl nitrate complexes with trialkyl phosphates has been characterized. Plutonium is separated from uranium by treating the TBP-kerosene solution with reducing agents to convert the plutonium to its +3 oxidation state, which will pass into the aqueous phase. Typical reducing agents include N,N-diethyl-

hydroxylamine Hydroxylamine is an inorganic compound with the formula . The material is a white crystalline, hygroscopic compound.Greenwood and Earnshaw. ''Chemistry of the Elements.'' 2nd Edition. Reed Educational and Professional Publishing Ltd. pp. 431–43 ...

ferrous In chemistry, the adjective Ferrous indicates a compound that contains iron(II), meaning iron in its +2 oxidation state, possibly as the divalent cation Fe2+. It is opposed to "ferric" or iron(III), meaning iron in its +3 oxidation state, such a ...

sulphamate, and

hydrazine Hydrazine is an inorganic compound with the chemical formula . It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour. Hydrazine is highly toxic unless handled in solution as, for example, hydrazine ...

. Uranium is then stripped from the kerosene solution by back-extraction into nitric acid at a concentration around 0.2 M.

PUREX raffinate

The term ''PUREX

raffinate In chemical separation terminology, the raffinate (from French ''raffiner'', to refine) is a product which has had a component or components removed. The product having the removed materials is referred to as the extract. For example, in solvent ex ...

'' describes the mixture of metals in

which are left behind when the

and

have been removed by the PUREX process from a

dissolution liquor. This mixture is often known as high level

nuclear waste Radioactive waste is a type of hazardous waste that contains radioactive material. Radioactive waste is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, rare-earth mining, and nuclear weapons r ...

. Two PUREX raffinates exist. The most highly active

from the first cycle is the one which is most commonly known as PUREX raffinate. The other is from the medium-active cycle in which the uranium and plutonium are refined by a second extraction with

. Deep blue is the bulk ions, light blue is the fission products (group I is Rb/Cs) (group II is Sr/Ba) (group III is Y and the

lanthanides The lanthanide () or lanthanoid () series of chemical elements comprises the 15 metallic chemical elements with atomic numbers 57–71, from lanthanum through lutetium. These elements, along with the chemically similar elements scandium and ytt ...

), orange is the

corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...

products (from stainless steel pipework), green are the major actinides, violet are the

minor actinides The minor actinides are the actinide elements in used nuclear fuel other than uranium and plutonium, which are termed the major actinides. The minor actinides include neptunium (element 93), americium (element 95), curium (element 96), berkeli ...

and magenta is the

neutron poison In applications such as nuclear reactors, a neutron poison (also called a neutron absorber or a nuclear poison) is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable eff ...

) Currently PUREX raffinate is stored in

stainless steel Stainless steel is an alloy of iron that is resistant to rusting and corrosion. It contains at least 11% chromium and may contain elements such as carbon, other nonmetals and metals to obtain other desired properties. Stainless steel's corros ...

tanks before being converted into glass. The first cycle PUREX raffinate is very

radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...

. It has almost all of the fission products,

products such as

iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...

nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to ...

, traces of uranium, plutonium and the

Pollution

The PUREX plant at the

Hanford Site The Hanford Site is a decommissioned nuclear production complex operated by the United States federal government on the Columbia River in Benton County in the U.S. state of Washington. The site has been known by many names, including SiteW a ...

was responsible for producing 'copious volumes of liquid wastes', resulting in the radioactive contamination of groundwater.

Greenpeace Greenpeace is an independent global campaigning network, founded in Canada in 1971 by Irving Stowe and Dorothy Stowe, immigrant environmental activists from the United States. Greenpeace states its goal is to "ensure the ability of the Earth t ...

measurements in

La Hague La Hague () is a commune in the department of Manche, northwestern France. The municipality was established on 1 January 2017 by merger of the former communes of Beaumont-Hague (the seat), Acqueville, Auderville, Biville, Branville-Hague, D ...

and Sellafield indicated that radioactive pollutants are steadily released into the sea, and the air. Therefore, people living near these processing plants are exposed to higher radiation levels than the naturally occurring

background radiation Background radiation is a measure of the level of ionizing radiation present in the environment at a particular location which is not due to deliberate introduction of radiation sources. Background radiation originates from a variety of sources ...

