Opal is a

hydrate In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understo ...

amorphous In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal. Etymology The term comes from the Greek ''a'' ("wi ...

form of silica (SiO₂·''n''H₂O); its water content may range from 3 to 21% by weight, but is usually between 6 and 10%. Due to its amorphous property, it is classified as a

mineraloid A mineraloid is a naturally occurring mineral-like substance that does not demonstrate crystallinity. Mineraloids possess chemical compositions that vary beyond the generally accepted ranges for specific minerals. For example, obsidian is an amor ...

, unlike crystalline forms of silica, which are considered minerals. It is deposited at a relatively low temperature and may occur in the fissures of almost any kind of rock, being most commonly found with

limonite Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxid ...

, sandstone,

rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...

marl Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae. Marl makes up the lower part o ...

, and basalt. The name ''opal'' is believed to be derived from the Sanskrit word (), which means 'jewel', and later the Greek derivative (), which means 'to see a change in color'. There are two broad classes of opal: precious and common. Precious opal displays play-of-color (

iridescence Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear to gradually change color as the angle of view or the angle of illumination changes. Examples of iridescence include soap bubbles, feathers, butterfl ...

); common opal does not. Play-of-color is defined as "a pseudo chromatic optical effect resulting in flashes of colored light from certain minerals, as they are turned in white light." The internal structure of precious opal causes it to diffract light, resulting in play-of-color. Depending on the conditions in which it formed, opal may be transparent, translucent, or opaque, and the background color may be white, black, or nearly any color of the visual spectrum. Black opal is considered the rarest, while white, gray, and green opals are the most common.

Precious opal

Precious opal shows a variable interplay of internal colors, and though it is a mineraloid, it has an internal structure. At microscopic scales, precious opal is composed of silica spheres some in diameter in a hexagonal or cubic close-packed lattice. It was shown by J. V. Sanders in the mid-1960s that these ordered silica spheres produce the internal colors by causing the interference and

diffraction Diffraction is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a s ...

of light passing through the microstructure of the opal. The regularity of the sizes and the packing of these spheres is a prime determinant of the quality of precious opal. Where the distance between the regularly packed planes of spheres is around half the wavelength of a component of visible light, the light of that wavelength may be subject to diffraction from the grating created by the stacked planes. The colors that are observed are determined by the spacing between the planes and the orientation of planes with respect to the incident light. The process can be described by Bragg's law of diffraction. Visible light cannot pass through large thicknesses of the opal. This is the basis of the optical band gap in a photonic crystal. The notion that opals are photonic crystals for visible light was expressed in 1995 by

Vasily Astratov Vasily Astratov is a full professor of Physics and Optical Science at the University of North Carolina at Charlotte. He became known for launching synthetic opals as new self-assembled photonic crystals for visible light in 1995 in his former gr ...

's group. In addition, microfractures may be filled with secondary silica and form thin lamellae inside the opal during its formation. The term

Opalescence Opalescence refers to the optical phenomena displayed by the mineraloid gemstone opalopalescent. 2019. In Noah Webster's 1828 American Dictionary of the English Language. Retrieved January 7, 2019, from https://1828.mshaffer.com/d/word/opalesc ...

is commonly used to describe this unique and beautiful phenomenon, which in gemology is termed play of color. In gemology, opalescence is applied to the hazy-milky- turbid sheen of common or potch opal which does not show a play of color. Opalescence is a form of adularescence. For

gemstone A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...

use, most opal is cut and polished to form a cabochon. "Natural" opal refers to polished stones consisting wholly of precious opal. Opals too thin to produce a "Natural" opal may be combined with other materials to form "composite" gems. An opal

doublet Doublet is a word derived from the Latin ''duplus'', "twofold, twice as much",