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Overglaze decoration, overglaze enamelling, or on-glaze decoration, is a method of decorating
pottery Pottery is the process and the products of forming vessels and other objects with clay and other raw materials, which are fired at high temperatures to give them a hard and durable form. The place where such wares are made by a ''potter'' is al ...
, most often
porcelain Porcelain (), also called china, is a ceramic material made by heating Industrial mineral, raw materials, generally including kaolinite, in a kiln to temperatures between . The greater strength and translucence of porcelain, relative to oth ...
, where the coloured decoration is applied on top of the already fired and glazed surface, and then fixed in a second firing at a relatively low temperature, often in a muffle kiln. It is often described as producing "enamelled" decoration. The colours fuse onto the glaze, so the decoration becomes durable. This decorative firing is usually done at a lower temperature which allows for a more varied and vivid palette of colours, using pigments which will not colour correctly at the high temperature necessary to fire the porcelain body. Historically, a relatively narrow range of colours could be achieved with
underglaze Underglaze is a method of decorating pottery in which painted decoration is applied to the surface before it is covered with a transparent ceramic glaze and fired in a kiln. Because the glaze subsequently covers it, such decoration is completely ...
decoration, where the coloured pattern is applied before glazing, notably the
cobalt Cobalt is a chemical element; it has Symbol (chemistry), symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. ...
blue of
blue and white porcelain "Blue and white pottery" () covers a wide range of white pottery and porcelain decorated underglaze, under the glaze with a blue pigment, generally cobalt(II) oxide, cobalt oxide. The decoration was commonly applied by hand, originally by brush p ...
. Many historical styles, for example mina'i ware,
Imari ware is a Western term for a brightly-coloured style of Japanese export porcelain made in the area of Arita, in the former Hizen Province, northwestern Kyūshū. They were exported to Europe in large quantities, especially between the second half ...
, Chinese
doucai ''Doucai'' () is a technique in painting Chinese porcelain, where parts of the design, and some outlines of the rest, are painted in underglaze blue, and the piece is then ceramic glaze, glazed and fired. The rest of the design is then added in o ...
, and wucai, combine the two types of decoration. In such cases the first firing for the body, underglaze decoration and glaze is followed by the second firing after the overglaze enamels have been applied. The technique essentially uses powdered glass mixed with coloured pigments, and is the application of
vitreous enamel Vitreous enamel, also called porcelain enamel, is a material made by melting, fusing powdered glass to a substrate by firing, usually between . The powder melts, flows, and then hardens to a smooth, durable vitrification, vitreous coating. The wo ...
to pottery;
enamelled glass Enamelled glass or painted glass is glass which has been decorated with vitreous enamel (powdered glass, usually mixed with a binder) and then fired to glass fusing, fuse the glasses. It can produce brilliant and long-lasting colours, and be tr ...
is very similar but on glass. Both these latter two are essentially painting techniques, and have been since they began. In contrast, on metal painting in enamel arrived very late, long after techniques such as
cloisonné Cloisonné () is an ancient technology, ancient technique for decorating metalwork objects with colored material held in place or separated by metal strips or wire, normally of gold. In recent centuries, vitreous enamel has been used, but inla ...
, where thin wires are applied to form raised barriers, which contain areas of (subsequently applied) enamel, and champlevé, where the metal surface is sunk to form areas where the enamel is poured. In
Chinese porcelain Chinese ceramics are one of the most significant forms of Chinese art and ceramics globally. They range from construction materials such as bricks and tiles, to hand-built pottery vessels fired in bonfires or kilns, to the sophisticated Chinese ...
, enamels were and are sometimes applied to unglazed pieces; this is called "enamel on the biscuit" and similar terms.


