Nitrogen trichloride, also known as trichloramine, is the

chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...

with the

formula In science, a formula is a concise way of expressing information symbolically, as in a mathematical formula or a ''chemical formula''. The informal use of the term ''formula'' in science refers to the general construct of a relationship betwee ...

NCl₃. This yellow, oily, pungent-smelling and explosive liquid is most commonly encountered as a byproduct of

chemical reaction A chemical reaction is a process that leads to the IUPAC nomenclature for organic transformations, chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the pos ...

s between

ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...

-derivatives and

chlorine Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...

(for example, in

swimming pool A swimming pool, swimming bath, wading pool, paddling pool, or simply pool, is a structure designed to hold water to enable Human swimming, swimming or other leisure activities. Pools can be built into the ground (in-ground pools) or built ...

s). Alongside

monochloramine Monochloramine, often called chloramine, is the chemical compound with the formula NH2Cl. Together with dichloramine (NHCl2) and nitrogen trichloride (NCl3), it is one of the three chloramines of ammonia. It is a colorless liquid at its melting p ...

and

dichloramine Dichloramine is a reactive inorganic compound. It has the formula . The yellow gas is unstable and reacts with many materials. It is formed by a reaction between ammonia and chlorine or sodium hypochlorite. It is a byproduct formed during the synth ...

, trichloramine is responsible for the distinctive 'chlorine smell' associated with swimming pools, where the compound is readily formed as a product from

hypochlorous acid Hypochlorous acid (HClO, HOCl, or ClHO) is a weak acid that forms when chlorine dissolves in water, and itself partially dissociates, forming hypochlorite, ClO−. HClO and ClO− are oxidizers, and the primary disinfection agents of chlorine so ...

reacting with

and other nitrogenous substances in the water, such as

urea Urea, also known as carbamide, is an organic compound with chemical formula . This amide has two amino groups (–) joined by a carbonyl functional group (–C(=O)–). It is thus the simplest amide of carbamic acid. Urea serves an important r ...

from

urine Urine is a liquid by-product of metabolism in humans and in many other animals. Urine flows from the kidneys through the ureters to the urinary bladder. Urination results in urine being excretion, excreted from the body through the urethra. Cel ...

Preparation and structure

The compound is prepared by treatment of ammonium salts, such as

ammonium nitrate Ammonium nitrate is a chemical compound with the chemical formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is ...

with chlorine. Intermediates in this conversion include

and

, NH₂Cl and NHCl₂, respectively. Like ammonia, NCl₃ is a

pyramidal molecule In chemistry, a trigonal pyramid is a molecular geometry with one atom at the apex and three atoms at the corners of a trigonal base, resembling a tetrahedron (not to be confused with the tetrahedral geometry). When all three atoms at the corner ...

. The N-Cl distances are 1.76 Å, and the Cl-N-Cl angles are 107°.

Reactions and uses

The chemistry of NCl₃ has been well explored. It is moderately

polar Polar may refer to: Geography Polar may refer to: * Geographical pole, either of two fixed points on the surface of a rotating body or planet, at 90 degrees from the equator, based on the axis around which a body rotates * Polar climate, the c ...

with a dipole moment of 0.6 D. The nitrogen center is basic but much less so than ammonia. It is

hydrolyzed Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolysis ...

by hot water to release

and

. :NCl₃ + 3 H₂O → NH₃ + 3 HOCl NCl₃ explodes to give N₂ and

chlorine gas Chlorine is a chemical element with the symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is ...

. This reaction is inhibited for dilute gases. Nitrogen trichloride can form in small amounts when public water supplies are disinfected with

, and in swimming pools by disinfecting chlorine reacting with

in urine and sweat from bathers. Nitrogen trichloride, trademarked as

Agene Nitrogen trichloride, also known as trichloramine, is the chemical compound with the formula NCl3. This yellow, oily, pungent-smelling and explosive liquid is most commonly encountered as a byproduct of chemical reactions between ammonia-derivativ ...

, was at one time used to bleach

flour Flour is a powder made by grinding raw grains, roots, beans, nuts, or seeds. Flours are used to make many different foods. Cereal flour, particularly wheat flour, is the main ingredient of bread, which is a staple food for many culture ...

, but this practice was banned in the United States in 1949 due to safety concerns.

Safety

Nitrogen trichloride can irritate mucous membranes—it is a

lachrymatory agent Tear gas, also known as a lachrymator agent or lachrymator (), sometimes colloquially known as "mace" after the early commercial aerosol, is a chemical weapon that stimulates the nerves of the lacrimal gland in the eye to produce tears. In ad ...

, but has never been used as such. The pure substance (rarely encountered) is a dangerous explosive, being sensitive to light, heat, even moderate shock, and organic compounds.

Pierre Louis Dulong Pierre Louis Dulong FRS FRSE (; ; 12 February 1785 – 19 July 1838) was a French physicist and chemist. He is remembered today largely for the law of Dulong and Petit, although he was much-lauded by his contemporaries for his studies into ...

first prepared it in 1812, and lost two fingers and an eye in two explosions. In 1813, an NCl₃ explosion blinded Sir

Humphry Davy Sir Humphry Davy, 1st Baronet, (17 December 177829 May 1829) was a British chemist and inventor who invented the Davy lamp and a very early form of arc lamp. He is also remembered for isolating, by using electricity, several elements for t ...

temporarily, inducing him to hire

Michael Faraday Michael Faraday (; 22 September 1791 – 25 August 1867) was an English scientist who contributed to the study of electromagnetism and electrochemistry. His main discoveries include the principles underlying electromagnetic inducti ...

as a co-worker. They were both injured in another NCl₃ explosion shortly thereafter.

References

External links

OSHA - Nitrogen trichloride

Nitrogen Trichloride - Health References
{{Chlorides Inorganic amines Chlorides Nitrogen halides Inorganic chlorine compounds Inorganic nitrogen compounds Explosive chemicals Nitrogen(III) compounds Liquid explosives

Preparation and structure

Reactions and uses

Safety

See also

References

Further reading

External links