. According to

, this additional radiation is small but not negligible.

History

The PUREX process was invented by Herbert H. Anderson and Larned B. Asprey at the Metallurgical Laboratory at the

University of Chicago The University of Chicago (UChicago, Chicago, U of C, or UChi) is a private research university in Chicago, Illinois. Its main campus is located in Chicago's Hyde Park neighborhood. The University of Chicago is consistently ranked among the b ...

, as part of the

Manhattan Project The Manhattan Project was a research and development undertaking during World War II that produced the first nuclear weapons. It was led by the United States with the support of the United Kingdom and Canada. From 1942 to 1946, the project w ...

under

Glenn T. Seaborg Glenn Theodore Seaborg (; April 19, 1912February 25, 1999) was an American chemist whose involvement in the synthesis, discovery and investigation of ten transuranium elements earned him a share of the 1951 Nobel Prize in Chemistry. His work i ...

; their patent "Solvent Extraction Process for Plutonium" filed in 1947, mentions

as the major reactant which accomplishes the bulk of the chemical extraction.

List of nuclear reprocessing sites

COGEMA La Hague site The La Hague site is a nuclear fuel reprocessing plant at La Hague on the Cotentin Peninsula in northern France, with the Manche storage centre bordering on it. Operated by Orano, formerly AREVA, and prior to that COGEMA (''Compagnie général ...

Mayak The Mayak Production Association (russian: Производственное объединение «Маяк», , from 'lighthouse') is one of the biggest nuclear facilities in the Russian Federation, housing a reprocessing plant. The closest ...

Thermal Oxide Reprocessing Plant The Thermal Oxide Reprocessing Plant, or THORP, is a nuclear fuel reprocessing plant at Sellafield in Cumbria, England. THORP is owned by the Nuclear Decommissioning Authority and operated by Sellafield Ltd (which is the site licensee company ...

and

B205 The Magnox Reprocessing Plant is a former nuclear reprocessing facility at Sellafield in northern England, which operated from 1964 to 2022. The plant used PUREX chemistry (based on tributyl phosphate (TBP)) to extract plutonium and uranium fro ...

at Sellafield * Tokai, Ibaraki *

West Valley Reprocessing Plant The West Valley Demonstration Project is a nuclear waste remediation site in West Valley, New York in the U.S. state of New York. The project focuses on the cleanup and containment of radioactive waste left behind after the abandonment of a co ...

Savannah River Site The Savannah River Site (SRS) is a U.S. Department of Energy (DOE) reservation in the United States in the state of South Carolina, located on land in Aiken, Allendale, and Barnwell counties adjacent to the Savannah River, southeast of August ...

* Idaho Chemical Processing Plant, (now

Idaho National Laboratory Idaho National Laboratory (INL) is one of the national laboratories of the United States Department of Energy and is managed by the Battelle Energy Alliance. While the laboratory does other research, historically it has been involved with nu ...

) * Radiochemical Engineering Development Center,

Oak Ridge National Laboratory Oak Ridge National Laboratory (ORNL) is a U.S. multiprogram science and technology national laboratory sponsored by the U.S. Department of Energy (DOE) and administered, managed, and operated by UT–Battelle as a federally funded research and ...

References & notes

External links

Processing of Used Nuclear Fuel
, World Nuclear Association

Analytical Center for Non-proliferation

{{Webarchive, url=https://web.archive.org/web/20130301173649/http://www.world-nuclear.org/info/inf29.html , date=2013-03-01 – World Nuclear Association

– Congressional Research Service Report for Congress

Radioactive waste Waste treatment technology Nuclear chemistry

Nuclear reprocessing Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, the ...

Plutonium Uranium