History

Enamel was used in jewellery, applied to metal, from very early on: there are examples in the
Tomb of Tutankhamun The tomb of Tutankhamun (reigned ), a pharaoh of the Eighteenth Dynasty of Egypt, Eighteenth Dynasty of ancient Egypt, is located in the Valley of the Kings. The tomb, also known by its List of burials in the Valley of the Kings, tomb number KV ...
of c. 1325 BC. Enamel was also used to decorate glass by the time of the Roman Empire. Applied to pottery, it is first seen in Persian mina'i ware from the late 12th century, using a group of seven main colours. Presumably the potters learnt the technique from glassmakers. Slightly later it appeared in
Chinese ceramics Chinese ceramics are one of the most significant forms of Chinese art and ceramics globally. They range from construction materials such as bricks and tiles, to hand-built pottery vessels fired in bonfires or kilns, to the sophisticated Chinese ...
in Cizhou stoneware from as early as the 13th century, with use on porcelain following within a century, though it did not become predominant until later, and the full possibilities were not realized until the 17th and 18th centuries in the famille jaune, noire, rose, verte group of palettes. Some techniques use thin metal leaf, including mina'i ware as well as the more usual pigments, which are typically applied in a liquid or paste form, painted by brush, or using
stencil Stencilling produces an image or pattern on a surface by applying pigment to a surface through an intermediate object, with designed holes in the intermediate object. The holes allow the pigment to reach only some parts of the surface creatin ...
s or
transfer printing Transfer printing is a method of decorating pottery or other materials using an engraved copper or steel plate from which a monochrome print on paper is taken which is then transferred by pressing onto the ceramic piece.John Fleming (art histori ...
. The Japanese kakiemon style, and other Japanese styles, used the technique from at least the second half of the 17th century. The technique was also developing in Europe, firstly in what the French called ''petit feu''
faience Faience or faïence (; ) is the general English language term for fine tin-glazed pottery. The invention of a white Ceramic glaze, pottery glaze suitable for painted decoration, by the addition of an stannous oxide, oxide of tin to the Slip (c ...
, and in the 18th century in porcelain, and there appears to have been some influence in both directions between Asia and Europe. From about 1770 to the mid 20th century it was the dominant decorative technique in expensive pottery, mostly porcelain, made in Europe, East Asia, and (to a lesser extent) North America. In 18th-century England, where the technique was developed, the earliest forms of
transfer printing Transfer printing is a method of decorating pottery or other materials using an engraved copper or steel plate from which a monochrome print on paper is taken which is then transferred by pressing onto the ceramic piece.John Fleming (art histori ...
on pottery, for example by Sadler & Green in
Liverpool Liverpool is a port City status in the United Kingdom, city and metropolitan borough in Merseyside, England. It is situated on the eastern side of the River Mersey, Mersey Estuary, near the Irish Sea, north-west of London. With a population ...
, were overglaze, although by the end of the century it was normal to print as underglaze. Today overglaze decoration is much less commonly used, other than in traditionalist wares, as the range of colours available in underglaze has greatly expanded. Overglazes called "lusters" are still used for achieving special effects, such as
iridescence Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear gradually to change colour as the angle of view or the angle of illumination changes. Iridescence is caused by wave interference of light in microstru ...
of
mother-of-pearl Nacre ( , ), also known as mother-of-pearl, is an organicinorganic composite material produced by some molluscs as an inner shell layer. It is also the material of which pearls are composed. It is strong, resilient, and iridescent. Nacre is ...
overglazes or metallic look of overglazes made with metal (eg. gold) particles.


Muffle kilns

The kiln used for the second firing is usually called a muffle kiln in Europe; like other types of muffle furnaces the design isolates the objects from the flames producing the heat (with electricity this is not so important). For historical overglaze enamels the kiln was generally far smaller than that for the main firing, and produced firing temperatures in the approximate range of 750 to 950 °C, depending on the colours used. Typically, wares were fired for between five and twelve hours and then cooled over twelve hours.Hughes, 34-35


Notes


References

*Hughes, G Bernard, ''The Country Life Pocket Book of China'', 1965, Country Life Ltd * Needham, Joseph (ed), ''Science and Civilisation in China'', Volume 5, Part 12, 2004, Cambridge University Press, , 9780521838337
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*Vainker, S.J., ''Chinese Pottery and Porcelain'', 1991, British Museum Press, 9780714114705 *Watson, Oliver, "Pottery under the Mongols" in ''Beyond the Legacy of Genghis Khan'', 2012, BRILL, Ed. Linda Komaroff, , 9789004243408
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{{Ceramics-stub Types of pottery decoration