Opal is a

hydrate In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understo ...

amorphous In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid, glassy solid) is a solid that lacks the long-range order that is characteristic of a crystal. Etymology The term comes from the Greek ''a'' ("wi ...

form of

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...

(SiO₂·''n''H₂O); its

water content Water content or moisture content is the quantity of water contained in a material, such as soil (called soil moisture), rock, ceramics, crops, or wood. Water content is used in a wide range of scientific and technical areas, and is expressed as ...

may range from 3 to 21% by weight, but is usually between 6 and 10%. Due to its amorphous property, it is classified as a

mineraloid A mineraloid is a naturally occurring mineral-like substance that does not demonstrate crystallinity. Mineraloids possess chemical compositions that vary beyond the generally accepted ranges for specific minerals. For example, obsidian is an amor ...

, unlike

crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...

line forms of silica, which are considered

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...

s. It is deposited at a relatively low temperature and may occur in the

fissure A fissure is a long, narrow crack opening along the surface of Earth. The term is derived from the Latin word , which means 'cleft' or 'crack'. Fissures emerge in Earth's crust, on ice sheets and glaciers, and on volcanoes. Ground fissure A ...

s of almost any kind of

rock Rock most often refers to: * Rock (geology), a naturally occurring solid aggregate of minerals or mineraloids * Rock music, a genre of popular music Rock or Rocks may also refer to: Places United Kingdom * Rock, Caerphilly, a location in Wales ...

, being most commonly found with

limonite Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxid ...

sandstone Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks. Most sandstone is composed of quartz or feldspar (both silicates) ...

rhyolite Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...

marl Marl is an earthy material rich in carbonate minerals, clays, and silt. When hardened into rock, this becomes marlstone. It is formed in marine or freshwater environments, often through the activities of algae. Marl makes up the lower part o ...

, and

basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...

. The name ''opal'' is believed to be derived from the Sanskrit word (), which means 'jewel', and later the Greek derivative (), which means 'to see a change in color'. There are two broad classes of opal: precious and common. Precious opal displays play-of-color (

iridescence Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear to gradually change color as the angle of view or the angle of illumination changes. Examples of iridescence include soap bubbles, feathers, butterfl ...

); common opal does not. Play-of-color is defined as "a pseudo chromatic optical effect resulting in flashes of colored light from certain minerals, as they are turned in white light." The internal structure of precious opal causes it to

diffract Diffraction is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a s ...

light, resulting in play-of-color. Depending on the conditions in which it formed, opal may be transparent, translucent, or opaque, and the background color may be white, black, or nearly any color of the visual spectrum. Black opal is considered the rarest, while white, gray, and green opals are the most common.

Precious opal

Precious opal shows a variable interplay of internal colors, and though it is a mineraloid, it has an internal structure. At microscopic scales, precious opal is composed of silica spheres some in diameter in a hexagonal or cubic

close-packed In geometry, close-packing of equal spheres is a dense arrangement of congruent spheres in an infinite, regular arrangement (or lattice). Carl Friedrich Gauss proved that the highest average density – that is, the greatest fraction of space occu ...

lattice Lattice may refer to: Arts and design * Latticework, an ornamental criss-crossed framework, an arrangement of crossing laths or other thin strips of material * Lattice (music), an organized grid model of pitch ratios * Lattice (pastry), an orna ...

. It was shown by J. V. Sanders in the mid-1960s that these ordered silica spheres produce the internal colors by causing the

interference Interference is the act of interfering, invading, or poaching. Interference may also refer to: Communications * Interference (communication), anything which alters, modifies, or disrupts a message * Adjacent-channel interference, caused by extr ...

and

diffraction Diffraction is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a s ...

of light passing through the microstructure of the opal. The regularity of the sizes and the packing of these spheres is a prime determinant of the quality of precious opal. Where the distance between the regularly packed planes of spheres is around half the wavelength of a component of

visible light Light or visible light is electromagnetic radiation that can be perceived by the human eye. Visible light is usually defined as having wavelengths in the range of 400–700 nanometres (nm), corresponding to frequencies of 750–420 te ...

, the light of that wavelength may be subject to diffraction from the

grating A grating is any regularly spaced collection of essentially identical, parallel, elongated elements. Gratings usually consist of a single set of elongated elements, but can consist of two sets, in which case the second set is usually perpendicul ...

created by the stacked planes. The colors that are observed are determined by the spacing between the planes and the orientation of planes with respect to the incident light. The process can be described by

Bragg's law In physics and chemistry , Bragg's law, Wulff–Bragg's condition or Laue–Bragg interference, a special case of Laue diffraction, gives the angles for coherent scattering of waves from a crystal lattice. It encompasses the superposition of wave ...

of diffraction. Visible light cannot pass through large thicknesses of the opal. This is the basis of the optical

band gap In solid-state physics, a band gap, also called an energy gap, is an energy range in a solid where no electronic states can exist. In graphs of the electronic band structure of solids, the band gap generally refers to the energy difference (in ...

in a

photonic crystal A photonic crystal is an optical nanostructure in which the refractive index changes periodically. This affects the propagation of light in the same way that the structure of Crystal structure, natural crystals gives rise to X-ray crystallograp ...

. The notion that opals are photonic crystals for visible light was expressed in 1995 by Vasily Astratov's group. In addition, microfractures may be filled with secondary silica and form thin

lamella Lamella (plural lamellae) means a small plate or flake in Latin, and in English may refer to: Biology * Lamella (mycology), a papery rib beneath a mushroom cap * Lamella (botany) * Lamella (surface anatomy), a plate-like structure in an animal ...

e inside the opal during its formation. The term

Opalescence Opalescence refers to the optical phenomena displayed by the mineraloid gemstone opalopalescent. 2019. In Noah Webster's 1828 American Dictionary of the English Language. Retrieved January 7, 2019, from https://1828.mshaffer.com/d/word/opalesc ...

is commonly used to describe this unique and beautiful phenomenon, which in gemology is termed play of color. In gemology, opalescence is applied to the hazy-milky-

turbid Turbidity is the cloudiness or haziness of a fluid caused by large numbers of individual particles that are generally invisible to the naked eye, similar to smoke in air. The measurement of turbidity is a key test of water quality. Fluids can ...

sheen of common or potch opal which does not show a play of color. Opalescence is a form of

adularescence Adularescence ( ) is an optical phenomenon that is produced in gemstones like moonstone. The optical effect is similar to labradorescence and aventurescence. Description The effect of adularescence, also commonly referred to as '' schiller'' ...

. For

gemstone A gemstone (also called a fine gem, jewel, precious stone, or semiprecious stone) is a piece of mineral crystal which, in cut and polished form, is used to make jewelry or other adornments. However, certain rocks (such as lapis lazuli, opal, ...

use, most opal is cut and polished to form a

cabochon A cabochon (; ) is a gemstone that has been shaped and polished, as opposed to faceted. The resulting form is usually a convex (rounded) obverse with a flat reverse. Cabochon was the default method of preparing gemstones before gemstone cuttin ...

. "Natural" opal refers to polished stones consisting wholly of precious opal. Opals too thin to produce a "Natural" opal may be combined with other materials to form "composite" gems. An opal

doublet Doublet is a word derived from the Latin ''duplus'', "twofold, twice as much",